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We discuss a quantum effect in the diffusion process by developing a theory, which takes the finite curvature of the potential field into account. The transport coefficients of our theory satisfy the well-known fluctuation-dissipation…

Nuclear Theory · Physics 2009-11-10 Noboru Takigawa , Sakir Ayik , Kouhei Washiyama , Sachie Kimura

A quantum-mechanical Gaussian wave-packet approach to the theoretical description of nuclear motions in a condensed-phase environment is developed. General expressions for the time-dependent reduced density matrix are given for a harmonic…

Chemical Physics · Physics 2009-10-31 L. Muhlbacher , A. Lucke , R. Egger

We apply advanced methods of control theory to open quantum systems and we determine finite-time processes which are optimal with respect to thermodynamic performances. General properties and necessary conditions characterizing optimal…

Quantum Physics · Physics 2018-08-01 Vasco Cavina , Andrea Mari , Alberto Carlini , Vittorio Giovannetti

A novel method is introduced in order to treat the dissipative dynamics of quantum systems interacting with a bath of classical degrees of freedom. The method is based upon an extension of the Nos\`e-Hoover chain (constant temperature)…

Quantum Physics · Physics 2009-11-13 Alessandro Sergi

We investigate whether making the friction spatially dependent on the reaction coordinate introduces quantum effects into the thermal reaction rates for dissipative reactions. Quantum rates are calculated using the numerically exact…

A large number of multifaceted quantum transport processes in molecular systems and physical nanosystems can be treated in terms of quantum relaxation processes which couple to one or several fluctuating environments. A thermal equilibrium…

Statistical Mechanics · Physics 2007-05-23 Igor Goychuk , Peter Hanggi

The time-dependent energy transfer in a driven quantum system strongly coupled to a heat bath is studied within an influence functional approach. Exact formal expressions for the statistics of energy dissipation into the different channels…

Mesoscale and Nanoscale Physics · Physics 2016-06-20 Matteo Carrega , Paolo Solinas , Maura Sassetti , Ulrich Weiss

Except for the universe, all quantum systems are open, and according to quantum state diffusion theory, many systems localize to wave packets in the neighborhood of phase space points. This is due to decoherence from the interaction with…

Quantum Physics · Physics 2008-11-26 Todd A. Brun , Ian C. Percival , Rüdiger Schack

Many-body approaches to open quantum systems have recently become powerful tools for investigating the detailed role of dissipative environments in diverse non-equilibrium molecular and condensed matter processes. Here, we report the…

Mesoscale and Nanoscale Physics · Physics 2016-02-15 Florian A. Y. N. Schröder , Alex W. Chin

We introduce a time evolution algorithm for one-dimensional quantum field theories with periodic boundary conditions. This is done by applying the Dirac-Frenkel time-dependent variational principle to the set of translational invariant…

Quantum Physics · Physics 2017-02-08 Damian Draxler , Jutho Haegeman , Frank Verstraete , Matteo Rizzi

We have presented a simple approach to quantum theory of Brownian motion and barrier crossing dynamics. Based on an initial coherent state representation of bath oscillators and an equilibrium canonical distribution of quantum mechanical…

Quantum Physics · Physics 2009-11-07 Dhruba Banerjee , Bidhan Chandra Bag , Suman Kumar Banik , Deb Shankar Ray

The semiclassical Euclidean path integral method is applied to compute the low temperature quantum decay rate for a particle placed in the metastable minimum of a cubic potential in a {\it finite} time theory. The classical path, which…

Quantum Physics · Physics 2008-03-20 Marco Zoli

The path integral approach offers not only an exact expression for the non- equilibrium dynamics of dissipative quantum systems, but is also a convenient starting point for perturbative treatments. An alternative way to explore the…

Statistical Mechanics · Physics 2022-09-21 Joachim Ankerhold

Using the quasi-equilibrium Helmholtz energy (qHE), defined as the thermodynamic work in a quasi-static process, we investigate the thermal properties of both an isothermal process and a transition process between the adiabatic and…

Statistical Mechanics · Physics 2022-07-06 Shoki Koyanagi , Yoshitaka Tanimura

We study quantum annealing in the quantum Ising model coupled to a thermal environment. When the speed of quantum annealing is sufficiently slow, the system evolves following the instantaneous thermal equilibrium. This quasistatic and…

Quantum Physics · Physics 2022-05-09 Hiroki Oshiyama , Sei Suzuki , Naokazu Shibata

Time evolution of a perturbed thermal state is studied in a quantum-mechanical system with O(N) symmetry. In the limit of large N, time dependence of O(N)-singlet expectation values can be described by classical equations of motion in a…

Quantum Physics · Physics 2009-03-26 P. V. Buividovich

We study decoherence, diffusion, friction, and how they thermalize a planar rotor in the presence of an external potential. Representing the quantum master equation in terms of auxiliary Wigner functions in periodic phase space not only…

Quantum Physics · Physics 2025-04-30 Birthe Schrinski , Yoon Jun Chan , Björn Schrinski

The decay of quantum complex systems through a potential barrier is often described with transition-state theory, also known as RRKM theory in chemistry. Here we derive the basic formula for transition-state theory based on a generic…

Nuclear Theory · Physics 2024-04-02 K. Hagino , G. F. Bertsch

For the purpose of understanding the quantum behavior such as quantum decoherence, fluctuations, dissipation, entanglement and teleportation of a mesoscopic or macroscopic object interacting with a general environment, we derive here a set…

Quantum Physics · Physics 2007-12-09 Chung-Hsien Chou , B. L. Hu , Ting Yu

We show that strong parametric driving of a quantum harmonic oscillator coupled to a thermal bath allows one to distinguish between different microscopic models for the oscillator-bath coupling. We consider a bath with an Ohmic spectral…

Atomic Physics · Physics 2018-07-25 Anastasia S. D. Dietrich , Martin Kiffner , Dieter Jaksch