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We introduce a novel coarse-grained bead-spring model for flexible polymers to systematically examine the effects of an adjusted bonded potential on the formation and stability of structural macrostates in a thermal environment. The density…

Biological Physics · Physics 2019-02-11 Kai Qi , Benjamin Liewehr , Tomas Koci , Busara Pattanasiri , Matthew J. Williams , Michael Bachmann

We perform Monte Carlo simulations to study the elastic properties of the helix-coil worm-like chain model of alpha-helical polypeptides. In this model the secondary structure enters as a scalar (Ising like) variable that controls the local…

Soft Condensed Matter · Physics 2007-05-23 Buddhapriya Chakrabarti , Alex J. Levine

In this paper we study a model describing a copolymer in a micro-emulsion. The copolymer consists of a random concatenation of hydrophobic and hydrophilic monomers, the micro-emulsion consists of large blocks of oil and water arranged in a…

Probability · Mathematics 2016-10-03 Frank den Hollander , Nicolas Pétrélis

Amphiphilic block copolymer solutions form various micellar structures including micelles and vesicles. We applied the density functional theory for block copolymers which we have proposed to amphiphilic block copolymer systems. The 3…

Soft Condensed Matter · Physics 2007-05-23 Takashi Uneyama , Masao Doi

Diffusion in an evolving environment is studied by continuos-time Monte Carlo simulations. Diffusion is modelled by continuos-time random walkers on a lattice, in a dynamic environment provided by bubbles between two one-dimensional…

Soft Condensed Matter · Physics 2010-11-22 Janne Juntunen , Juha Merikoski

Synthetic copolymers and biopolymers, such as polypeptides and double-stranded DNA, often exhibit strong variations in bending stiffness along their contour, which can significantly impact conformational behavior at larger scales. To…

Soft Condensed Matter · Physics 2025-11-04 Yannick Witzky , Friederike Schmid , Arash Nikoubashman

Monte Carlo simulations of the Asakura-Oosawa (AO) model for colloid-polymer mixtures confined between two parallel repulsive structureless walls are presented and analyzed in the light of current theories on capillary condensation and…

Soft Condensed Matter · Physics 2009-11-13 Andres De Virgiliis , Richard L. C. Vink , Jürgen Horbach , Kurt Binder

We perform numerical simulations of isolated, partially active polymers, driven out-of-equilibrium by a fraction of their monomers. We show that, if the active beads are all gathered in a contiguous block, the position of the section along…

Soft Condensed Matter · Physics 2023-09-04 Marin Vatin , Sumanta Kundu , Emanuele Locatelli

We consider the adsorption kinetics of a regular block-copolymer of total length $N$ and block size $M$ at a selective liquid-liquid interface in the limit of strong localization. We propose a simple analytic theory based on scaling…

Soft Condensed Matter · Physics 2007-05-23 Andrea Corsi , Andrey Milchev , Vakhtang G. Rostiashvili , Thomas A. Vilgis

We study random copolymers consisted of two kinds of monomers with attraction between similar kinds. The mean field analysis of this system indicates a continuous phase transition into a phase with periodic microdomain structure. It is…

Condensed Matter · Physics 2009-10-22 A. M. Gutin , C. D. Sfatos , E. I. Shakhnovich

Computer simulation studies on the miscibility behavior and single chain properties in binary polymer blends are reviewed. We consider blends of various architectures in order to identify important architectural parameters on a coarse…

Statistical Mechanics · Physics 2007-05-23 Marcus Mueller

The structure of a polystyrene matrix filled with tightly cross-linked polystyrene nanoparticles, forming an athermal nanocomposite system, is investigated by means of a Monte Carlo sampling formalism. The polymer chains are represented as…

Soft Condensed Matter · Physics 2014-01-17 Georgios G. Vogiatzis , Evangelos Voyiatzis , Doros N. Theodorou

This report deals with phase transition in Bond Fluctuation Model (BFM) of a linear homo polymer on a two dimensional square lattice. Each monomer occupies a unit cell of four lattice sites. The condition that a lattice site can at best be…

Soft Condensed Matter · Physics 2012-04-16 Hima Bindu Kolli , K. P. N. Murthy

As an extension of the former study on 2-dimensional systems, we simulate phase behavior of polymer-grafted colloidal particles in 3 dimensions by molecular Monte Carlo technique in the canonical ensemble. We use a spherically symmetric…

Soft Condensed Matter · Physics 2014-04-02 Yuki Norizoe , Toshihiro Kawakatsu

We consider orientation mechanisms for block copolymers in an electric field. Theoretical and experimental studies have shown that nonuniformity of the dielectric constant gives rise to a preferred orientation of the melt with respect to…

Soft Condensed Matter · Physics 2009-11-10 Y. Tsori , F. Tournilhac , L. Leibler

Using a combination of analytical theory, Monte Carlo simulations, and three dimensional self-consistent field calculations, we study the equilibrium properties and the switching behavior of adsorption-active polymer chains included in a…

Soft Condensed Matter · Physics 2017-11-01 Shuanhu Qi , Leonid I. Klushin , Alexander M. Skvortsov , Alexey A. Polotsky , Friederike Schmid

Monte Carlo computer simulations are used to study the segregation behaviour of two polymers under cylindrical confinement. Using a multiple-histogram method, the conformational free energy, F, of the polymers was measured as a function of…

Soft Condensed Matter · Physics 2018-05-24 James M. Polson , Deanna R. -M. Kerry

The classical bond-fluctuation model (BFM) is an efficient lattice Monte Carlo algorithm for coarse-grained polymer chains where each monomer occupies exclusively a certain number of lattice sites. In this paper we propose a generalization…

Soft Condensed Matter · Physics 2009-08-12 J. P. Wittmer , A. Cavallo , T. Kreer , J. Baschnagel , A. Johner

Polymers confined to a narrow channel are subject to strong entropic forces that tend to drive the molecules apart. In this study, we use Monte Carlo computer simulations to study the segregation behavior of two flexible hard-sphere…

Soft Condensed Matter · Physics 2021-01-27 James M. Polson , Qinxin Zhu

Exact bounds are obtained for the quenched free energy of a polymer with random hydrophobicities in the presence of an interface separating a polar from a non polar solvent. The polymer may be ideal or have steric self-interactions. The…

Statistical Mechanics · Physics 2007-05-23 A. Maritan , M. P. Riva , A. Trovato
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