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The prediction of product translational, vibrational, and rotational energy distributions for arbitrary initial conditions for reactive atom+diatom collisions is of considerable practical interest in atmospheric re-entry. Due to the large…

Chemical Physics · Physics 2023-06-23 Juan Carlos San Vicente Veliz , Julian Arnold , Raymond J. Bemish , Markus Meuwly

The cross section of light absorption by semiconductor quantum dots in the case of the resonance with excitons $\Gamma_6 \times \Gamma_7$ in cubical crystals $T_d$ is calculated. It is shown that an interference of stimulating and induced…

Statistical Mechanics · Physics 2007-05-23 I. G. Lang , L. I. Korovin , S. T. Pavlov

We develop semiclassical approximations for calculating photoabsorption cross sections beyond the continuum threshold in quantum many-body systems. These approximations use the fully quantum-mechanical Wigner function of the ground state…

Atomic Physics · Physics 2023-05-24 Julien Toulouse

For ethylene carbonate on the (100) surface of lithium, we calculate the adsorption energy in two binding motifs as well as the barrier height for a ring-opening decomposition reaction. We validate a scheme for producing results in the…

The vibrational entropy of a solid at finite temperature is investigated from the perspective of information theory. Ab initio molecular dynamics (AIMD) simulations generate ensembles of atomic configurations at finite temperature from…

Statistical Mechanics · Physics 2022-05-11 Yang Huang , Michael Widom

We devise a theory of x-ray absorption by symmetric-top molecules which are aligned by an intense optical laser. Initially, the density matrix of the system is composed of the electronic ground state of the molecules and a thermal ensemble…

Chemical Physics · Physics 2008-02-23 Christian Buth , Robin Santra

We present transient absorption spectra of an extreme ultraviolet attosecond pulse train in helium dressed by an 800 nm laser field with intensity ranging from $2\times10^{12}$ W/cm$^2$ to $2\times10^{14}$ W/cm$^2$. The energy range probed…

We simultaneously trap ultracold lithium and cesium atoms in an optical dipole trap formed by the focus of a CO$_2$ laser and study the exchange of thermal energy between the gases. The cesium gas, which is optically cooled to $20 \mu$K,…

Atomic Physics · Physics 2009-11-07 M. Mudrich , S. Kraft , K. Singer , R. Grimm , A. Mosk , M. Weidemuller

We calculate the cross sections for dissociation of $J/\psi$ by pions and $\rho$-mesons within the framework of a meson exchange model. We find that these cross sections are small at center-of-mass energies less than 1 GeV above threshold,…

Nuclear Theory · Physics 2008-11-26 Sergei G. Matinyan , Berndt Müller

We report state-of-the-art ab initio calculations of the potential energy curve for the $a^3\Sigma_u^+$ state of the lithium dimer conducted to achieve spectroscopic accuracy ($<$1cm$^{-1}$) without any prior adjustment to fit the…

Chemical Physics · Physics 2021-01-27 Michał Lesiuk , Monika Musiał , Robert Moszynski

Precision measurements are performed on highly excited vibrational quantum states of molecular hydrogen. The $v=12, J=0-3$ rovibrational levels of H$_2$ ($X^1\Sigma_g^+$), lying only $2000$ cm$^{-1}$ below the first dissociation limit, were…

Atomic Physics · Physics 2015-09-30 M. L. Niu , E. J. Salumbides , W. Ubachs

X-ray absorption spectroscopy is a crucial experimental technique for elucidating the mechanisms of structural degradation in battery materials. However, extracting information from the measured spectrum is challenging without high-quality…

Photoionization spectroscopy of cold cesium dimers obtained by photoassociation of cold atoms in a magneto-optical trap is reported here. In particular, we report on the observation and on the spectroscopic analysis of all the excited…

Photodetachment thermometry on a beam of OH$^-$ in a cryogenic storage ring cooled to below 10 K is carried out using two-dimensional, frequency and time dependent photodetachment spectroscopy over 20 minutes of ion storage. In equilibrium…

Temperature dependence of intersubband transitions in AlN/GaN multiple quantum wells grown with molecular beam epitaxy is investigated both by absorption studies at different temperatures and modeling of conduction-band electrons. For the…

We use the theory of quantum estimation in two different qubit-boson coupling models to demonstrate that the temperature of a quantum harmonic oscillator can be estimated with high precision by quantum-limited measurements on the qubit. The…

Quantum Physics · Physics 2012-10-31 Matteo Brunelli , Stefano Olivares , Mauro Paternostro , Matteo G. A. Paris

Electron transfer coupled to a collective vibronic degree of freedom is studied in strongly condensed phase and at lower temperatures where quantum fluctuations are essential. Based on an exact representation of the reduced density matrix…

Statistical Mechanics · Physics 2009-11-10 Joachim Ankerhold , Hartwig Lehle

Spectroscopy of hydrogen can be used for a search into physics beyond the Standard Model. Differences between the absorption spectra of H$_2$ as observed at high redshift and those measured in the laboratory can be interpreted in terms of…

Atomic Physics · Physics 2017-08-23 Wim Ubachs , Jeroen C. J. Koelemeij , Kjeld S. E. Eikema , Edcel J. Salumbides

Absorption imaging is a commonly adopted method to acquire, with high temporal resolution, spatial information on a partially transparent object. It relies on the interference between a probe beam and the coherent response of the object. In…

We present a new method for recovering the kinetic temperature of the intervening diffuse gas to an accuracy of 10%. The method is based on the comparison of unsaturated absorption-line profiles of two species with different atomic weights.…

Astrophysics · Physics 2009-10-30 Sergei A. Levshakov , Fumio Takahara , Irina I. Agafonova