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Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…

chao-dyn · Physics 2008-02-03 J. Kumicak , X. de Hemptinne

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

Heat exchanges are the essence of Thermodynamics. In order to investigate non-equilibrium effects like quantum coherence and correlations in heat flows we introduce the concept of apparent temperature. Its definition is based on the…

Quantum Physics · Physics 2020-01-10 Camille L. Latune , Ilya Sinayskiy , Franceso Petruccione

Building on the fundamental equation, this study revisits key thermodynamic concepts in a cohesive and innovative manner. It demonstrates the consistency of thermodynamic theory while addressing and clarifying common misconceptions and…

Statistical Mechanics · Physics 2025-07-04 Joaquim Anacleto

It is shown that the partial temperatures of a homogeneous multicomponent gas mixture in the thermodynamical equilibrium cannot be equal to each other. New general solutions for equilibrium distribution functions of the multicomponent…

Statistical Mechanics · Physics 2007-05-23 Yurii M. Loskutov

We develop the strong coupling quantum thermodynamics based on the solution of the exact master equation. We find that both the Hamiltonian and the temperature must be renormalized due to the system-reservoir couplings. With the…

Quantum Physics · Physics 2020-10-06 Wei-Ming Huang , Wei-Min Zhang

Gibbsian statistical mechanics is extended into the domain of non-negligible {though non-specified} correlations in phase space while respecting the fundamental laws of thermodynamics. The appropriate Gibbsian probability distribution is…

Statistical Mechanics · Physics 2014-06-26 R. A. Treumann , W. Baumjohann

We investigate non-equilibrium behavior of driven dissipative systems, using the model presented in [Phys. Rev. Lett. 93, 240601 (2004)]. We solve the non-Boltzmann steady state energy distribution and the temporal evolution to it, and find…

Statistical Mechanics · Physics 2007-05-23 Yair Shokef , Dov Levine

A picture for thermodynamics of the glassy state is introduced. It assumes that one extra parameter, the effective temperature, is needed to describe the glassy state. This explains the classical paradoxes concerning the Ehrenfest relations…

Disordered Systems and Neural Networks · Physics 2009-10-31 Th. M. Nieuwenhuizen

We study the single-particle distributions of three-dimensional hard sphere gas described by the Boltzmann equation. We focus on the steady homogeneous isotropic solutions in thermodynamically open conditions, i.e. in the presence of…

Chaotic Dynamics · Physics 2011-10-10 Davide Proment , Sergey Nazarenko , Pietro Asinari , Miguel Onorato

The classical thermodynamic laws fail to capture the behavior of systems with energy Hamiltonian which is an explicit function of the temperature. Such Hamiltonian arises, for example, in modeling information processing systems, like…

Statistical Mechanics · Physics 2009-11-13 Ori Shental , Ido Kanter

The basic idea of a microscopic understanding of Thermodynamics is to derive its main features from a microscopic probability distribution. In such a vein, we investigate the thermal statistics of quasi-probabilities's semi-classical…

Statistical Mechanics · Physics 2016-09-20 F. Pennini , A. Plastino , M. C. Rocca

Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

The concept of effective temperatures in nonequilibrium systems is studied within an exactly solvable model of non-Markovian diffusion. The system is coupled to two heat baths which are kept at different temperatures: one ('fast') bath…

Statistical Mechanics · Physics 2009-11-11 Patrick Ilg , J. -L. Barrat

A system is glassy when the observation time is much smaller than the equilibration time. A unifying thermodynamic picture of the glassy state is presented. Slow configurational modes are in quasi-equilibrium at an effective temperature. It…

Statistical Mechanics · Physics 2009-10-31 Th. M. Nieuwenhuizen

This review presents the effective temperature notion as defined from the deviations from the equilibrium fluctuation-dissipation theorem in out of equilibrium systems with slow dynamics. The thermodynamic meaning of this quantity is…

Statistical Mechanics · Physics 2015-05-28 Leticia F. Cugliandolo

This paper investigates generalized thermodynamic relationships in physical systems where relevant macroscopic variables are determined by the exponential Kolmogorov-Nagumo average. We show that while the thermodynamic entropy of such…

Statistical Mechanics · Physics 2025-01-23 Pablo A. Morales , Jan Korbel , Fernando E. Rosas

Our previous works have shown the statistical mechanics of self-gravitating system. In this paper, we will show its thermodynamics and compare our results with observations and simulations. We propose that our statistical mechanics can be…

Cosmology and Nongalactic Astrophysics · Physics 2011-12-30 Dong-Biao Kang