English

Computation of nucleation of a non-equilibrium first-order phase transition using a rare-event algorithm

Statistical Mechanics 2015-05-19 v1

Abstract

We introduce a new Forward-Flux Sampling in Time (FFST) algorithm to efficiently measure transition times in rare-event processes in non-equilibrium systems, and apply it to study the first-order (discontinuous) kinetic transition in the Ziff-Gulari-Barshad model of catalytic surface reaction. The average time for the transition to take place, as well as both the spinodal and transition points, are clearly found by this method.

Keywords

Cite

@article{arxiv.1007.0521,
  title  = {Computation of nucleation of a non-equilibrium first-order phase transition using a rare-event algorithm},
  author = {David A. Adams and Robert M. Ziff and Leonard M. Sander},
  journal= {arXiv preprint arXiv:1007.0521},
  year   = {2015}
}

Comments

12 pages, 10 figures

R2 v1 2026-06-21T15:44:11.063Z