English

Contactium: A strongly correlated model system

Chemical Physics 2023-05-24 v1 Quantum Gases Quantum Physics

Abstract

At the limit of an infinite confinement strength ω\omega, the ground state of a system that comprises two fermions or bosons in a harmonic confinement interacting through the Fermi--Huang pseudopotential remains strongly correlated. A detailed analysis of the one-particle description of this ``contactium'' reveals several peculiarities that are not encountered in conventional model systems (such as the two-electron harmonium atom, ballium, and spherium) involving Coulombic interparticle interactions. First of all, none of the natural orbitals (NOs) {ψn(ω;r)}\{ \psi_\mathfrak{n}(\omega;\vec r) \} of the contactium is unoccupied, which implies nonzero collective occupancies for all the angular momenta. Second, the NOs and their nonascendingly ordered occupation numbers {νn}\{ \nu_\mathfrak{n} \} turn out to be related to the eigenfunctions and eigenvalues of a zero-energy Schr\"odinger equation with an attractive Gaussian potential. This observation enables the derivation of their properties such as the n4/3\mathfrak{n}^{-4/3} asymptotic decay of νn\nu_\mathfrak{n} at the n\mathfrak{n} \to \infty limit (which differs from that of n8/3\mathfrak{n}^{-8/3} in the Coulombic systems), the independence of the confinement energy {v_\mathfrak{n} = \langle \psi_\mathfrak{n}(\omega;\vec r) | \frac{1}{2} % \omega^2r^2 | \psi_\mathfrak{n}(\omega;\vec r) \rangle} of n\mathfrak{n}, and the n2/3\mathfrak{n}^{-2/3} asymptotic decay of the respective contribution νntn\nu_\mathfrak{n}t_\mathfrak{n} to the kinetic energy. Upon suitable scaling, the weakly occupied NOs of the contactium turn out to be virtually identical with those of the two-electron harmonium atom at the ω{\omega \to \infty} limit, despite the entirely different interparticle interactions in these systems.

Keywords

Cite

@article{arxiv.2303.14982,
  title  = {Contactium: A strongly correlated model system},
  author = {Jerzy Cioslowski and Berthold-Georg Englert and Martin-Isbjörn Trappe and Jun Hao Hue},
  journal= {arXiv preprint arXiv:2303.14982},
  year   = {2023}
}

Comments

9 pages, 5 figures, 1 table

R2 v1 2026-06-28T09:34:55.738Z