English

Active alignment-driven coarsening in confined near-critical fluids

Soft Condensed Matter 2026-01-15 v1 Materials Science Statistical Mechanics Biological Physics

Abstract

We investigate vapor-liquid phase separation of an active near critical Lennard-Jones fluid confined within a cylindrical pore using molecular dynamics simulations. Activity is introduced via Vicsek-type alignment interactions, enabling a systematic study of how self-propulsion modifies domain morphology and coarsening kinetics under quasi-one-dimensional confinement. In the passive limit, the system undergoes early-time spinodal decomposition (diffusive growth characterized by the Lifshitz-Slyozov exponent α=1/3\alpha = 1/3), followed by the formation of periodically modulated, plug-like liquid domains along the pore axis. At late times, coarsening becomes kinetically arrested, and the system remains trapped in a metastable striped state. Introducing activity destabilizes this arrested morphology by enhancing collective domain transport, leading to frequent domain mergers and complete phase separation at sufficiently high activity. The late-stage coarsening then exhibits a crossover to faster, ballistic growth with an effective exponent α=2/3\alpha = 2/3, consistent with a cluster-coalescence mechanism. Analysis of two-point correlation functions and structure factors confirms dynamic scaling across all activity regimes. Our results demonstrate that alignment-induced activity can overcome confinement-driven kinetic arrest, providing new insight into phase separation in confined active fluids. The relevant growth laws are analyzed and interpreted using appropriate theoretical frameworks.

Keywords

Cite

@article{arxiv.2601.09181,
  title  = {Active alignment-driven coarsening in confined near-critical fluids},
  author = {Parameshwaran A and Bhaskar Sen Gupta},
  journal= {arXiv preprint arXiv:2601.09181},
  year   = {2026}
}
R2 v1 2026-07-01T09:03:50.877Z