English

Ab initio path integral Monte Carlo simulations of warm dense two-component systems without fixed nodes: structural properties

Computational Physics 2024-03-05 v1 Chemical Physics Plasma Physics

Abstract

We present extensive new \emph{ab initio} path integral Monte Carlo (PIMC) results for a variety of structural properties of warm dense hydrogen and beryllium. To deal with the fermion sign problem -- an exponential computational bottleneck due to the antisymmetry of the electronic thermal density matrix -- we employ the recently proposed [\textit{J.~Chem.~Phys.}~\textbf{157}, 094112 (2022); \textbf{159}, 164113 (2023)] ξ\xi-extrapolation method and find excellent agreement with exact direct PIMC reference data where available. This opens up the intriguing possibility to study a gamut of properties of light elements and potentially material mixtures over a substantial part of the warm dense matter regime, with direct relevance for astrophysics, material science, and inertial confinement fusion research.

Keywords

Cite

@article{arxiv.2403.01979,
  title  = {Ab initio path integral Monte Carlo simulations of warm dense two-component systems without fixed nodes: structural properties},
  author = {Tobias Dornheim and Sebastian Schwalbe and Maximilian Böhme and Zhandos Moldabekov and Jan Vorberger and Panagiotis Tolias},
  journal= {arXiv preprint arXiv:2403.01979},
  year   = {2024}
}
R2 v1 2026-06-28T15:08:17.555Z