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Related papers: Two-Step Enantio-selective Optical Switch

200 papers

Enantioselective orientation of chiral molecules excited by a shaped picosecond laser pulse and a delayed femtosecond pulse is considered. Using quantum mechanical simulations, we demonstrate a strong field-free enantioselective orientation…

Optics · Physics 2022-03-31 Long Xu

We put forward an enantioselective method for chiral nanoparticles using optical tweezers. We demonstrate that the optical trapping force in a typical, realistic optical tweezing setup with circularly-polarized trapping beams is sensitive…

Optics · Physics 2019-11-07 R. Ali , F. A. Pinheiro , F. S. S. Rosa , R. S. Dutra , P. A. Maia Neto

Three-wave mixing spectroscopy of chiral molecules, which exist in left-handed and right-handed conformations, allows for enantio-selective population transfer despite random orientation of the molecules. This is based on constructive…

Quantum Physics · Physics 2019-07-09 Monika Leibscher , Thomas F. Giesen , Christiane P. Koch

Sculpting sub-cycle temporal structures of optical waveforms allows one to image and even control electronic clouds in atoms, molecules and solids. Here we show how the transverse spin component arising upon spatial confinement of such…

Optics · Physics 2020-11-17 David Ayuso , Andres Ordonez , Misha Ivanov , Olga Smirnova

We propose a method for enantio-detection of chiral molecules based on a cavity-molecule system, where the left- and right-handed molecules are coupled with a cavity and two classical light fields to form cyclic three-level models. Via the…

Quantum Physics · Physics 2021-10-25 Yu-Yuan Chen , Chong Ye , Yong Li

A new scheme for enantiomer differentiation of chiral molecules using a pair of linearly polarized intense ultrashort laser pulses with skewed mutual polarization is presented. The technique relies on the fact that the off-diagonal…

Chemical Physics · Physics 2017-05-04 Andrey Yachmenev , Sergei N. Yurchenko

A problem of inducing a required sign of chirality in a racemic mixture of enantiomers of a chiral molecule is analyzed. As an example, a racemic mixture (vapor) of left- and right-handed enantiomers of hydrogen peroxide (H2O2) molecule is…

Chemical Physics · Physics 2007-05-23 Boris Grishanin , Victor Zadkov

State-selective enantiomeric excess is realized using microwave-driven coherent population transfer. The method selectively promotes either R or S molecules to a higher rotational state by phase-controlled microwave pulses that drive…

Chemical Physics · Physics 2017-03-23 Sandra Eibenberger , John Doyle , David Patterson

Detecting and controlling the chirality of materials play an essential role in exploring nature, providing new avenues for material creation, discrimination, and manipulation. In such tasks, chiral reagents are essential in defining or…

Locally chiral light is an emerging tool for probing and controlling molecular chirality. It can generate large and freely adjustable enantioselectivities in purely electric-dipole effects, offering its major advantages over traditional…

Optics · Physics 2023-10-19 Chong Ye , Yifan Sun , Libin Fu , Xiangdong Zhang

We study quantum systems with broken symmetry that can be modelled as cyclic three-level atoms with coexisting one- and two-photon transitions. They can be selectively optically excited to any state. As an example, we show that left- and…

Quantum Physics · Physics 2008-01-28 Yong Li , C. Bruder

We study the enantio-specific state transfer in a four-level model for symmetric-top chiral molecules. Such a model is formed by coupling the electric-dipole transitions among four appropriate working states with three electromagnetic…

Quantum Physics · Physics 2022-04-27 Bo Liu , Chong Ye , C. P. Sun , Yong Li

Chiral discrimination that is efficient to tiny amounts of chiral substances, especially at the single-molecule level, is highly demanded. Here, we propose a single-shot nondestructive quantum sensing method addressing such an issue. Our…

Quantum Physics · Physics 2023-10-05 Chong Ye , Yifan Sun , Yong Li , Xiangdong Zhang

We propose to discriminate chiral molecules by combining one- and two-photon processes in a closed-loop configuration. The one-photon-coupling intrinsic {\pi}-phase difference between two enantiomers leads to their different superposition…

Quantum Physics · Physics 2020-02-20 Jin-Lei Wu , Yan Wang , Jie Song , Yan Xia , Shi-Lei Su , Yong-Yuan Jiang

Controlling the internal quantum states of chiral molecules for a selected enantiomer has a wide range of fundamental applications. Using tailored microwave fields, a chosen rotational state can be enriched for a selected enantiomer, even…

Chemical Physics · Physics 2024-02-28 JuHyeon Lee , Elahe Abdiha , Boris G. Sartakov , Gerard Meijer , Sandra Eibenberger-Arias

We study the excitation of asymmetric-top (including chiral) molecules by two-color femtosecond laser pulses. In the cases of non-chiral asymmetric-top molecules excited by an orthogonally polarized two-color pulse, we demonstrate,…

Optics · Physics 2021-09-16 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We propose an enantioselective scheme to sort homogeneous chiral particles using optical tweezers. For a certain range of material parameters, we show that a highly focused circularly-polarized laser beam traps particles of a specific…

Optics · Physics 2023-07-19 R. Ali , F. A. Pinheiro , R. S. Dutra , F. S. S. Rosa , P. A. Maia Neto

As much as chiral metasurfaces are significant in stereochemistry and polarization control, tunable chiroptical response is important for their dynamic counterparts. A single metasurface device with invertible chiral states can selectively…

Optics · Physics 2023-06-07 Andrew S. Kim , Anjan Goswami , Mohammad Taghinejad , Wenshan Cai

We prove complete controllability for rotational states of an asymmetric top molecule belonging to degenerate values of the orientational quantum number M. Based on this insight, we construct a pulse sequence that energetically separates…

With a microwave-regime cyclic three-state configuration, an enantiomer-selective state transfer~(ESST) is carried out through the two-path interference between a direct one-photon coupling and an effective two-photon coupling. The…

Quantum Physics · Physics 2020-04-15 Jin-Lei Wu , Yan Wang , Jin-Xuan Han , Cong Wang , Shi-Lei Su , Yan Xia , Yongyuan Jiang , Jie Song