Related papers: Analysis of Molecular Rotational Spectra
When circularly polarized light is scattered from a rotating target, a rotational Doppler shift (RDS) emerges from an exchange of angular momentum between the spinning object and the electromagnetic field. Here, we used coherently spinning…
Single molecule rotational correlation functions are analyzed for several reorientation geometries. Even for the simplest model of isotropic rotational diffusion our findings predict non-exponential correlation functions to be observed by…
Spin properties of the nucleon are discussed based on the ongoing and planned measurements. Role, method and features of radiative corrections applied in the analyses are presented. Future prospects of the spin physics are reviewed.
We demonstrate single spin spectroscopy of a fluorescent tumbling defect in silicon called the G center, behaving as a pseudo-molecule randomly reorienting itself in the crystalline matrix. Using high-resolution spin spectroscopy, we reveal…
We show how the small perturbations of a linear cocycle have a relative rotation number associated with an invariant measure of the base dynamics an with a $2$-dimensional bundle of the finest dominated splitting (provided that some…
A correlation between the symmetry of NMR spectra, including higher-order spectra, and the properties of the spin system has been established. It is shown that for a spectrum to be symmetric about the mid-resonance frequency ({\nu}0), two…
Spin and pseudospin symmetries in the spectra of nucleons and antinucleons are studied in a relativistic mean-field theory with scalar and vector Woods-Saxon potentials, in which the strength of the latter is allowed to change. We observe…
Molecular rotation spectra, generated by the coupling of the molecular electric-dipole moments to an external time-dependent electric field, are discussed in a few particular conditions which can be of some experimental interest. First, the…
We investigate the dynamics of a rotating Morse wave packet, appropriate for a ro-vibrating diatomic molecule. The coupling between vibrational and rotational degrees of freedom is explicated in real position space as well as in phase space…
We present a theoretical study of the impact of an electric field combined with a magnetic field on the rotational dynamics of open shell diatomic molecules. Within the rigid rotor approximation, we solve the time-independent Schr\"odinger…
The dynamics of non-polar diatomic molecules interacting with a far-detuned narrow-band laser field, that only may drive rotational transitions, is studied. The rotation of the molecule is considered both classically and quantum…
Optical fluorescence imaging is capable of measuring both the spatial and rotational dynamics of single molecules. However, unavoidable measurement noise will result in inaccurate estimates of rotational dynamics, causing a molecule to…
It is proposed that nuclear (or electron) spins in a trapped molecule would be well isolated from the environment and the state of each spin can be measured by means of mechanical detection of magnetic resonance. Therefore molecular traps…
Spectra of methyl cyanide were recorded to analyze interactions in low-lying vibrational states and to construct line lists for radio astronomical observations as well as for infrared spectroscopic investigations of planetary atmospheres.…
The phenomenon of molecular optical activity manifests itself as the rotation of the plane of linear polarization when light passes through chiral media. Measurements of optical activity and its wavelength dependence, optical rotatory…
We identify the molecular ion NH^+ as a potential candidate for probing variations in the fine structure constant alpha and electron-to-proton mass ratio mu. NH^+ has an anomalously low-lying excited Sigma state, being only a few hundred…
It is shown that particle motion in a bent (straight) crystal is accompanied by particle spin rotation and oscillations that allows to measure the tensor electric and magnetic polarizabilities of nuclei and elementary particles. It is shown…
Line-by-line calculations are becoming the standard procedure for carrying spectral simulations. However, it is important to insure the accuracy of such spectral simulations through the choice of adapted models for the simulation of key…
It is widely admitted that the helical conformation of certain chiral molecules may induce a sizable spin selectivity observed in experiments. Spin selectivity arises as a result of the interplay between a helicity-induced spin-orbit…
Quantum particles, such as spins, can be used for communicating spatial directions to observers who share no common coordinate frame. We show that if the emitter's signals are the orbit of a group, then the optimal detection method may not…