Related papers: A twist in chiral interaction between biological h…
A first-principles approach for active chiral hard disks is presented, that explicitly accounts for steric interactions on the two-body level. We derive an effective one-body equation for the joint probability distribution of ositions and…
We study the effects of chirality at the segment scale on the thermodynamics of block copolymer melts using self consistent field theory. In linear diblock melts where segments of one block prefer a twisted, or cholesteric, texture, we show…
Stiff, elongated biomolecules such as filamentous viruses, DNA or cellulose nanocrystals are known to form liquid crystals often exhibiting a helical supramolecular organization. Little is known about the microscopic origin, size and…
The shape of the building blocks plays a crucial role in directing self-assembly towards desired architectures. Out of the many different shapes, helix has a unique position. Helical structures are ubiquitous in nature and a helical shape…
Chirality induced spin selectivity, discovered about two decades ago in helical molecules, is a non-equilibrium effect that emerges from the interplay between geometrical helicity and spin-orbit interactions. Several model Hamiltonians…
We report a computer simulation study on the effect of molecular structural biaxiality in the phase formation of chiral molecules. In this study, we have done coarse-grained modeling to observe self-assembled phase behavior. In our…
We show that polymer cholesterics have much longer pitches than comparable short molecule cholesterics, due to their anomalous elasticity. The pitch $P$ of a chiral mixture with concentration $c$ near the racemic (non-chiral) concentration…
Directed motion up a concentration gradient is crucial for the survival and maintenance of numerous biological systems, such as sperms moving towards an egg during fertilization or ciliates moving towards a food source. In these systems,…
We have investigated the relationship between the morphology of helical particles and the features of the cholesteric (N$^\ast $) phase that they form. Using an Onsager-like theory, applied to systems of hard helices, we show that the…
We derive a set of design requirements that lead to structures suitable for molecular circular dichroism (CD) enhancement. Achirality of the structure and two suitably selected sequentially incident beams of opposite helicity ensures that…
The criteria for chiral doublet bands based on one particle and one hole coupled to a triaxial rotor have been summarized. Two representative cases in $A\sim100$ odd-odd nuclei, nearly degenerate $\Delta I =1$ doublet bands in $^{104}$Rh…
We identify the dominant collisional decoherence mechanism which serves to stabilize and super-select the configuration states of chiral molecules. A high-energy description of this effect is compared to the results of the exact molecular…
The helical distribution of the electronic density in chiral molecules, such as DNA and bacteriorhodopsin, has been suggested to induce a spin-orbit coupling interaction that may lead to the so-called chirality-induced spin selectivity…
Chirality and chiral molecules are key elements in modern chemical and biochemical industries. Individual addressing, and the eventual separation of chiral enantiomers has been and still is an important elusive task in molecular physics and…
We investigate the statistical mechanics of chirality and biaxiality in liquid crystals through a variety of theoretical approaches, including Monte Carlo simulations, lattice mean-field theory, and Landau theory. All of these calculations…
The molecules in lyotropic membranes are typically aligned with the surface normal. When these molecules are chiral, there is a tendency for the molecular direction to twist. These competing effects can reach a compromise by producing…
Chiral nematic or cholesteric liquid crystals (LCs) are mesophases with long-ranged orientational order featuring a quasi-layered periodicity imparted by a helical configuration but lacking positional order. Doping molecular cholesteric LCs…
A particle rotor model is developed which couples several valence protons and neutrons to a rigid triaxial rotor core. It is applied to investigating the chirality in odd-$A$ nucleus $^{135}$Nd with $\pi h_{11/2}^2\otimes\nu h^{-1}_{11/2}$…
Molecular chirality leads to a wonderful variety of equilibrium structures, from the simple cholesteric phase to the twist-grain-boundary phases, and it is responsible for interesting and technologically important materials like…
Evidence of a special chiral nematic phase is provided using numerical simulation and Onsager theory for systems of hard helical particles. This phase appears at the high density end of the nematic phase, when helices are well aligned, and…