English

Cavity engineered phonon-mediated superconductivity in MgB$_2$ from first principles quantum electrodynamics

Superconductivity 2025-02-05 v3 Materials Science Applied Physics Computational Physics

Abstract

Strong laser pulses can control superconductivity, inducing non-equilibrium transient pairing by leveraging strong-light matter interaction. Here we demonstrate theoretically that equilibrium ground-state phonon-mediated superconductive pairing can be affected through the vacuum fluctuating electromagnetic field in a cavity. Using the recently developed ab initio quantum electrodynamical density-functional theory approximation, we specifically investigate the phonon-mediated superconductive behavior of MgB2_2 under different cavity setups and find that in the strong light-matter coupling regime its superconducting transition temperature can be, in principles, enhanced by 73%\approx 73\% (40%\approx 40\%) in an in-plane (out-of-plane) polarized cavity. However, in a realistic cavity, we expect the Tc_{\rm{c}} of MgB2_2 can increase, at most, by 55 K via photon vacuum fluctuations. The results highlight that strong light-matter coupling in extended systems can profoundly alter material properties in a non-perturbative way by modifying their electronic structure and phononic dispersion at the same time. Our findings indicate a pathway to the experimental realization of light-controlled superconductivity in solid-state materials at equilibrium via cavity-material engineering.

Keywords

Cite

@article{arxiv.2404.08122,
  title  = {Cavity engineered phonon-mediated superconductivity in MgB$_2$ from first principles quantum electrodynamics},
  author = {I-Te Lu and Dongbin Shin and Mark Kamper Svendsen and Hannes Hübener and Umberto De Giovannini and Simone Latini and Michael Ruggenthaler and Angel Rubio},
  journal= {arXiv preprint arXiv:2404.08122},
  year   = {2025}
}

Comments

30 pages, 3 figures

R2 v1 2026-06-28T15:51:55.690Z