English

Approach to equilibrium for a particle interacting with a harmonic thermal bath

Statistical Mechanics 2026-04-21 v2 Mathematical Physics math.MP

Abstract

We study the long time evolution of the position-position correlation function Cα,N(s,t)C_{\alpha,N}(s,t) for a harmonic oscillator (the {\it probe}) interacting via a coupling α\alpha with a large chain of NN coupled oscillators (the {\it heat bath}). At t=0t=0 the probe and the bath are in equilibrium at temperature TPT_P and TBT_B, respectively. We show that for times tt and ss of the order of NN, Cα,N(s,t)C_{\alpha,N}(s,t) is very well approximated by its limit Cα(s,t)C_{\alpha}(s,t) as NN\to\infty. We find that, if the frequency Ω\Omega of the probe is in the spectrum of the bath, the system appears to thermalize, at least at higher order in α\alpha. This means that, at order 0 in α\alpha, Cα(s,t)C_\alpha(s,t) equals the correlation of a probe in contact with an ideal stochastic {\it thermostat}, that is forced by a white noise and subject to dissipation. In particular we find that limtCα(t,t)=TB/Ω2\lim_{t\to\infty} C_\alpha(t,t)=T_B/\Omega^2 while that limτCα(τ,τ+t)\lim_{\tau\to\infty} C_\alpha(\tau,\tau+t) exists and decays exponentially in tt. Notwithstanding this, at higher order in α\alpha, Cα(s,t)C_{\alpha}(s,t) contains terms that oscillate or vanish as a power law in ts|t-s|. That is, even when the bath is very large, it cannot be thought of as a stochastic thermostat. When the frequency of the bath is far from the spectrum of the bath, no thermalization is observed.

Keywords

Cite

@article{arxiv.2510.20003,
  title  = {Approach to equilibrium for a particle interacting with a harmonic thermal bath},
  author = {Federico Bonetto and Alberto Mario Maiocchi},
  journal= {arXiv preprint arXiv:2510.20003},
  year   = {2026}
}

Comments

39 pages

R2 v1 2026-07-01T07:00:46.300Z