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Related papers: Two-Step Enantio-selective Optical Switch

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Determination of enantiomeric excess is important and remains challenges. We theoretically propose a new spectroscopic method for this issue based on the chirality-dependent AC Stark effects in cyclic three-level models under the…

Optics · Physics 2019-09-17 Chong Ye , Quansheng Zhang , Yu-Yuan Chen , Yong Li

Optical chirality is central to many industrial photonic technologies including enantiomer identification, ellipsometry-based tomography and spin multiplexing in optical communication. However, a substantial chiral response requires a…

Optics · Physics 2018-07-11 Longqing Cong , Prakash Pitchappa , Nan Wang , Ranjan Singh

Optical fields can exert forces of chiral nature on molecules and nanoparticles, which would prove extremely valuable in the separation of enantiomers with pharmaceutical applications, yet it is inherently complex, and the varied frameworks…

Recently, several laser schemes have been proposed to separate racemic mixtures of enantiomers by splitting a molecular beam into subbeams consisting of molecules of definite chirality [Y. Li, C. Bruder, and C. P. Sun, Phys. Rev. Lett. 99,…

Quantum Physics · Physics 2012-08-09 Andreas Jacob , Klaus Hornberger

Molecular chirality is an omnipresent phenomenon of fundamental significance in physics, chemistry and biology. For this reason, search for novel techniques for enantioselective control, detection and separation of chiral molecules is of…

A novel approach for the state-specific enantiomeric enrichment and the spatial separation of enantiomers is presented. Our scheme utilizes techniques from strong-field laser physics, specifically an optical centrifuge in conjunction with a…

Chemical Physics · Physics 2019-12-18 Andrey Yachmenev , Jolijn Onvlee , Emil Zak , Alec Owens , Jochen Küpper

Optical forces can be chiral when they exhibit opposite signs for the two enantiomeric versions of a chiral molecule or particle. Such forces could be eventually used to separate enantiomers, which could find application in numerous…

We present two methods for efficient detection of chiral molecules based on sequences of single pulses and Raman pulse pairs. The chiral molecules are modelled by a closed-loop three-state system with different signs in one of the couplings…

Quantum Physics · Physics 2020-11-18 Boyan T. Torosov , Michael Drewsen , Nikolay V. Vitanov

An interesting class of molecules is that in which the molecules do not possess a stereogenic center but can become chiral due to their spatial arrangement. These molecules can be seen as chiral conformers, whose two non-superimposable…

Chemical Physics · Physics 2021-06-11 Cristóbal Pérez , Amanda L. Steber , Anna Krin , Melanie Schnell

A different paradigm is proposed to selectively manipulate and transport small engineered chiral particles and discriminate different enantiomers using unstructured chiral light. It is theoretically shown that the response of a chiral…

Optics · Physics 2022-01-03 David E. Fernandes , Mário G. Silveirinha

We present a one-step deterministic entanglement purification protocol with linear optics and postselection. Compared with the Simon-Pan protocol (Phys. Rev. Lett. 89, 257901 (2002)), this one-step protocol has some advantages. First, it…

Quantum Physics · Physics 2011-08-09 Yu-Bo Sheng , Fu-Guo Deng

We introduce and theoretically analyze the concept of manipulating optical chirality via strong coupling of the optical modes of chiral nanostructures with excitonic transitions in molecular layers or semiconductors. With chirality being…

This review is based on the talk in the conference of "Spectroscopic Studies on Molecular Chirality" held on Dec 20-21 2013. The objects of the present paper are to (1) derive the energy difference between Laevorotatory, or left-handed,…

High Energy Physics - Phenomenology · Physics 2014-04-02 Takeshi Fukuyama

We here report on a quantitative study of Enantiomer-Specific State Transfer (ESST), performed in a pulsed, supersonic molecular beam. The chiral molecule 1-indanol is cooled to low rotational temperatures (1-2 K) and a selected rotational…

We optically trap freestanding single metallic chiral nanoparticles using a standing-wave optical tweezer. We also incorporate within the trap a polarimetric setup that allows to perform in situ chiral recognition of single enantiomers.…

We introduce an ultrafast all-optical approach for efficient chiral recognition which relies on the interference between two low-order nonlinear processes which are ubiquitous in nonlinear optics: sum-frequency generation and third-harmonic…

Optics · Physics 2023-06-09 Josh Vogwell , Laura Rego , Olga Smirnova , David Ayuso

To develop active nanomaterials that can instantly respond to external stimuli with designed mechanical motions is an important step towards the realization of nanomachines and nanorobots. Herein, we present our finding of a versatile…

Applied Physics · Physics 2020-01-08 Zexi Liang , Daniel Teal , Donglei Fan

We study the optical response of a metamaterial surface created by a lattice of split-ring resonators covered with a nematic liquid crystal and demonstrate millisecond timescale switching between electric and magnetic resonances of the…

From the beginning of molecular theory, the interplay of chirality and magnetism has intrigued scientists. There is still the question if enantiospecific adsorption of chiral molecules occurs on magnetic surfaces. Enantiomer discrimination…

Two molecules are enantiomers if they are non-superimposable mirror images of each other. Electric dipole-allowed cyclic transitions $|1\rangle\to|2\rangle\to|3\rangle\to|1\rangle$ obey the symmetry relation…

Quantum Physics · Physics 2022-03-08 Kai Schwennicke , Joel Yuen-Zhou
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