Related papers: Semiclassical Propagation of Wavepackets with Real…
We develop a semiclassical framework for studying quantum particles constrained to curved surfaces using the momentous quantum mechanics formalism, which extends classical phase-space to include quantum fluctuation variables (moments). In a…
Quantum mechanical real-time tunneling through general scattering potentials is studied in the semiclassical limit. It is shown that the exact path integral of the real-time propagator is dominated in the long time sector by…
The semiclassical approximation for electron wave-packets in crystals leads to equations which can be derived from a Lagrangian or, under suitable regularity conditions, in a Hamiltonian framework. In the plane, these issues are studied %in…
We present a new semiclassical method that yields an approximation to the quantum mechanical wavefunction at a fixed, predetermined position. In the approach, a hierarchy of ODEs are solved along a trajectory with zero velocity. The new…
We discuss "the plane wave approximation" to quantum mechanical scattering using simple one-dimensional examples. The central points of the paper are that (a) plane waves should be thought of as infinitely wide wave packets, and (b) the…
We analyze the semiclassical evolution of Gaussian wavepackets in chaotic systems. We prove that after some short time a Gaussian wavepacket becomes a primitive WKB state. From then on, the state can be propagated using the standard TDWKB…
Trajectories are a central concept in our understanding of classical phenomena and also in rationalizing quantum mechanical effects. In this work we provide a way to determine semiclassical paths, approximations to quantum averages in phase…
Unbound wave packets propagating to macroscopic space and time coordinates become proportional to their (Fourier transform) momentum distribution at earlier times whereby the asymptotic coordinates and the initial momenta are connected…
The semiclassical long-time limit of free evolution of quantum wave packets on the torus is under consideration. Despite of simplicity of this system, there are still open questions concerning the detailed description of the evolution on…
It is well known that the Gaussian wave packet dynamics can be written in terms of Hamilton equations in the extended phase space that is twice as large as in the corresponding classical system. We construct several generalizations of this…
We present an analytical closed form expression, which gives a good approximate propagator for diffusion on the sphere. Our formula is the spherical counterpart of the Gaussian propagator for diffusion on the plane. While the analytical…
A semiclassical approximation is derived by using a family of wavepackets to map arbitrary wavefunctions into phase space. If the Hamiltonian can be approximated as linear over each individual wavepacket, as often done when presenting…
Semiclassical approximation based on extracting a c-number classical component from quantum field is widely used in the quantum field theory. Semiclassical states are considered then as Gaussian wave packets in the functional Schrodinger…
We review some recent results obtained for the time evolution of wave packets for systems of equations of pseudo-differential type, including Schr{\"o}dinger ones, and discuss their application to the approximation of the associated unitary…
To alleviate the computational cost associated with on-the-fly ab initio semiclassical calculations of molecular spectra, we propose the single-Hessian thawed Gaussian approximation, in which the Hessian of the potential energy at all…
An initial coherent state is propagated exactly by a kicked quantum Hamiltonian and its associated classical stroboscopic map. The classical trajectories within the initial state are regular for low kicking strengths, then bifurcate and…
Evaluation of symmetry-forbidden or weakly-allowed vibronic spectra requires treating the transition dipole moment beyond the Condon approximation. To include vibronic spectral features not captured in the global harmonic models, we have…
A nonreflecting wavepacket is constructed by the superposition of reflectionless eigenstates of sech2 potential. Free propagation and propagation in the presence of the above potential of such a wavepacket is considered using the concept of…
Simulations are made of a probe particle diffusing through a complex fluid. Probe particle motions are described by the Mori-Zwanzig equation and Mori's orthogonal hierarchy of random forces scheme, subject to the approximation that the…
We consider the quantum mechanical propagator for a particle moving in a $d$-dimensional Lorentz gas, with fixed, hard sphere scatterers. To evaluate this propagator in the semi-classical region, and for times less than the Ehrenfest time,…