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We give a theoretical treatment of the interaction of electronic excitations (excitons) in biomolecules and quantum dots with the surrounding polar solvent. Significant quantum decoherence occurs due to the interaction of the electric…

Soft Condensed Matter · Physics 2009-11-10 Joel Gilmore , Ross H. McKenzie

F\"orster's theory of resonant energy transfer (FRET) predicts the strength and range of exciton transport between separated molecules. We introduce an exactly soluble model for FRET which reproduces F\"orster's results as well as…

Mesoscale and Nanoscale Physics · Physics 2012-03-09 C. King , B. Barbiellini , D. Moser , V. Renugopalakrishnan

The mechanisms of energy and spin transfer in quantum dot pairs coupled via the Coulomb interaction are studied. Exciton transfer can be resonant or phonon-assisted. In both cases, the transfer rates strongly depend on the resonance…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Alexander O. Govorov

Resonant energy transfers, i.e. the non-radiative redistribution of an electronic excitation between two particles coupled by the dipole-dipole interaction, lie at the heart of a variety of chemical and biological phenomena, most notably…

Resonance energy transfer has become an indispensable experimental tool for single-molecule and single-cell biophysics. Its physical underpinnings, however, are subtle: It involves a discrete jump of excitation from one molecule to another,…

Biomolecules · Quantitative Biology 2018-09-18 Philip C. Nelson

We present a theoretical analysis of exciton transfer and decoherence effects in a photosynthetic dimer interacting with collective (correlated) and local (uncorrelated) protein-solvent environments. Our approach is based on the framework…

Quantum Physics · Physics 2015-12-31 M. Merkli , G. P. Berman , R. T. Sayre , S. Gnanakaran , M. Könenberg , A. I. Nesterov , H. Song

The conversion of an absorbed photon from the exciton energy into the reaction centre in the photosynthetic complex has a near unit efficiency. It is becoming clear that any classical model, where the exciton hopping is modeled by a…

Quantum Physics · Physics 2010-06-21 Vlatko Vedral , Tristan Farrow

A numerically exact path integral treatment of the absorption and emission spectra of open quantum systems is presented that requires only the straightforward solution of a stochastic differential equation. The approach converges rapidly…

Chemical Physics · Physics 2015-05-05 Jeremy Moix , Jian Ma , Jianshu Cao

We study transfer of coherent nuclear oscillations between an excitation energy donor and an acceptor in a simple dimeric electronic system coupled to an unstructured thermodynamic bath and some pronounced vibrational intramolecular mode.…

Chemical Physics · Physics 2015-01-08 Tomáš Mančal , Jakub Dostál , Jakub Pšenčík , Donatas Zigmantas

We explore the dynamics of energy transfer between two nanocrystal quantum dots placed within an optical microcavity. By adjusting the coupling strength between the cavity photon mode and the quantum dots, we have the capacity to fine-tune…

Mesoscale and Nanoscale Physics · Physics 2024-10-02 Kaiyue Peng , Eran Rabani

We consider a spin-boson model in which a spin 1 system is coupled to an oscillator. A unitary transformation is applied which allows a separation of terms responsible for the Bloch-Siegert shift, and terms responsible for the level…

Quantum Physics · Physics 2009-11-13 Peter L. Hagelstein , Irfan U. Chaudhary

Central spin decoherence is useful for detecting many-body physics in environments and moreover, the spin echo control can remove the effects of static thermal fluctuations so that the quantum fluctuations are revealed. The central spin…

Mesoscale and Nanoscale Physics · Physics 2014-04-17 Shao-Wen Chen , Ren-Bao Liu

In this paper, we present a theoretical description to the quantum coherence and decoherence phenomena of energy transfer in photosynthesis observed in a recent experiment [see Science 316, 1462 (2007)]. As a successive two-color laser…

Quantum Physics · Physics 2010-01-28 Xian-Ting Liang , Wei-Min Zhang , Yi-Zhong Zhuo

Using detailed balance and scaling properties of integrals that appear in the Coulomb gas reformulation of quantum impurity problems, we establish exact relations between the nonequilibrium transfer rates of the boundary sine-Gordon and the…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Holger Baur , Andrea Fubini , Ulrich Weiss

The Forster resonant energy transfer mechanism (FRET) is investigated in optically driven and electrically gated tunnel coupled quantum dot molecules. Two novel FRET induced optical signatures are found in the dressed excitonic spectrum.…

Mesoscale and Nanoscale Physics · Physics 2009-06-18 Juan E. Rolon , Sergio E. Ulloa

We study the nature of the energy transfer process within a pair of coupled two-level systems (donor and acceptor) subject to interactions with the surrounding environment. Going beyond a standard weak-coupling approach, we derive a master…

Quantum Physics · Physics 2011-04-05 Dara P. S. McCutcheon , Ahsan Nazir

We consider a generalization of the spin-boson model in which two different two-level systems are coupled to an oscillator, under conditions where the oscillator energy is much less than the two-level system energies, and where the…

Quantum Physics · Physics 2009-11-13 Peter L. Hagelstein , Irfan U. Chaudhary

We show that the quantum coherent transfer of excitations between biomolecular chromophores is strongly influenced by spatial correlations of the environmental fluctuations. The latter are due either to propagating environmental modes or to…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 P. Nalbach , J. Eckel , M. Thorwart

Photosynthetic proteins have evolved over billions of years so as to undergo optimal energy transfer to the sites of charge separation. Based on spectroscopically detected quantum coherences, it has been suggested that this energy transfer…

Chemical Physics · Physics 2016-07-13 David Paleček , Petra Edlund , Sebastian Westenhoff , Donatas Zigmantas

The coherent control of a two-level system is among the most essential challenges in modern quantum optics. Understanding its fundamental limitations is crucial, also for the realization of next generation quantum devices. The quantum…

Quantum Physics · Physics 2023-12-19 Michael K. Koch , Vibhav Bharadwaj , Alexander Kubanek
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