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The adsorption behavior of ions at liquid-vapor interfaces exhibits several unexpected yet generic features. In particular, energy and entropy are both minimum when the solute resides near the surface, for a variety of ions in a range of…

Statistical Mechanics · Physics 2017-02-08 Suriyanarayanan Vaikuntanathan , Patrick R. Shaffer , Phillip L. Geissler

Non-polar magnetic nanoparticles agglomerate upon cooling. This process is followed by in-situ small angle X-ray scattering to assess structural properties of the emerging agglomerates. On the length scale of a few particle diameters, no…

Soft Condensed Matter · Physics 2020-11-30 Christian Appel , Björn Kuttich , Tobias Kraus , Bernd Stühn

We study the structure and interfacial properties of model athermal mixtures of colloids and excluded volume polymers. The colloid particles are modeled as hard spheres whereas the polymer coils are modeled as chains formed from…

Soft Condensed Matter · Physics 2007-05-23 Pawel Bryk

Using N-body/hydrodynamic simulations, the influence of non-equipartition processes on the thermal and dynamical properties of cosmological baryonic gas is investigated. We focus on a possible departure from equilibrium between electrons,…

Astrophysics · Physics 2009-11-10 S. Courty , J. -M. Alimi

We study the behavior of aqueous surfactant solutions in the bulk phase and in slit-like pores by molecular dynamics. Adsorption and self-assembly of nonionic surfactants C$_7$E$_3$ that mimic alkyl poly(ethylene oxide) molecules are…

Soft Condensed Matter · Physics 2026-03-31 T. Staszewski , M. Borówko

Complex fluids such as emulsions, colloidal gels, polymer or surfactant solutions are all characterized by the existence of a "microstructure" which may couple to an external flow on timescales that are easily probed in experiments. Such a…

Soft Condensed Matter · Physics 2015-02-11 Christophe Perge , Marc-Antoine Fardin , Sebastien Manneville

Understanding the response of coal mechanical properties to dewatering and gas depletion is critical for estimating borehole stability and designing infill coal seam gas (CSG) wells. Despite its importance, the full impact of these…

Densities, $\rho$ , and speeds of sound, $u$, of 2-propanone + dipropylamine,+ dibutylamine or + triethylamine systems have been measured at (293.15, 298.15 and 303.15) K and atmospheric pressure using a vibrating tube densimeter and sound…

The dielectric properties of molecules or nanostructures are usually modified in a complex manner, when assembled into a condensed phase. We propose a first-principles method to compute polarizabilities of sub-entities of solids and…

Chemical Physics · Physics 2018-09-10 Ding Pan , Marco Govoni , Giulia Galli

This work is devoted to a method to generate particle cluster assemblies, and connected to evaporative lithography. Experiments are carried out using nonuniform evaporation of an isopropanol film containing polystyrene microspheres in a…

Soft Condensed Matter · Physics 2021-09-02 M. A. Al-Muzaiqer , K. S. Kolegov , N. A. Ivanova , V. M. Fliagin

In this paper we propose several models that describe the dynamics of liquid films which are covered by a high concentration layer of insoluble surfactant. First, we briefly review the 'classical' hydrodynamic form of the coupled evolution…

Fluid Dynamics · Physics 2013-03-25 Uwe Thiele , Andrew J. Archer , Mathis Plapp

With most of the focus to date having been on the coalescence of freely suspended droplets, much less is known about the coalescence of sessile droplets, especially in the case of droplets laden with surfactant. Here, we employ large-scale…

Soft Condensed Matter · Physics 2024-03-19 S. Arbabi , P. Deuar , R. Bennacer , Z. Che , P. E. Theodorakis

Compressible flow varies from ideal-gas behavior at high pressures where molecular interactions become important. Density is described through a cubic equation of state while enthalpy and sound speed are functions of both temperature and…

Fluid Dynamics · Physics 2020-03-11 William A. Sirignano

It is shown that structuring at the microlevel, a previously not described in detail phenomenon, is the intrinsic property of water and aqueous solutions. At room conditions water (including "ultrapure" one) and aqueous solutions are…

Soft Condensed Matter · Physics 2018-09-05 Tatiana Yakhno , Vladimir Yakhno

We present a coarse-grained model for ionic surfactants in explicit aqueous solutions, and study by computer simulation both the impact of water content on the morphology of the system, and the consequent effect of the formed interfaces on…

Soft Condensed Matter · Physics 2015-03-16 Samuel Hanot , Sandrine Lyonnard , Stefano Mossa

The effects of different forms of the sound-velocity function c_s(T) on the hydrodynamic evolution of matter created in the central region of ultra-relativistic heavy-ion collisions are studied. At high temperatures (above the critical…

Nuclear Theory · Physics 2008-11-26 Mikolaj Chojnacki , Wojciech Florkowski

When the theoretical values of the interfacial tension -resulting from the homogeneous distribution of ionic surfactant molecules amongst the interface of emulsion drops- are plotted against the total surfactant concentration, they produce…

Soft Condensed Matter · Physics 2014-01-07 German Urbina-Villalba , Sabrina Di Scipio , Neyda Garcia-Valera

The electrostatic screening properties of ionic fluids are of paramount importance in countless physical processes. Yet, the behavior of ionic conductors out of thermal equilibrium has to date mainly been studied in the context of…

Statistical Mechanics · Physics 2023-04-19 Andrea Grisafi , Federico Grasselli

2D conjugated polyphthalocyanines can be obtained as two distinctly different types of material with specific molecular structures and different morphological properties. It was believed that the temperature is the key factor affecting the…

Models and observations suggest that ice-particle aggregation at and beyond the snowline dominates the earliest stages of planet-formation, which therefore is subject to many laboratory studies. However, the pressure-temperature gradients…

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