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We consider a multiatomic system where the nuclei are assumed to be point charges at fixed positions. Particles interact via Coulomb potential and electrons have pseudo-relativistic kinetic energy. We prove the van der Waals-London law,…

Mathematical Physics · Physics 2022-11-16 Jean-Marie Barbaroux , Michael Hartig , Dirk Hundertmark , Semjon Vugalter

We calculate the long-range Vanderwaals force and the photoelectric cross section in a \nc set up. While we argue that non-commutativity effects could not be discerned for the Vanderwaals interactions, the result for the photoelectric…

High Energy Physics - Phenomenology · Physics 2007-08-13 K. Li , N. Chamoun

A systematic study of the leading isotropic van der Waals coefficients for the alkali-metal atom + molecule and molecule + molecule systems is presented. Dipole moments and static and dynamic dipole polarizabilities are calculated employing…

Atomic Physics · Physics 2013-02-22 P. S. Zuchowski , M. Kosicki , M. Kodrycka , P. Soldan

Molecular-scale manipulation of electronic/ionic charge accumulation in materials is a preeminent challenge, particularly in electrochemical energy storage. Layered van der Waals (vdW) crystals exemplify a diverse family of materials that…

We studied the van der Waals interactions of two finite, solid, cylindrical rods at arbitrary angle and position with respect to each other. An analytic interpolative formula for the interaction potential energy is constructed, based on…

Soft Condensed Matter · Physics 2018-10-03 Jack A. Logan , Alexei V. Tkachenko

In principle, density functional theory yields the correct ground-state densities and energies of electronic systems under the action of a static external potential. However, traditional approximations fail to include Van der Waals energies…

Condensed Matter · Physics 2016-08-31 Walter Kohn , Yigal Meir , Dmitrii E. Makarov

We propose a practical approach to spin-polarized systems within the van der Waals density functional (vdW-DF). The method was applied to a gas phase oxygen molecule and a parallel (H-type) pair of oxygen molecules. It was found that vdW-DF…

Materials Science · Physics 2013-10-16 Masao Obata , Makoto Nakamura , Ikutaro Hamada , Tatsuki Oda

We use the master equation approach to calculate the energy level shifts of an atom in the presence of a general dielectric semi-infinite medium characterized by a dielectric constant $\epsilon(\omega)$. Particularly, we analyze the case of…

Quantum Physics · Physics 2007-05-23 T. N. C. Mendes , C. Farina

We study the electromagnetically induced transparency (EIT) effect with two individually addressed four-level Rydberg atoms subjected to the interatomic van der Waals interaction. We derive an effectively atomic Raman transition model where…

Quantum Physics · Physics 2014-10-15 Huaizhi Wu , Meng-Meng Bian , Li-Tuo Shen , Rong-Xin Chen , Zhen-Biao Yang , Shi-Biao Zheng

A quantum electrodynamic calculation of the interaction of an excited-state atom with a ground-state atom is performed. For an excited reference state and a lower-lying virtual state, the contribution to the interaction energy naturally…

Quantum Physics · Physics 2017-05-19 U. D. Jentschura , V. Debierre

While photons in free space barely interact, matter can mediate interactions between them resulting in optical nonlinearities. Such interactions at the single-quantum level result in an on-site photon repulsion, crucial for photon-based…

Mesoscale and Nanoscale Physics · Physics 2020-06-24 Weijie Li , Xin Lu , Sudipta Dubey , Luka Devenica , Ajit Srivastava

Dipolar relaxation happens when one or both colliding atoms flip their spins exothermically inside a magnetic ($B$) field. This work reports precise measurements of dipolar relaxation in a Bose-Einstein condensate of ground state $^{87}$Rb…

Quantum Gases · Physics 2021-01-28 Yuan-Gang Deng , Yi-Quan Zou , Gao-Ren Wang , Qi Liu , Su Yi , Meng Khoon Tey , Li You

We present a systematic study of interaction induced dipole electric properties of all molecular dimers in the S66 set, relying on CCSD(T)-F12b/aug-cc-pVDZ-F12 as reference level of theory. For field strengths up to $\approx$5 GV m$^{-1}$…

Chemical Physics · Physics 2021-12-22 Max Schwilk , Pál D. Mezei , Diana N. Tahchieva , O. Anatole von Lilienfeld

Van der Waals forces between atoms and molecules are universally assumed to act along the line separating them. Inspired by recent works on effects which can propel atoms parallel to a macroscopic surface via the Casimir--Polder force, we…

Quantum Physics · Physics 2020-09-03 Pablo Barcellona , Robert Bennett , Stefan Yoshi Buhmann

We study the interaction between a neutral atom or molecule and a conductor-patched dielectric surface. We model this system by a perfectly reflecting disc lying atop of a non-dispersive dielectric half-space, both interacting with the…

Quantum Physics · Physics 2015-06-11 Claudia Eberlein , Robert Zietal

The retarded dispersion interaction (Casimir interaction) between two dilute dielectric media at high temperatures is considered. The excited atoms are taken into account. It is shown that the perturbation technique can not be applied to…

Quantum Physics · Physics 2009-11-13 Yury Sherkunov

We study the repulsive van der Waals interaction of cold rubidium $70S_{1/2}$ Rydberg atoms by analysis of time-delayed pair correlation functions. After excitation, Rydberg atoms are allowed to accelerate under the influence of the van der…

Atomic Physics · Physics 2016-11-16 N. Thaicharoen , A. Schwarzkopf , G. Raithel

This article focuses on isomerizations of molecules, i.e. chemical reactions during which a molecule is transformed into another one with the same atoms in a different spatial configuration. We consider the special case in which the system…

Mathematical Physics · Physics 2023-03-15 Ioannis Anapolitanos , Marco Olivieri , Sylvain Zalczer

The damping coefficients for the alkali atoms are determined very accurately by taking into account the optical properties of the atoms and three distinct types of trapping materials such as Au (metal), Si (semi-conductor) and vitreous SiO2…

Atomic Physics · Physics 2015-06-17 Bindiya Arora , B. K. Sahoo

We consider the system of three ${}^4$He atoms to assess whether a pure van der Waals potential can be used as a starting point for an effective field theory to describe three-body processes in ultracold atomic systems. Using a long-range…

Quantum Gases · Physics 2021-08-11 Daniel Odell , Arnoldas Deltuva , Lucas Platter