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We propose a novel phase-field model to predict elastic microphase separation in polymer gels. To this end, we extend the Cahn-Hilliard free-energy functional to incorporate an elastic strain energy and a coupling term. These contributions…

Materials Science · Physics 2025-05-05 Hamza Oudich , Pietro Carrara , Laura De Lorenzis

The folding pathway and rate coefficients of the folding of a knotted protein are calculated for a potential energy function with minimal energetic frustration. A kinetic transition network is constructed using the discrete path sampling…

Biomolecules · Quantitative Biology 2010-07-05 Michael C. Prentiss , David J. Wales , Peter G. Wolynes

Field-theoretical method is efficient in predicting the assembling structures of polymeric systems. However, for the polymer/nanoparticle mixture, the continuous density description is not suitable to capture the realistic assembly of…

Soft Condensed Matter · Physics 2017-05-17 Hui-shu Li , Bo-kai Zhang , Jian Li , Wen-de Tian , Kang Chen

Applying multicanonical simulations we investigated folding properties of off-lattice heteropolymers employing a mesoscopic hydrophobic-polar model. We study for various sequences folding channels in the free-energy landscape by comparing…

Soft Condensed Matter · Physics 2009-02-17 Stefan Schnabel , Michael Bachmann , Wolfhard Janke

Chain molecules play a key role in the polymer field and in living cells. Our focus is on a new homopolymer model of a linear chain molecule subject to an attractive self-interaction promoting compactness. We analyze the model using simple…

Statistical Mechanics · Physics 2021-07-14 Tatjana Škrbić , Trinh Xuan Hoang , Achille Giacometti , Amos Maritan , Jayanth R. Banavar

A recently developed lattice field theory approach to the statistical mechanics of charged polymers in electrolyte solutions [S. Tsonchev, R. D. Coalson, and A. Duncan, Phys. Rev. E {\bf{60}}, 4257, (1999)] is generalized to the case where…

Statistical Mechanics · Physics 2016-08-31 S. Tsonchev , R. D. Coalson , A. Duncan

While stretching of most polymer chains leads to rather featureless force-extension diagrams, some, notably DNA, exhibit non-trivial behavior with a distinct plateau region. Here we propose a unified theory that connects force-extension…

Mesoscale and Nanoscale Physics · Physics 2013-02-26 Alexander V. Savin , Mikhail A. Mazo , Irina P. Kikot , Alexey V. Onufriev

We consider self-avoiding lattice polygons, in the hypercubic lattice, as a model of a ring polymer adsorbed at a surface and either being desorbed by the action of a force, or pushed towards the surface. We show that, when there is no…

Statistical Mechanics · Physics 2018-02-14 AJ Guttmann , EJ Janse van Rensburg , I Jensen , SG Whittington

Phase separation in polymer solutions often correlates with single-chain and two-chain properties, such as the single-chain radius of gyration, Rg, and the pairwise second virial coefficient, B22. However, recent studies have shown that…

Soft Condensed Matter · Physics 2025-07-02 Jessica Jin , Wesley Oliver , Michael A. Webb , William M. Jacobs

Semiflexible polymers in poor solvents exhibit a rich variety of collapsed morphologies, including globules, toroids, and rodlike bundles, arising from the competition between attractive interactions and chain stiffness. Computer…

Statistical Mechanics · Physics 2026-01-22 Biman Bagchi

The equilibrium free energy landscape of an off-lattice model protein as a function of an internal (reaction) coordinate is reconstructed from out-of-equilibrium mechanical unfolding manipulations. This task is accomplished via two…

Statistical Mechanics · Physics 2007-10-17 Alberto Imparato , Stefano Luccioli , Alessandro Torcini

A method to reconstruct the energy landscape of small peptides is presented with reference to a 2d off--lattice model. The starting point is a statistical analysis of the configurational distances between generic minima and directly…

Soft Condensed Matter · Physics 2007-05-23 Lorenzo Bongini , Roberto Livi , Antonio Politi , Alessandro Torcini

The energy landscapes of proteins have evolved to be different from most random heteropolymers. Many studies have concluded that evolutionary selection for rapid and reliable folding to a given structure that is stable at biological…

Disordered Systems and Neural Networks · Physics 2009-11-10 Steven S. Plotkin , Peter G. Wolynes

We study algorithms for solving quadratic systems of equations based on optimization methods over polytopes. Our work is inspired by a recently proposed convex formulation of the phase retrieval problem, which estimates the unknown signal…

Information Theory · Computer Science 2018-05-25 Oussama Dhifallah , Christos Thrampoulidis , Yue M. Lu

We have analyzed the dependence of average ground state energy per monomer, $e$, of the complex of two random heteropolymers with quenched sequences, on chain length, $n$, in the ensemble of chains with uniform distribution of primary…

Statistical Mechanics · Physics 2009-11-13 M. V. Tamm , S. K. Nechaev

Phase diagram of the ground states of DNA in a bad solvent is studied for a semi-flexible polymer model with a generalized local elastic bending potential characterized by a nonlinearity parameter $x$ and effective self-attraction promoting…

Biomolecules · Quantitative Biology 2016-01-28 Trinh X. Hoang , Hoa Lan Trinh , Achille Giacometti , Rudolf Podgornik , Jayanth R. Banavar , Amos Maritan

Protein folding is analyzed using a replica variational formalism to investigate some free energy landscape characteristics relevant for dynamics. A random contact interaction model that satisfies the minimum frustration principle is used…

Disordered Systems and Neural Networks · Physics 2009-10-30 Shoji Takada , Peter G. Wolynes

A system of two self and mutual interacting ring polymers, close together in space, can display several competing equilibrium phases and phase transitions. Using Monte Carlo simulations and combinatorial arguments on a corresponding lattice…

Soft Condensed Matter · Physics 2026-04-17 EJ Janse van Rensburg , E Orlandini , MC Tesi , SG Whittington

The self-avoid random walk algorithm has been extensively used in the study of polymers. In this work we study the basic properties of the trajectories generated with this algorithm when two interactions are added to it: contact and folding…

Soft Condensed Matter · Physics 2023-04-14 R. J. Santos Neto , A. A. Costa , P. F. Gomes

In this paper we analyse both the dynamics and the high density physics of the infinite dimensional lattice gas model for random heteropolymers recently introduced in \cite{jort}. Restricting ourselves to site-disordered heteropolymers, we…

Disordered Systems and Neural Networks · Physics 2009-11-07 H. Chakravorty , J. van Mourik , A. C. C. Coolen