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Multichannel Quantum Defect Theory (MQDT) is shown to be capable of producing quantitatively accurate results for low-energy atom-molecule scattering calculations. With a suitable choice of reference potential and short-range matching…

Atomic Physics · Physics 2015-03-19 James F. E. Croft , Alisdair O. G. Wallis , Jeremy M. Hutson , Paul S. Julienne

Multichannel quantum defect theory (MQDT) provides a powerful toolkit for describing and understanding collisions of cold alkali atoms. Various MQDT approximations differ primarily in how they characterize the so-called short-ranged…

Atomic Physics · Physics 2023-08-01 Alyson Laskowski , Nirav Mehta

We present a multiscale quantum-defect theory (QDT) for two identical atoms in a symmetric harmonic trap that combines the quantum-defect theory for the van der Waals interaction [B. Gao, Phys. Rev. A \textbf{64}, 010701(R) (2001)] at short…

Statistical Mechanics · Physics 2009-11-13 Yujun Chen , Bo Gao

We present a general formulation of multichannel quantum-defect theory (MQDT) for anisotropic long-range potentials. The theory unifies the treatment of atomic and molecular interactions of all types, and greatly expands the set of…

Atomic Physics · Physics 2020-08-19 Bo Gao

As a physically motivated and computationally simple model for cold atomic and molecular collisions, the multichannel quantum defect theory (MQDT) with frame transformation (FT) formalism provides an analytical treatment of scattering…

We extend Multichannel Quantum Defect Theory (MQDT) to ultracold collisions involving high partial wave quantum numbers $L$. This requires a careful standardization of the MQDT reference wave functions at long range to ensure their linear…

Atomic Physics · Physics 2015-06-12 Brandon P. Ruzic , Chris H. Greene , John L. Bohn

We show that multichannel quantum defect theory (MQDT) can be applied successfully as an efficient computational method for cold molecular collisions in Li+NH, which has a deep and strongly anisotropic interaction potential. In this…

Chemical Physics · Physics 2013-05-10 James F. E. Croft , Jeremy M. Hutson

Multichannel quantum defect theory (MQDT) has been widely applied to resonant and non-resonant scattering in a variety of atomic collision processes. In recent years, the method has been applied to cold collisions with considerable success,…

Atomic Physics · Physics 2015-06-22 Jisha Hazra , Brandon P. Ruzic , N. Balakrishnan , John L. Bohn

We present a quantum-defect theory (QDT) for the $-1/r^4$ type of long-range potential, as a foundation for a systematic understanding of charge-neutral quantum systems such as ion-atom, ion-molecule, electron-atom, and positron-atom…

Atomic Physics · Physics 2014-02-18 Bo Gao

The multichannel quantum defect theory (MQDT) in combination with the frame transformation (FT) approach is applied to model the Fano-Feshbach resonances measured for $^{7}$Li$^{87}$Rb and $^{6}$Li$^{87}$Rb [Marzok {\it et al.} Phys. Rev. A…

Atomic Physics · Physics 2015-05-20 Jesús Pérez-Ríos , Sourav Dutta , Yong P. Chen , Chris H. Greene

Multichannel quantum defect theory (MQDT) can provide an efficient alternative to full coupled-channel calculations for low-energy molecular collisions. However, the efficiency relies on interpolation of the Y matrix that encapsulates the…

Chemical Physics · Physics 2013-05-10 James F. E. Croft , Jeremy M. Hutson , Paul S. Julienne

We present a multichannel quantum-defect theory for slow atomic collisions that takes advantages of the analytic solutions for the long-range potential, and both the energy and the angular-momentum insensitivities of the short-range…

Atomic Physics · Physics 2009-11-11 Bo Gao , Eite Tiesinga , Carl J. Williams , Paul S. Julienne

We develop an analytical model for ultracold atom-ion collisions using the multichannel quantum-defect formalism. The model is based on the analytical solutions of the r^-4 long-range potential and on the application of a frame…

Atomic Physics · Physics 2015-05-28 Zbigniew Idziaszek , Andrea Simoni , Tommaso Calarco , Paul S. Julienne

Quantum defect embedding theory (QDET) is a many-body embedding method designed to describe condensed systems with correlated electrons localized within a given region of space, for example spin defects in semiconductors and insulators.…

Materials Science · Physics 2025-08-28 Siyuan Chen , Victor Wen-zhe Yu , Yu Jin , Marco Govoni , Giulia Galli

Multichannel quantum defect theory is applied in the treatment of the dissociative recombination and vibrational excitation processes for the BeD$^+$ ion in the twenty four vibrational levels of its ground electronic state…

We present a quantum theory of ion-atom interaction that is applicable at energies comparable to or smaller than the atomic hyperfine splitting and takes proper account of the effects of identical nuclei. The theory reveals the subtlety and…

Atomic Physics · Physics 2015-06-18 Ming Li , Li You , Bo Gao

Quantum Defect theory is a well established theoretical concept in modern spectroscopy. We show that this approach is useful in electron impact ionization problems where state of the art theoretical methods are presently restricted mostly…

Quantum Physics · Physics 2007-05-23 S. Mazevet , G. Nguyen Vien , J. Langlois , R. J. Tweed , O. Robaux , C. Tannous , K. Fakhreddine

We consider atoms or molecules coupled to the quantized electromagnetic radiation field in a dipole approximation. We show the existence of ground states and resonance states in situations where the eigenvalues are degenerate and protected…

Mathematical Physics · Physics 2025-07-08 David Hasler , Markus Lange

We consider a general problem of inelastic collision of particles interacting with power-law potentials. Using quantum defect theory we derive an analytical formula for the energy-dependent complex scattering length, valid for arbitrary…

Atomic Physics · Physics 2014-10-14 Krzysztof Jachymski , Michał Krych , Paul S. Julienne , Zbigniew Idziaszek

Scattering resonances due to the dipole-dipole interaction between ultracold molecules, induced by static or microwave fields, are studied theoretically. We develop a method for coupled-channel calculations that can efficiently impose many…

Quantum Gases · Physics 2023-07-11 Tijs Karman
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