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This report discusses two new ideas for using perturbation methods to solve the time-independent Schr\"odinger equation. The first concept begins with rewriting the perturbation equations in a form that is closely related to matrix…

Quantum Physics · Physics 2013-10-25 Gerald I. Kerley

A few modified textbook Rayleigh-Schr\"{o}dinger perturbative representations of bound states are reviewed. They were all inspired by an adaptive re-split of the Hamiltonian, using nonstandard bases and the flexibility of normalization of…

Quantum Physics · Physics 2007-05-23 Miloslav Znojil

A remarkable extension of Rayleigh-Schroedinger perturbation method is found. Its (N+q) x (N+1) - dimensional Hamiltonians (as emerging, e.g., during quasi-exact constructions of bound states) are non-square matrices at q > 1. The role of…

Mathematical Physics · Physics 2007-05-23 Miloslav Znojil

I propose a new version of the Rayleigh - Schr\"{o}dinger perturbation method. It admits a lower triangular matrix in place of the usual diagonal propagator. Illustrated on rational anharmonicities polynomial}(x)/polynomial}(x), treated as…

Quantum Physics · Physics 2007-05-23 Miloslav Znojil

A recently developed linear algebraic method for the computation of perturbation expansion coefficients to large order is applied to the problem of a hydrogenic atom in a magnetic field. We take as the zeroth order approximation the $D…

chem-ph · Physics 2009-10-22 Timothy C. Germann , Dudley R. Herschbach , Bruce M. Boghosian

In this work we show that results of Rayleigh-Schr\"{o}dinger perturbation theory can be easily obtained using the recently proposed supersymmetric expansion algorithm. Our formalism avoids the sums over intermediate states and yield…

High Energy Physics - Phenomenology · Physics 2026-01-15 M. Napsuciale , S. Rodríguez

We generalize a recently proposed small-energy expansion for one-dimensional quantum-mechanical models. The original approach was devised to treat symmetric potentials and here we show how to extend it to non-symmetric ones. Present…

Quantum Physics · Physics 2014-10-23 Paolo Amore , Francisco M. Fernández

The O(4) supersymmetry of the hydrogen atom is utilized to construct a complete basis using only the bound state wave functions. For a large class of perturbations, an expansion of the electron (exciton) wave function into such a complete…

Mathematical Physics · Physics 2012-05-25 E. A. Muljarov

We derive new expressions for the Rayleigh-Schr\"odinger seriesdescribing the perturbation of eigenvalues of quantumHamiltonians. The method, somehow close to the so-called dimensionalrenormalization in quantum field theory, involves the…

Analysis of PDEs · Mathematics 2020-03-25 Jean-Christophe Novelli , Thierry Paul , David Sauzin , Jean-Yves Thibon

The new perturbation theory for the problem of nonstationary anharmonic oscillator with polynomial nonstationary perturbation is proposed. As a zero order approximation the exact wave function of harmonic oscillator with variable frequency…

Quantum Physics · Physics 2016-09-08 Alexander V. Bogdanov , Ashot S. Gevorkyan

The perturbation technique within the framework of the asymptotic iteration method is used to obtain large-order shifted 1/N expansions, where N is the number of spatial dimensions. This method is contrary to the usual…

Quantum Physics · Physics 2007-08-17 T. Barakat

Sextic oscillator in D dimensions is considered as a typical quasi-exactly solvable (QES) model. Usually, its QES N-plets of bound states have to be computed using the coupled Magyari's nonlinear algebraic equations. We propose and describe…

Mathematical Physics · Physics 2007-05-23 Miloslav Znojil

We present a novel form of relativistic quantum mechanics and demonstrate how to solve it using a recently derived unitary perturbation theory, within partial wave analysis. The theory is tested on a relativistic problem, with two spinless,…

Quantum Physics · Physics 2021-08-11 Scott E. Hoffmann

The explicit semiclassical treatment of the logarithmic perturbation theory for the bound-state problem for the spherical anharmonic oscillator and the screened Coulomb potential is developed. Based upon the $\hbar$-expansions and suitable…

Mathematical Physics · Physics 2007-12-13 I. V. Dobrovolska , R. S. Tutik

According to classical non-relativistic Schr\"odinger equation, any local perturbation of wave function instantaneously affects all infinite region, because this equation is of parabolic type, and its solutions demonstrate infinite speed of…

Quantum Physics · Physics 2012-02-08 Isaac Shnaid

We develop a modified semi-classical approach to the approximate solution of Schrodinger's equation for certain nonlinear quantum oscillations problems. At lowest order, the Hamilton-Jacobi equation of the conventional semi-classical…

Mathematical Physics · Physics 2015-06-03 Vincent Moncrief , Antonella Marini , Rachel Maitra

The wavefunction for the multiparticle Schr\"odinger equation is a function of many variables and satisfies an antisymmetry condition, so it is natural to approximate it as a sum of Slater determinants. Many current methods do so, but they…

Mathematical Physics · Physics 2009-11-13 Gregory Beylkin , Martin J. Mohlenkamp , Fernando Pérez

A new approach to find exact solutions to one--dimensional quantum mechanical systems is devised. The scheme is based on the introduction of a potential function for the wavefunction, and the equation it satisfies. We recover known…

Quantum Physics · Physics 2021-02-08 Sergio A. Hojman , Felipe A. Asenjo

We propose an extension of Wenzel-Kramers-Brillouin (WKB) approximation for solving the Schr\"odinger equation. A set of coupled differential equations is obtained by considering an ansatz of the wave function with an auxiliary condition on…

Quantum Physics · Physics 2025-04-01 Yu-An Tsai , Sheng D. Chao

We present a new method for the solution of the Schrodinger equation applicable to problems of non-perturbative nature. The method works by identifying three different scales in the problem, which then are treated independently: An…

Quantum Physics · Physics 2009-11-10 Paolo Amore , Alfredo Aranda , Arturo De Pace
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