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Variational algorithms for strongly correlated chemical and materials systems are one of the most promising applications of near-term quantum computers. We present an extension to the variational quantum eigensolver that approximates the…

Quantum Physics · Physics 2020-08-26 William J. Huggins , Joonho Lee , Unpil Baek , Bryan O'Gorman , K. Birgitta Whaley

Estimating the overlap between an approximate wavefunction and a target eigenstate of the system Hamiltonian is essential for the efficiency of quantum phase estimation. In this work, we derive upper and lower bounds on this overlap using…

Quantum Physics · Physics 2025-03-18 Junan Lin , Artur F. Izmaylov

The bound state wave functions for a wide class of exactly solvable potentials are found utilizing the quantum Hamilton-Jacobi formalism. It is shown that, exploiting the singularity structure of the quantum momentum function, until now…

Quantum Physics · Physics 2009-11-07 S. Sree Ranjani , K. G. Geojo , A. K. Kapoor , P. K. Panigrahi

We discuss classical algorithms for approximating the largest eigenvalue of quantum spin and fermionic Hamiltonians based on semidefinite programming relaxation methods. First, we consider traceless $2$-local Hamiltonians $H$ describing a…

Quantum Physics · Physics 2019-10-08 Sergey Bravyi , David Gosset , Robert Koenig , Kristan Temme

The GW approximation for the electronic self-energy is an important tool for the quantitative prediction of excited states in solids, but its mathematical exploration is hampered by the fact that it must, in general, be evaluated…

Materials Science · Physics 2013-02-27 Arno Schindlmayr

We consider a computational problem where the goal is to approximate the maximum eigenvalue of a two-local Hamiltonian that describes Heisenberg interactions between qubits located at the vertices of a graph. Previous work has shed light on…

Quantum Physics · Physics 2020-06-11 Anurag Anshu , David Gosset , Karen Morenz

The scientific interest in the analytical solution of the quantum Rabi model is due to the widespread use of this simple model in quantum optics, quantum computing, cavity QED, and nanoelectromechanical systems. This interest is related to…

Quantum Physics · Physics 2023-02-14 Andrei Ivanov

We derive the analytical eigenvalues and eigenstates of a family of potentials wells with exponential form (FPWEF). We provide a brief summary of the supersymmetry formalism applied to quantum mechanics and illustrate it by producing from…

Quantum Physics · Physics 2010-12-22 Charlotte Fabre , David Guery-Odelin

An approximate method is suggested to obtain analytical expressions for the eigenvalues and eigenfunctions of the some quantum optical models. The method is based on the Lie-type transformation of the Hamiltonians. In a particular case it…

Quantum Physics · Physics 2009-11-11 Ramazan Koc

We present a method for obtaining the quasi-exact solutions of the Rabi Hamiltonian in the framework of the asymptotic iteration method. The energy eigenvalues, the eigenfunctions and the associated Bender-Dunne orthogonal polynomials are…

Mathematical Physics · Physics 2013-06-14 S. -A. Yahiaoui , M. Bentaiba

A more reasonable trial ground state wave function is constructed for the relative motion of an interacting two-fermion system in a 1D harmonic potential. At the boundaries both the wave function and its first derivative are continuous and…

Quantum Gases · Physics 2017-04-06 Yanxia Liu , Jun Ye , Yuanyuan Li , Yunbo Zhang

We show that semi-classical states adapted to the symmetry of the Hamiltonian are an excellent approximation to the exact quantum solution of the ground and first excited states of the Dicke model. Their overlap to the exact quantum states…

Quantum Physics · Physics 2012-12-05 O. Castaños , E. Nahmad-Achar , R. López-Peña , J. G. Hirsch

The quantum mechanical concept of quasi-exact solvability is based on the idea of partial algebraizability of spectral problem. This concept is not directly extendable to the systems with infinite number of degrees of freedom. For such…

High Energy Physics - Theory · Physics 2009-10-30 A. G. Ushveridze

We present a self-consistent approach for computing the correlated quasiparticle spectrum of charged excitations in iterative $\mathcal{O}[N^5]$ computational time. This is based on the auxiliary second-order Green's function approach [O.…

Chemical Physics · Physics 2020-10-05 Oliver J. Backhouse , George H. Booth

The finite square potential well is a staple problem in introductory quantum mechanics. There is an extensive literature on the determination of the allowed energies, which requires the solution of a transcendental equation by numerical,…

Quantum Physics · Physics 2026-03-10 Nivaldo A. Lemos

We investigate two methods of obtaining exactly solvable potentials with analytic forms.

High Energy Physics - Theory · Physics 2007-05-23 Darwin Chang , We-Fu Chang

Higher-order WKB methods are used to investigate the border between the solvable and insolvable portions of the spectrum of quasi-exactly solvable quantum-mechanical potentials. The analysis reveals scaling and factorization properties that…

High Energy Physics - Theory · Physics 2009-10-30 C. M. Bender , G. Dunne , M. Moshe

We introduce a numerical method for the approximation of functions which are analytic on compact intervals, except at the endpoints. This method is based on variable transforms using particular parametrized exponential and…

Numerical Analysis · Mathematics 2016-09-06 Ben Adcock , Jésus Martín-Vaquero , Mark Richardson

Several approximations are tested by calculating the ground-state energy and the energy of the first excited $0^{+}$ state using an exactly solvable model with two symmetric levels interacting via a pairing force. They are the BCS…

Nuclear Theory · Physics 2009-09-29 Nguyen Dinh Dang

This paper introduces two mechanisms for computing over-approximations of sets of reachable states, with the aim of ensuring termination of state-space exploration. The first mechanism consists in over-approximating the automata…

Formal Languages and Automata Theory · Computer Science 2013-11-27 Alois Dreyfus , Pierre-Cyrille Heam , Olga Kouchnarenko