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We present a combined analytical and numerical investigation to show how an optimal control field can be designed to generate maximum field-free orientation of molecules for three populated rotational states. Based on a model involving pure…

Quantum Physics · Physics 2021-07-28 Qian-Qian Hong , Li-Bao Fan , Chuan-Cun Shu , Niels E. Henriksen

We study the control by electromagnetic fields of molecular alignment and orientation, in a linear, rigid rotor model. With the help of a monotonically convergent algorithm, we find that the optimal field is in the microwave part of the…

Chemical Physics · Physics 2007-05-23 Julien Salomon , Claude M. Dion , Gabriel Turinici

A three-dimensional semiclassical model is used to study double ionization of Ar when driven by a near-infrared and near-single-cycle laser pulse for intensities ranging from 0.85$\times$10$^{14}$ W/cm$^{2}$ to 5$\times$10$^{14}$…

Atomic Physics · Physics 2017-02-15 A. Chen , M. Kübel , B. Bergues , M. F. Kling , A. Emmanouilidou

We analyze the alignment of molecules generated by a pair of crossed ultra-short pump pulses of different polarizations by a technique based on the induced time-dependent gratings. Parallel polarizations yield an intensity grating, while…

Quantum Physics · Physics 2009-11-13 Arnaud Rouzee , Vincent Renard , Stephane Guerin , Olivier Faucher , Bruno Lavorel

Molecules with their axes sharply confined in space, available through laser-induced alignment methods, are essential for many current experiments, including ultrafast molecular imaging. Most of these applications require both that the…

The alternative to dynamic alignment explanation of experimental results on spatial-asymmetric dissociation of molecules in a laser field is proposed. The concept of geometrical alignment is sufficient for explanation of these results. In…

Optics · Physics 2007-05-23 V. A. Kuz'menko

Laser cooling of molecules employing broadband optical pumping involves a timescale separation between laser excitation and spontaneous emission. Here, we optimize the optical pumping step using shaped laser pulses. We derive two…

Quantum Physics · Physics 2013-12-24 Daniel M. Reich , Christiane P. Koch

We report experiments on field-free molecular alignment performed at FLASH, the free electron laser (FEL) in Hamburg. The impulsive alignment induced by a 100 fs near-infrared laser pulse in a rotationally cold CO_2 sample is characterized…

We make use of an inhomogeneous electrostatic dipole field to impart a quantum-state-dependent deflection to a pulsed beam of OCS molecules, and show that those molecules residing in the absolute ground state, $X ^1\Sigma^+$, $\ket{00^00}$,…

In the present paper, we develop a semiclassical quasi-static model accounting for molecular double ionization in an intense laser pulse. With this model, we achieve insight into the dynamics of two highly-correlated valence electrons under…

Atomic and Molecular Clusters · Physics 2009-11-13 Di-Fa Ye , Jing Chen , Jie Liu

We explore the possibility of forming a oriented polar molecule directly from a pair of colliding atoms. The process comprises the photoassociation and vibrational stabilization along with the molecular orientation. These processes are…

Quantum Physics · Physics 2026-01-14 Murilo D. Forlevesi , Edson Denis Leonel , Emanuel F. de Lima

We demonstrate experimentally a method of all-optical selective rotational control in gas mixtures. Using an optical centrifuge - an intense laser pulse whose linear polarization rotates at an accelerated rate, we simultaneously excite two…

Chemical Physics · Physics 2024-06-19 P. Amani , A. A. Milner , V. Milner

Few-cycle pulses of intense 800 nm light are used to probe ionization and dissociation of carbon disulfide in the intensity and temporal regime where rescattering is expected to dominate the laser-molecule interaction. The wavepacket of the…

We extend the semiclassical two-step model for strong-field ionization that describes quantum interference and accounts for the Coulomb potential beyond the semiclassical perturbation theory to the hydrogen molecule. In the simplest case of…

Atomic Physics · Physics 2019-03-27 N. I. Shvetsov-Shilovski , M. Lein , K. Tőkési

By analysis and simulation we demonstrate two methods for achieving complete orientational alignment of a set of identical, asymmetric colloidal objects dispersed randomly in a fluid. Sedimentation or electrophoresis in a constant field can…

Soft Condensed Matter · Physics 2014-03-18 Brian Moths , T. A. Witten

Precise control of the electron phase accumulated during its sub-cycle motion within intense laser fields is essential in strong-field physics, yet remains mostly indirect and complicated so far. In this Letter, we develop a novel approach…

Fixing molecules in space is a crucial step for the imaging of molecular structure and dynamics. Here, we demonstrate three-dimensional (3D) field-free alignment of the prototypical asymmetric top molecule indole using elliptically…

We provide a detailed theoretical analysis of molecular rotational excitation by a chiral pulse train -- a sequence of linearly polarised pulses with the polarisation direction rotating from pulse to pulse by a controllable angle. Molecular…

Quantum Physics · Physics 2013-05-30 Johannes Floß , Ilya Sh. Averbukh

Since its invention in 1999, optical centrifuge has become a powerful tool for controlling molecular rotation and studying molecular dynamics and molecular properties at extreme levels of rotational excitation. The technique has been…

Instrumentation and Detectors · Physics 2020-05-20 Ian MacPhail-Bartley , Walter W. Wasserman , Alexander A. Milner , V. Milner

We report our investigation on ultrashort laser pulse optimization using an AI algorithm in a system consisting of a mode-locked oscillator, a spectral phase shaper, and a highly nonlinear amplifier. We analyzed the performance of the pulse…

Optics · Physics 2024-01-02 Mikołaj Krakowski , Alicja Kwaśny , Grzegorz Soboń
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