Correlation decoupling of Casimir interaction in an electrolyte driven by external electric fields
Abstract
It has been established for a long time that the long range van der Waals or thermal Casimir interaction between two semi-infinite dielectrics separated by a distance is screened by an intervening electrolyte. Here we show how this interaction is modified when an electric field of strength is applied parallel to the dielectric boundaries, leading to a non-equilibrium steady state with a current. The presence of the field induces a long range thermal repulsive interaction, scaling just like the thermal Casimir interaction between dielectrics without the intervening electrolyte, {\em i.e.} as . At small the effect is of order while at large fields it saturates to an independent value. We explain the results in terms of a decoupling mechanism between the charge density fluctuations of cations and anions at large applied fields.
Cite
@article{arxiv.2404.06028,
title = {Correlation decoupling of Casimir interaction in an electrolyte driven by external electric fields},
author = {Guangle Du and David S. Dean and Bing Miao and Rudolf Podgornik},
journal= {arXiv preprint arXiv:2404.06028},
year = {2025}
}
Comments
6 pages, 2 figures, final published version