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Despite its enormous empirical success, the formalism of quantum theory still raises fundamental questions: why is nature described in terms of complex Hilbert spaces, and what modifications of it could we reasonably expect to find in some…

Quantum Physics · Physics 2017-04-27 Marius Krumm , Howard Barnum , Jonathan Barrett , Markus P. Mueller

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

Recently David Jennings and Terry Rudolph published two papers as reaction on Maccone's paper "Quantum Solution to the Arrow-of-Time Dilemma". In these papers, the authors suppose that second law of thermodynamics is not relevant for…

Quantum Physics · Physics 2013-05-01 Oleg Kupervasser

In statistical mechanics the zeroth law of thermodynamics is taken as a postulate which, as its name indicates, logically precedes the first and second laws. Treating it as a postulate has consequences for how temperature is introduced into…

Statistical Mechanics · Physics 2025-02-11 Kim Sharp

Examining textbooks of thermodynamics we have not able to find a proof of increasing of entropy under free adiabatic expansion in vacuum based on the state equation of the Van der Waals gas. This communication remedies the situation. During…

Fluid Dynamics · Physics 2007-05-23 Yury A. Koksharov

We propose a new formulation of stochastic thermodynamics for systems subjected to nonequilibrium constraints (i.e. broken detailed balance at steady state) and furthermore driven by external time-dependent forces. A splitting of the second…

Statistical Mechanics · Physics 2015-05-18 Massimiliano Esposito , Christian Van den Broeck

The origins of thermodynamics from the microscopic properties of matter have not been satisfactorily accounted for. This work presents a formulation that connects Lagrangian mechanics to thermodynamics. By using such a formulation and…

Atomic and Molecular Clusters · Physics 2021-04-05 Eduardo Hernández-Huerta , Ruben Santamaria , Tomás Rocha Rinza

A review is given on the thermodynamical structure of bipartite entanglement. By comparing it to the axiomatic formulation of thermodynamics presented by Giles it is shown that for finite dimensional systems the two theories are formally…

Quantum Physics · Physics 2016-04-11 Nikolaos K. Kollas

Materials that are constantly driven out of thermodynamic equilibrium, such as active and living systems, typically violate the Einstein relation. This may arise from active contributions to particle fluctuations which are unrelated to the…

Statistical Mechanics · Physics 2025-01-07 Benjamin Sorkin , Haim Diamant , Gil Ariel , Tomer Markovich

It has long been known that, fundamentally different from a large body of rarefied gas, when a Knudsen gas is immersed in a thermal bath, it may never reach thermal equilibrium. The root cause is nonchaoticity: as the particle-particle…

Statistical Mechanics · Physics 2024-11-15 Yu Qiao , Zhaoru Shang

Uncertainty relations state that there exist certain incompatible measurements, to which the outcomes cannot be simultaneously predicted. While the exact incompatibility of quantum measurements dictated by such uncertainty relations can be…

Quantum Physics · Physics 2015-06-05 Esther Hänggi , Stephanie Wehner

Quantum thermodynamics investigates how robust the second law of thermodynamics serves as the unique fundamental law in the small quantum world. To tackle this problem, the quantum coherence constitutes a major difficulty of investigations,…

Quantum Physics · Physics 2025-10-08 Naoto Shiraishi , Ryuji Takagi

From the principle of maximum entropy for a closed system in thermal equilibrium, for the first instance a clear relation is shown to exist between total entropy S (in terms of arrangements of particles) and the classical expression for the…

Classical Physics · Physics 2009-11-07 Mario J. Pinheiro

All presently available results lead to the conclusion that nonextensivity, in the sense of nonextensive statistical mechanics (i.e., $q \ne 1$), does {\it not} modify anything to the second principle of thermodynamics, which therefore…

Statistical Mechanics · Physics 2017-08-23 Constantino Tsallis

The purpose of this note is to see to what extent ideal gas laws can be obtained from simple Newtonian mechanics, specifically elastic collisions. We present simple one-dimensional situations that seem to validate the laws. The first…

Classical Physics · Physics 2013-05-30 Stephen Montgomery-Smith , Hannah Morgan

We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…

Quantum Physics · Physics 2009-11-13 Qi-Ren Zhang

Even after over 150 years of discussion, the interpretation of the second law of thermodynamics continues to be a source of confusion and controversy in physics. This confusion has been accentuated by recent challenges to the second law and…

Statistical Mechanics · Physics 2015-06-24 T. Duncan , J. Semura

To address the observation of Max Born (M. Born 1969) that the Newton's second law can emerge from a purely statistical perspective, we derive the evolution equation about the statistical distribution for dilute gas based solely on…

Statistical Mechanics · Physics 2024-10-23 Hong Yuan , Chang-Pu Sun

The first in a long series of papers by John T. Lewis, G. W. Ford and the present author, considered the problem of the most general coupling of a quantum particle to a linear passive heat bath, in the course of which they derived an exact…

Quantum Physics · Physics 2016-09-08 R. F. O'Connell

An apparent violation of the second law of thermodynamics occurs when an atom coupled to a zero-temperature bath, being necessarily in an excited state, is used to extract work from the bath. Here the fallacy is that it takes work to couple…

Quantum Physics · Physics 2009-11-13 G. W. Ford , R. F. O'Connell
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