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Fundamental entanglement related challenges have prevented quantum interference-based control (i.e. coherent control) of collisional cross sections from being implemented in the laboratory. Here, differential cross sections for reactive…

Chemical Physics · Physics 2020-10-07 Adrien Devolder , Timur Tscherbul , Paul Brumer

We consider the coherent control of ultracold molecule-molecule scattering, impacted by a dense set of rovibrational resonances. To characterize the resonance spectrum, a rudimentary model based on multichannel quantum defect theory has…

Atomic Physics · Physics 2023-01-18 Adrien Devolder , Timur V. Tscherbul , Paul Brumer

We show that quantum interference-based coherent control is a highly efficient tool for tuning ultracold molecular collision dynamics, and is free from the limitations of commonly used methods that rely on external electromagnetic fields.…

Atomic Physics · Physics 2021-04-21 Adrien Devolder , Paul Brumer , Timur V. Tscherbul

Full-dimensional quantum scattering calculations are reported for ro-vibrational transitions in HD+HD collisions using a highly accurate interaction potential for the H$_2$-H$_2$ system. Several near-resonant ro-vibrational transitions are…

Atomic Physics · Physics 2026-03-06 Bikramaditya Mandal , Hubert Jóźwiak , Piotr Wcisło , Naduvalath Balakrishnan

Cold collisions of light molecules are often dominated by a single partial wave resonance. For the rotational quenching of HD(v=1,j=2) by collisions with ground state para-H2, the process is dominated by a single L=2 partial wave resonance…

Stereodynamics of cold collisions has become a fertile ground for quantized studies of molecular collisions and control of the collision outcome. A benchmark process for stereodynamic control is rotational transition in He+HD collisions.…

Chemical Physics · Physics 2020-09-04 Masato Morita , Naduvalath Balakrishnan

Quantum control of molecular collision dynamics is an exciting emerging area of cold collisions. Co-expansion of collision partners in a supersonic molecular beam combined with precise control of their quantum states and…

Chemical Physics · Physics 2021-09-29 Pablo G. Jambrina , James F. E. Croft , Naduvalath Balakrishnan , F. Javier Aoiz

Quantum reactive scattering calculations on the vibrational quenching of HD due to collisions with H were carried out employing an accurate potential energy surface. The state-to-state cross sections for the chemical reaction HD ($v=1, \…

Chemical Physics · Physics 2020-06-19 Boyi Zhou , Benhui Yang , N. Balakrishnan , B. K. Kendrick , P. C. Stancil

A scattering resonance is one of the most striking quantum effects in low-temperature molecular collisions. Predicted decades ago theoretically, they have only been resolved experimentally for systems involving at most four atoms. Extension…

We present an efficient method for rigorous quantum calculations of cross sections for atom-molecule reactive scattering in the presence of a dc electric field. The wavefunction of the reaction complex is expanded in an overcomplete set of…

Chemical Physics · Physics 2026-05-07 Timur V. Tscherbul , Roman V. Krems

Interference is widely regarded as a foundational attribute of quantum mechanics. However, for a given experimental arrangement, interference can either contribute or not contribute to the outcome depending upon the basis in which it is…

Atomic Physics · Physics 2024-02-08 Adrien Devolder , Timur V. Tscherbul , Paul Brumer

Intriguing quantum effects that result from entangled molecular rovibrational states are shown to provide a novel means for controlling both differential and total collision cross sections in identical particle diatom-diatom scattering.…

Quantum Physics · Physics 2009-11-07 Jiangbin Gong , Moshe Shapiro , Paul Brumer

Conventional approaches for controlling open quantum systems use coherent control which affects the system's evolution through the Hamiltonian part of the dynamics. Such control, although being extremely efficient for a large variety of…

Quantum Physics · Physics 2009-05-04 Alexander Pechen , Herschel Rabitz

The coherent control of scattering processes is considered, with electron impact dissociation of H$_2^+$ used as an example. The physical mechanism underlying coherently controlled stationary state scattering is exposed by analyzing a…

Quantum Physics · Physics 2009-11-13 Michael Spanner , Paul Brumer

Quantum coherent control (1-3) is a powerful tool for steering the outcome of quantum processes towards a desired final state, by accurate manipulation of quantum interference between multiple pathways. Although coherent control techniques…

Atomic Physics · Physics 2013-01-22 Itan Barmes , Stefan Witte , Kjeld S. E. Eikema

Coherent controlization, i.e., coherent conditioning of arbitrary single- or multi-qubit operations on the state of one or more control qubits, is an important ingredient for the flexible implementation of many algorithms in quantum…

Quantum Physics · Physics 2015-12-16 Nicolai Friis , Alexey A. Melnikov , Gerhard Kirchmair , Hans J. Briegel

The results of accurate quantum reactive scattering calculations for the D + HD($v=4$, $j=0$) $\to$ D + HD($v'$, $j'$), D + HD($v=4$, $j=0$) $\to$ H + D$_2$($v'$, $j'$) and H + D$_2$($v=4$, $j=0$) $\to$ D + HD($v'$,$j'$) reactions are…

Chemical Physics · Physics 2017-01-04 Brian K. Kendrick , Jisha Hazra , N. Balakrishnan

We describe optimized coherent control methods for two-photon transitions in atoms of a ladder-type three-state energy configuration. Our approach is based on the spatial coherent control scheme which utilizes counter-propagating ultrashort…

Atomic Physics · Physics 2015-10-28 Woojun Lee , Hyosub Kim , Kyungtae Kim , Jaewook Ahn

In this study, we achieved magnetic control of reactive scattering in an ultracold mixture of $^{23}$Na atoms and $^{23}$Na$^{6}$Li molecules. In most molecular collisions, particles react or are lost near short range with unity…

Atomic Physics · Physics 2022-03-14 Hyungmok Son , Juliana J. Park , Yu-Kun Lu , Alan O. Jamison , Tijs Karman , Wolfgang Ketterle

Quantum reactive scattering calculations for the hydrogen exchange reaction H + H$_2$($v=4$, $j=0$) $\to$ H + H$_2$($v'$, $j'$) and its isotopic analogues are reported for ultracold collision energies. Due to the unique properties…

Chemical Physics · Physics 2015-10-14 Brian K. Kendrick , Jisha Hazra , Naduvalath Balakrishnan
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