Related papers: Isotope shift in the electron affinity of chlorine
Today, the electron affinity is experimentally well known for most of the elements and is a useful guideline for developing ab initio computational methods. However, the measurements of isotope shifts on the electron affinity are limited by…
The electron affinities eA(S) are measured for the two isotopes 32S and 34S (16752.9753(41) and 16752.9776(85) cm-1, respectively). The isotope shift in the electron affinity is found to be positive, eA(34S)-eA(32S) = +0.0023(70) cm-1, but…
We use observations of chlorine-bearing species in molecular absorbers at intermediate redshifts to investigate chemical properties and $^{35}$Cl/$^{37}$Cl isotopic ratios in the absorbing sightlines. Chloronium (H$_2$Cl$^+$) is detected…
We report additional detections of the chloronium molecular ion, H$_2$Cl$^+$, toward four bright submillimeter continuum sources: G29.96, W49N, W51, and W3(OH). With the use of the HIFI instrument on the Herschel Space Observatory, we…
Nuclear charge radii are vital for nuclear and atomic physics, the determination of fundamental constants, and searches for new physics. Muonic atoms, where a single negative muon orbits a nucleus, are sensitive tools for determining…
We report a precise measurement of the isotope shifts in the $4^2$S$_{1/2} \rightarrow 3^2$D$_{5/2}$ electric quadrupole transition at 729~nm in the $^{40 - 42,44,48}$Ca$^+$. The measurement has been made via high-resolution laser…
The multiconfiguration Dirac-Hartree-Fock method is applied to study the electron affinities of At and its homologous elements Cl, Br, and I. Our method of calculation is validated through the comparison with the available experimental…
We measured the isotope shift in the $^2$S$_{1/2}$-$^2$P$_{3/2}$ (D2) transition in singly-ionized calcium ions using photon recoil spectroscopy. The high accuracy of the technique enables us to resolve the difference between the isotope…
We report on saturated absorption spectroscopy measurements of the $(4s^2) ^{1}S_0\rightarrow(4s4p) ^{1}P_1$ transition for the four most abundant even-mass isotopes in calcium. By referencing the laser locked to an ultralow expansion…
Although it is known that the $N=28$ spherical shell closure erodes, the strength of the closure with decreasing proton number $Z<20$ is an open question in nuclear structure. In this region of interest, direct high-precision mass…
Longstanding problems in the comparison of very accurate hyperfine-shift measurements to theory were partly overcome by precise measurements on few-electron highly-charged ions. Still the agreement between theory and experiment is…
This study investigated the consistency/inconsistency of carbon isotope compositions of chlorine-isotopologue pairs, e.g., 12C235Cl4 vs. 12C13C35Cl4, of individual organochlorines including two chloroethylenes, three polychlorinated…
This work presents a method for the ab initio calculation of isotope shift in atoms and ions with one valence electron above closed shells. As a zero approximation we use relativistic Hartree-Fock and then calculate correlation corrections.…
We report on improved isotope shift measurements of the isotopes $^{40,42,44,48}$Ca in the $4s\,^2 \rm{S}_{\frac{1}{2}} \rightarrow 4p\,^2\rm{P}_{\frac{3}{2}}$ (D2) transition using collinear laser spectroscopy. Accurately known isotope…
Chlorine abundances are reported in 15 evolved giants and one M dwarf in the solar neighborhood. The Cl abundance was measured using the vibration-rotation 1-0 P8 line of H$^{35}$Cl at 3.69851 $\mu$m. The high resolution L-band spectra were…
Compound-specific chlorine isotope analysis (CSIA-Cl) is a practicable and high-performance approach for quantification of transformation processes and pollution source apportionment of chlorinated organic compounds. This study developed a…
Atomic isotope shifts (ISs) are the isotope-dependent energy differences in the atomic electron energy levels. These shifts serve an important role in atomic and nuclear physics, and particularly in the latter as signatures of nuclear…
The electron affinity of tellurium has been determined to 1.970 876(7) eV. The threshold for photodetachment of Te^-(^{2} P_{3/2}) forming neutral Te in the ground state was investigated by measuring the total photodetachment cross section…
We measured $^{35}$Cl abundances in 52 M giants with metallicities between -0.5 $<$ [Fe/H] $<$ 0.12. Abundances and atmospheric parameters were derived using infrared spectra from CSHELL on the IRTF and from optical echelle spectra. We…
We demonstrate the importance of electron correlation effects in the hyperfine structure constants of many low-lying states in $^{210}$Fr and $^{212}$Fr. This is achieved by calculating the magnetic dipole and electric quadrupole hyperfine…