Related papers: Analytic calculation of nonadiabatic transition pr…
On-the-fly quantum nonadiabatic dynamics for large systems greatly benefits from the adiabatic representation readily available from the electronic structure programs. However, frequently occurring in this representation conical…
Adiabatic processes driven by non-Hermitian, time-dependent Hamiltonians may be sped up by generalizing inverse engineering techniques based on Berry's transitionless driving algorithm or on dynamical invariants. We work out the basic…
We consider nonadiabatic transitions in explicitly time-dependent systems with Hamiltonians of the form $\hat{H}(t) = \hat{A} +\hat{B} t + \hat{C}/t$, where $t$ is time and $\hat{A}$, $\hat{B}$, $\hat{C}$ are Hermitian $N\times N$ matrices.…
We obtain the exact expression for the matrix of nonadiabatic transition probabilities in the model of three interacting states with a time-dependent Hamiltonian. Unlike other known solvable Landau-Zener-like problems, our solution is…
Exceptional points, at which two or more eigenfunctions of a Hamiltonian coalesce, occur in non-Hermitian systems and lead to surprising physical effects. In particular, the behaviour of a system under parameter variation can differ…
Transition probabilities for a class of two level systems described by explicitly time dependent Hamiltonians are considered. Provided only that the approach to the infinite time limit is non-trivial falling at least as fast as 1/t for…
A class of surface hopping algorithms is studied comparing two recent Landau-Zener (LZ) formulas for the probability of nonadiabatic transitions. One of the formulas requires a diabatic representation of the potential matrix while the other…
We explore nonadiabatic quantum phase transitions in an Ising spin chain with a linearly time-dependent transverse field and two different spins per unit cell. Such a spin system passes through critical points with gapless excitations,…
We examine the effect of nonlinearity at a level crossing on the probability for nonadiabatic transitions $P$. By using the Dykhne-Davis-Pechukas formula, we derive simple analytic estimates for $P$ for two types of nonlinear crossings. In…
The process of phase separation of binary systems is described by the Cahn-Hilliard equation. The main objective of this article is to give a classification on the dynamic phase transitions for binary systems using either the classical…
We study quantum dynamics of Grover's adiabatic search algorithm with the equivalent two-level system. Its adiabatic and non-adiabatic evolutions are visualized as trajectories of Bloch vectors on a Bloch sphere. We find the change in the…
The quantum adiabatic theorem incorporating the Berry phase phenomenon can be characterized as a factorization of the time evolution operator into a path-dependent geometric factor, a usual dynamical factor and a non-adiabatic factor that…
While it is well-known that every nearly-periodic Hamiltonian system possesses an adiabatic invariant, extant methods for computing terms in the adiabatic invariant series are inefficient. The most popular method involves the heavy…
We derive a time-dependent master equation for an externally driven system whose subsystems weakly interact with each other and locally connect to the thermal reservoirs. The nonadiabatic equation obtained here can be viewed as a…
We revisit the adiabatic criterion in stimulated Raman adiabatic passage for the three-level $\Lambda$-system, and compare the situation with and without nonlinearity. In linear systems, the adiabatic condition is derived with the help of…
Changes of type transitions for the two-component hydrodynamic type systems are discussed. It is shown that these systems generically assume the Jordan form (with 2 X 2 Jordan block) on the transition line with hodograph equations becoming…
At present, several models for quantum computation have been proposed. Adiabatic quantum computation scheme particularly offers this possibility and is based on a slow enough time evolution of the system, where no transitions take place. In…
We discuss the energetic cost of superadiabatic models of quantum computation. Specifically, we investigate the energy-time complementarity in general transitionless controlled evolutions and in shortcuts to the adiabatic quantum search…
Rare nonadiabatic reactions are a key component of many important molecular processes but are challenging to capture with direct dynamical simulations. In this paper, we combine our recently developed mapping approach to surface hopping…
The anomalous dynamical evolution and the crossing of nonadiabatic energy levels are investigated for exactly solvable time-dependent quantum systems through a reverse-engineering scheme. By exploiting a typical driven model, we elucidate…