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We propose a fast and non-destructive spectroscopic method for single molecular ions that implements quantum logic schemes between an atomic ion and the molecular ion of interest. Our proposal relies on a hybrid coherent manipulation of the…

Laser spectroscopy of cold and trapped molecular ions is a powerful tool for fundamental physics, including the determination of fundamental constants, the laboratory test for their possible variation, and the search for a possible electric…

Atomic Physics · Physics 2016-02-26 Fabian Wolf , Yong Wan , Jan C. Heip , Florian Gebert , Chunyan Shi , Piet O. Schmidt

Single dye molecules at cryogenic temperatures display many spectroscopic phenomena known from free atoms and are thus promising candidates for fundamental quantum optical studies. However, the existing techniques for the detection of…

Quantum Physics · Physics 2008-02-12 Gert Wrigge , Ilja Gerhardt , Jaesuk Hwang , Gert Zumofen , Vahid Sandoghdar

High-resolution microscopy of two-dimensional dipolar quantum gases requires selecting individual atomic layers, a task complicated for strongly magnetic lanthanide atoms by the limited applicability of standard magnetic-gradient…

Quantum Gases · Physics 2026-05-14 Niclas Höllrigl , Marian Kreyer , Rudolf Grimm , Emil Kirilov

We propose and analyze a nanomechanical architecture where light is used to perform linear quantum operations on a set of many vibrational modes. Suitable amplitude modulation of a single laser beam is shown to generate squeezing,…

Mesoscale and Nanoscale Physics · Physics 2012-12-17 Michael Schmidt , Max Ludwig , Florian Marquardt

A single quantum of excitation of a mechanical oscillator is a textbook example of the principles of quantum physics. Mechanical oscillators, despite their pervasive presence in nature and modern technology, do not generically exist in an…

By making use of the quantization rule of Raab and Friedrich [P. Raab and H. Friedrich, Phys. Rev. A 78, 022707 (2008)], we derive simple and accurate formulae for the number of rotational states supported by a weakly-bound vibrational…

Atomic Physics · Physics 2009-06-08 Mikhail Lemeshko , Bretislav Friedrich

We propose an improved photoassociation scheme to produce ultracold molecules in their vibronic ground state for the generic case where non-adiabatic effects facilitating transfer to deeply bound levels are absent. Formation of molecules is…

Atomic Physics · Physics 2008-10-28 Christiane P. Koch , Robert Moszynski

We consider the formation of cold ground-state polar molecules in a low vibrational level by laser fields. Starting from a pair of cold colliding atoms of dissimilar species, we propose a strategy consisting of three steps. In the first…

Atomic Physics · Physics 2026-01-14 Emanuel F. de Lima

We propose a scheme for direct laser deceleration of molecules based on a vibrational transition-mediated bichromatic force (VBCF). By precisely engineering mid-infrared optical fields, we establish coherent absorption-stimulated emission…

Atomic Physics · Physics 2026-05-20 Meng-Yi Yu , Ya-Nan Lv , Cun-Feng Cheng , Shui-Ming Hu

We excite YbF molecules to low-lying vibrational levels of the $A^2\Pi_{1/2}$ state, and of the nearby perturber state sometimes called [18.6]0.5. By dispersing the fluorescence, we measure branching ratios for the radiative decay to…

Atomic Physics · Physics 2015-06-18 I. J. Smallman , F. Wang , T. C. Steimle , M. R. Tarbutt , E. A. Hinds

We suggest a protocol for the sympathetic cooling of a molecular asymmetric top rotor co-trapped with laser-cooled atomic ions, based on resonant coupling between the molecular ion's electric dipole moment and a common normal mode of the…

Quantum Physics · Physics 2026-02-04 Monika Leibscher , Alexander Blech , Christiane P. Koch

We show that individual vibrational modes in single-molecule junctions with asymmetric molecule-lead coupling can be selectively excited by applying an external bias voltage. Thereby, a non-statistical distribution of vibrational energy can…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 R. Volkovich , R. Härtle , M. Thoss , U. Peskin

Rovibrational states of the four dimers formed by the light and the heavy isotopologues of the methane and the water molecules are computed using a potential energy surface taken from the literature. The general rovibrational energy-level…

Chemical Physics · Physics 2017-08-07 János Sarka , Attila G. Császár , Edit Mátyus

Molecular vibrations and their dynamics are of outstanding importance for electronic and thermal transport in nanoscale devices as well as for molecular catalysis. The vibrational dynamics of <100 molecules are studied through three-colour…

Optical detection and spectroscopy of single molecules has become an indispensable tool in biological imaging and sensing. Its success is based on fluorescence of organic dye molecules under carefully engineered laser illumination. In this…

Chemical Physics · Physics 2011-01-18 Ilja Gerhardt , Lijian Mai , Antia Lamas-Linares , Christian Kurtsiefer

We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to…

Quantum Physics · Physics 2016-09-28 Milan Sindelka , Nimrod Moiseyev

Control over the quantum states of individual molecules is crucial in the quest to harness their rich internal structure and dipolar interactions for applications in quantum science. In this paper, we develop a toolbox of techniques for the…

Atomic Physics · Physics 2024-08-28 Daniel K. Ruttley , Alexander Guttridge , Tom R. Hepworth , Simon L. Cornish

We report on the state-selective detection of near-dissociation ultracold KRb molecules in the ground $X^1\Sigma^+$ state and the metastable $a^3\Sigma^+$ state. The molecules are produced by photoassociation of ultracold atoms followed by…

Atomic Physics · Physics 2009-11-11 D. Wang , E. E. Eyler , P. L. Gould , W. C. Stwalley

We have created a dark quantum superposition state of a Rb Bose-Einstein condensate (BEC) and a degenerate gas of Rb$_2$ ground state molecules in a specific ro-vibrational state using two-color photoassociation. As a signature for the…

Other Condensed Matter · Physics 2007-05-23 K. Winkler , G. Thalhammer , M. Theis , H. Ritsch , R. Grimm , J. Hecker Denschlag