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In this paper, unambiguous redefinitions of heat and work are presented for quantum thermodynamic systems. We will use genuine reasoning based on which Clausius originally defined work and heat in establishing thermodynamics. The change in…

Quantum Physics · Physics 2023-03-15 B. Ahmadi , S. Salimi , A. S. Khorashad

Accurately describing work extraction from a quantum system is a central objective for the extension of thermodynamics to individual quantum systems. The concepts of work and heat are surprisingly subtle when generalizations are made to…

Quantum Physics · Physics 2015-03-30 Felix C. Binder , Sai Vinjanampathy , Kavan Modi , John Goold

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

Originally formulated for macroscopic machines, the laws of thermodynamics were recently shown to hold for quantum systems coupled to ideal sources of work (external classical fields) and heat (systems at equilibrium). Ongoing efforts have…

Quantum Physics · Physics 2023-06-29 Cyril Elouard , Camille Lombard Latune

We investigate the connection between recent results in quantum thermodynamics and fluctuation relations by adopting a fully quantum mechanical description of thermodynamics. By including a work system whose energy is allowed to fluctuate,…

Quantum Physics · Physics 2017-03-27 Álvaro M. Alhambra , Lluis Masanes , Jonathan Oppenheim , Christopher Perry

The internal energy of individual subsystems is not well defined in interacting quantum systems, leading to ambiguities in the definition of thermodynamic quantities. Applying the Schmidt basis formalism to general bipartite autonomous…

Quantum Physics · Physics 2024-09-27 Fabricio Toscano , Diego A. Wisniacki

In bipartite quantum systems commutation relations between the Hamiltonian of each subsystem and the interaction impose fundamental constraints on the dynamics of each partition. Here we investigate work, heat and entropy production in…

Quantum Physics · Physics 2015-07-03 Hoda Hossein-Nejad , Edward J. O'Reilly , Alexandra Olaya-Castro

Underlying the classical thermodynamic principles are analogous microscopic laws, arising from the fundamental axioms of quantum mechanics. These define quantum thermodynamic variables such as quantum work and heat and characterize the…

Quantum Physics · Physics 2023-05-03 Roie Dann , Ronnie Kosloff

Assigning the variations of internal energy into heat or work contributions is a challenging task due to the fact that these properties are trajectory dependent. A number of proposals have been put forward for open quantum systems following…

Quantum Physics · Physics 2021-09-01 Adrián Juan-Delgado , Aurélia Chenu

We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

Quantum Physics · Physics 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

The first law of thermodynamics restates the law of conservation of energy. It partitions the change in energy of a system into two pieces, heat and work. While there is no ambiguity to define heat and work in classical thermodynamics,…

Quantum Physics · Physics 2023-01-19 Xue-Qun Yan , Yan-Jiao Du , Wen-Tao Hou , Xiao-Ming Liu

The development of a self-consistent thermodynamic theory of quantum systems is of fundamental importance for modern physics. Still, despite its essential role in quantum science and technology, there is no unifying formalism for…

Quantum Physics · Physics 2022-11-30 André Malavazi , Frederico Brito

In quantum thermodynamics, the decomposition of energy exchanges into heat and work remains an open problem beyond weak-coupling and slow-driving regimes. Recent formulations have shown that quantum coherence introduces additional energy…

Quantum Physics · Physics 2026-05-20 Mario Reis , Maron F. Anka , Vinicius Gomes de Paula , Clebson Cruz

Thermodynamics of a three-level maser was studied in the pioneering work of Scovil and Schulz-DuBois [Phys. Rev. Lett. 2, 262 (1959)]. In this work we consider the same three-level model, but treat both the matter and light quantum…

Quantum Physics · Physics 2007-05-23 E. Boukobza D. J. Tannor

How to rigorously define thermodynamic quantities such as heat, work, and internal energy in open quantum systems driven far from equilibrium remains a significant open question in quantum thermodynamics. Heat is a quantity whose…

Mesoscale and Nanoscale Physics · Physics 2023-07-18 Parth Kumar , Charles A. Stafford

We provide a characterization of energy in the form of exchanged heat and work between two interacting constituents of a closed, bipartite, correlated quantum system. By defining a binding energy we derive a consistent quantum formulation…

Quantum Physics · Physics 2016-10-25 S. Alipour , F. Benatti , F. Bakhshinezhad , M. Afsary , S. Marcantoni , A. T. Rezakhani

In this work, we investigate the heat flow of two interacting quantum systems on the perspective of noncommutativity phase-space effects and show that by controlling the new constants introduced in the quantum theory, due to a deformed…

Quantum Physics · Physics 2020-12-25 Jonas F. G. Santos

We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal, but have an amount of coherence proportional to a…

Materials that are constantly driven out of thermodynamic equilibrium, such as active and living systems, typically violate the Einstein relation. This may arise from active contributions to particle fluctuations which are unrelated to the…

Statistical Mechanics · Physics 2025-01-07 Benjamin Sorkin , Haim Diamant , Gil Ariel , Tomer Markovich

Building on parallels between geometric quantum mechanics and classical mechanics, we explore an alternative basis for quantum thermodynamics that exploits the differential geometry of the underlying state space. We develop both…

Quantum Physics · Physics 2024-03-13 Fabio Anza , James P. Crutchfield
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