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We give a detailed account of an $\it{ab}$ $\it{initio}$ spectral approach for the calculation of energy spectra of two active electron atoms in a system of hyperspherical coordinates. In this system of coordinates, the Hamiltonian has the…

A variationally improved Sturmian approximation for solving time-independent Schr\"odinger equation is developed. This approximation is used to obtain the energy levels of a quartic anharmonic oscillator, a quartic potential, and a Gaussian…

Quantum Physics · Physics 2009-11-07 Ali Mostafazadeh

The first discussion of basis sets consisting of exponentially decaying Coulomb Sturmian functions for modelling electronic structures is presented. The proposed basis set construction selects Coulomb Sturmian functions using separate upper…

Chemical Physics · Physics 2019-01-23 Michael F. Herbst , James Emil Avery , Andreas Dreuw

In this work we develop an approach to obtain analytical expressions for potentials in an impenetrable box. It is illustrated through the particular cases of the harmonic oscillator and the Coulomb potential. In this kind of system the…

High Energy Physics - Theory · Physics 2007-05-23 A. de Souza Dutra , V. G. C. S. dos Santos , A. M. Stuchi

We have developed a simple method to solve anharmonic oscillators equations. The idea of our method is mainly based on the partitioning of the potential curve into (n+1) small intervals, solving the Schr\"odinger equation in each…

Quantum Physics · Physics 2008-12-23 F. Maiz , M. Nasr

We introduce various optimization schemes for highly accurate calculation of the eigenvalues and the eigenfunctions of the one-dimensional anharmonic oscillators. We present several methods of analytically fixing the nonlinear variational…

Mathematical Physics · Physics 2012-12-07 Pouria Pedram

In the quantization scheme which weakens the hermiticity of a Hamiltonian to its mere PT invariance the superposition V(x) = x^2+ Ze^2/x of the harmonic and Coulomb potentials is defined at the purely imaginary effective charges (Ze^2=if)…

Mathematical Physics · Physics 2009-10-31 Miloslav Znojil

The quantum quartic anharmonic oscillator with the Hamiltonian $H=\frac{1}{2}\left( p^{2}+x^{2}\right) +\lambda x^{4}$ is a classical and fundamental model that plays a key role in various branches of physics, including quantum mechanics,…

Quantum Physics · Physics 2025-05-13 V. A. Babenko , A. V. Nesterov

The new perturbation theory for the problem of nonstationary anharmonic oscillator with polynomial nonstationary perturbation is proposed. As a zero order approximation the exact wave function of harmonic oscillator with variable frequency…

Quantum Physics · Physics 2016-09-08 Alexander V. Bogdanov , Ashot S. Gevorkyan

We propose a new analytical method to solve for the nonexactly solvable Schrodinger equation. Successfully, it is applied to a class of spiked harmonic oscillators and truncated Coulomb potentials. The utility of this method could be…

Mathematical Physics · Physics 2009-10-31 Omar Mustafa , Maen Odeh

Sturmian bound states emerging at a fixed energy and numbered by a complete set of real eigencouplings are considered. For Sturm-Schroedinger equations which are manifestly non-Hermitian we outline the way along which the correct…

Quantum Physics · Physics 2008-04-25 Miloslav Znojil

The explicit semiclassical treatment of the logarithmic perturbation theory for the bound-state problem for the spherical anharmonic oscillator and the screened Coulomb potential is developed. Based upon the $\hbar$-expansions and suitable…

Mathematical Physics · Physics 2007-12-13 I. V. Dobrovolska , R. S. Tutik

An exact analytical solution for the Bohr Hamiltonian with an energy dependent Coulomb-like $\gamma$-unstable potential is presented. Due to the linear energy dependence of the potential's coupling constant, the corresponding spectrum in…

Nuclear Theory · Physics 2016-10-18 R. Budaca

Harmonic calculations based on density-functional theory are generally the method of choice for the description of phonon spectra of metals and insulators. The inclusion of anharmonic effects is, however, delicate as it relies on…

Materials Science · Physics 2015-06-17 Ion Errea , Matteo Calandra , Francesco Mauri

In this paper, we describe a numerical continuation method that enables harmonic analysis of nonlinear periodic oscillators. This method is formulated as a boundary value problem that can be readily implemented by resorting to a standard…

Dynamical Systems · Mathematics 2015-05-19 Federico Bizzarri , Daniele Linaro , Bart Oldeman , Marco Storace

Assuming that a constant potential energy function has meaning for a dissipated harmonic oscillator, then an important issue is the time dependence of the turning points. Turning point studies demonstrate that the common model of external…

Classical Physics · Physics 2007-05-23 Randall D. Peters

The hyperspherical harmonic basis is used to describe bound states in an $A$--body system. The approach presented here is based on the representation of the potential energy in terms of hyperspherical harmonic functions. Using this…

Computational Physics · Physics 2009-05-13 M. Gattobigio , A. Kievsky , M. Viviani , P. Barletta

We introduce a new approach to deriving approximate analytical solutions of a harmonic oscillator damped by purely nonlinear, or combinations of linear and nonlinear damping forces. Our approach is based on choosing a suitable trial…

Classical Physics · Physics 2025-12-30 Karlo Lelas , Robert Pezer

We investigate the use of the sinc collocation and harmonic oscillator bases for solving a two-particle system bound by a Gaussian potential described by the radial Schr\"odinger equation. We analyze the properties of the bound state wave…

Nuclear Theory · Physics 2019-12-17 Mamoon Sharaf , Ryan McCarty , Robert A. M. Basili , James P. Vary

A new variational basis with well-behaved local approximation properties and multiple output is proposed for Coulomb systems. The trial function has proper behaviour at all Coulomb centres. Nonlinear asymptotic parameters are introduced…

Atomic Physics · Physics 2007-05-23 Vladimir S. Vanyashin
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