Algebraic description of anharmonic stretching vibrations
Chemical Physics
2009-10-31 v1
Abstract
A U(2) algebraic model is presented to describe stretching vibrations of XY (n=2, 3, and 4) systems, where anharmonic interactions between the bond modes are considered. This model in a limit corresponds to an anharmonically coupled local mode model. As an example, the model for a molecule XY is applied to recently observed spectra of methane in both gas and liquid phases, and the results obtained are in good agreement with the experiments.
Keywords
Cite
@article{arxiv.physics/9904021,
title = {Algebraic description of anharmonic stretching vibrations},
author = {Xi-Wen Hou and Shi-Hai Dong and Zhong-Qi Ma},
journal= {arXiv preprint arXiv:physics/9904021},
year = {2009}
}