English

Correlation decoupling of Casimir interaction in an electrolyte driven by external electric fields

Statistical Mechanics 2025-01-23 v2 Soft Condensed Matter

Abstract

It has been established for a long time that the long range van der Waals or thermal Casimir interaction between two semi-infinite dielectrics separated by a distance HH is screened by an intervening electrolyte. Here we show how this interaction is modified when an electric field of strength EE is applied parallel to the dielectric boundaries, leading to a non-equilibrium steady state with a current. The presence of the field induces a long range thermal repulsive interaction, scaling just like the thermal Casimir interaction between dielectrics without the intervening electrolyte, {\em i.e.} as 1/H31/H^3. At small EE the effect is of order E2E^2 while at large fields it saturates to an EE independent value. We explain the results in terms of a decoupling mechanism between the charge density fluctuations of cations and anions at large applied fields.

Keywords

Cite

@article{arxiv.2404.06028,
  title  = {Correlation decoupling of Casimir interaction in an electrolyte driven by external electric fields},
  author = {Guangle Du and David S. Dean and Bing Miao and Rudolf Podgornik},
  journal= {arXiv preprint arXiv:2404.06028},
  year   = {2025}
}

Comments

6 pages, 2 figures, final published version

R2 v1 2026-06-28T15:48:20.329Z