English

Classical microscopic theory of polaritons in ionic crystals

Statistical Mechanics 2014-03-05 v1 Optics

Abstract

It is well known that the optical branches of the dispersion curves of ionic crystals exhibit a polaritonic feature, i.e., a splitting about the electromagnetic dispersion line ω=ck\omega=ck. This phenomenon is considered to be due to the retardation of the electromagnetic forces among the ions. However, the problem is usually discussed at a phenomenological level, through the introduction of a macroscopic polarization field, so that a microscopic treatment is apparently lacking. A microscopic first principles deduction is given here, in a classical frame, for a model in which the ions are dealt with as point charges. At a qualitative level it is made apparent that retardation is indeed responsible for the splitting. A quantitative comparison with the empirical data for LiF is also given, showing a fairly good agreement over the whole Brillouin zone.

Keywords

Cite

@article{arxiv.1312.0893,
  title  = {Classical microscopic theory of polaritons in ionic crystals},
  author = {A. Lerose and A. Sanzeni and A Carati and L. Galgani},
  journal= {arXiv preprint arXiv:1312.0893},
  year   = {2014}
}

Comments

2 Figures, submitted to EJPD

R2 v1 2026-06-22T02:19:57.646Z