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We propose an integrated surface enhanced Raman scattering (SERS) chip based on liquid-core waveguide with total reflection, through which the depression of leaky mode enable a long propagating distance. An Raman enhancement factor for…

Optics · Physics 2015-12-08 Chunhong Lai , Gang Chen , Li Chen , Junhui Li , Qinghao Liu , Yi Xu

Single-molecule detection with chemical specificity is a powerful and much desired tool for biology, chemistry, physics, and sensing technologies. Surface-enhanced spectroscopies enable single molecule studies, yet reliable substrates of…

Mesoscale and Nanoscale Physics · Physics 2008-02-22 D. R. Ward , N. K. Grady , C. S. Levin , N. J. Halas , Y. Wu , P. Nordlander , D. Natelson

Surface-enhanced Raman scattering (SERS) combines analyte-specificity and single-molecule sensitivity, but its potential is limited by slow readout where sophisticated nanosensors are analysed in a serial fashion, one particle at a time. We…

A periodic arrangement of chains of gold discs shows pronounced plasmonic grating resonances. These have a clear impact on the Surface Enhanced Raman Scattering (SERS)-signal from 4-methylbenzenethiol molecules which form self-assembled…

We present a self-consistent quantum optics approach to calculating the surface enhanced Raman spectrum of molecules coupled to arbitrarily shaped plasmonic systems. Our treatment is intuitive to use and provides fresh analytical insight…

Optics · Physics 2017-06-26 Mohsen Kamandar Dezfouli , Stephen Hughes

A theory of electron spin-flip Raman scattering (SFRS) is presented that describes the Raman spectral signals shifted by both single and twice the electron Zeeman energy under nearly resonant excitation of the heavy hole excitons in…

Mesoscale and Nanoscale Physics · Physics 2021-01-04 A. V. Rodina , E. L. Ivchenko

Nanoscale gaps between adjacent metallic nanostructures give rise to extraordinarily large field enhancements, known as "hot spots", upon illumination. Incident light with the electric field polarized across the gap (along the interparticle…

Mesoscale and Nanoscale Physics · Physics 2013-03-27 Joseph B. Herzog , Mark W. Knight , Yajing Li , Kenneth M. Evans , Naomi J. Halas , Douglas Natelson

A quantum-mechanical model to calculate the electron energy-loss spectra (EELS) for the system of a closely located metallic nanoshell and a molecule has been developed. At the resonance between the molecular excitation and plasmon modes in…

Atomic Physics · Physics 2014-10-07 I. Yu. Goliney , Ye. V. Onykienko

The problem of enhanced molecular emission in close proximity to dielectric and metallic interfaces is of great importance for many physical and biological applications. Here we present an exact treatment of the problem from the view point…

Optics · Physics 2022-11-10 Dentcho A Genov

In this study, we combined the surface-enhanced Raman scattering (SERS) with density functional theory (DFT) calculations to investigate the SERS spectra of lanthanide (Ln)-citrate complexes (Ln = La, Ce, Pr, Nd, Sm, Eu, and Gd) under 488,…

Chemical Physics · Physics 2025-03-25 Hao Jin , Tamitake Itoh , Yuko S. Yamamoto

Chiral nanophotonic platforms provide a means of creating near fields with both enhanced asymmetric properties and intensities. They can be exploited for optical measurements that allow enantiomeric discrimination at detection levels…

The exact analytical solution of Maxwell equations for a Bessel light beam scattered by a sphere is found. Scattered power, stored energy and a generalized Q factor as a function of frequency, the sphere radius, permittivity, and the Bessel…

Optics · Physics 2020-08-26 Vasily Klimov

Exceptional points (EPs), singularities of non-Hermitian physics where complex spectral resonances degenerate, are one of the most exotic features of nonequilibrium open systems with unique properties. For instance, the emission rate of…

The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some models of rough metal surfaces and of some features of the dipole…

Optics · Physics 2011-10-18 A. M. Polubotko

Discriminating the low-abundance hydroxylated proline from hydroxylated proline is crucial for monitoring diseases and eval-uating therapeutic outcomes that require single-molecule sensors. While the plasmonic nanopore sensor can detect the…

Chemical Physics · Physics 2024-12-30 Yingqi Zhao , Kuo Zhan , Pei-Lin Xin , Zuyan Chen , Shuai Li , Francesco De Angelis , Jianan Huang

Surface-enhanced Raman spectroscopy (SERS) using gold-nanorod-dimer nanoantennas has shown great potential in various applications. This reflects in their large values of the customary figure of merit of SERS: the enhancement factor (EF),…

We analyze Photo-Electron Spectra (PES) for a variety of excitation mechanisms from a simple mono-frequency laser pulse to involved combination of pulses as used, e.g., in attosecond experiments. In the case of simple pulses, the peaks in…

Atomic and Molecular Clusters · Physics 2015-05-20 C. -Z. Gao , P. M. Dinh , P. -G. Reinhard , E. Suraud

We introduce a class of distributions which may be considered as a smoothed probabilistic version of the ultrametric property that famously characterizes the Gibbs distributions of various spin glass models. This class of \emph{high-entropy…

Computational Complexity · Computer Science 2024-10-08 Juspreet Singh Sandhu , Jonathan Shi

Hotspots of surface-enhanced resonance Raman scattering (SERRS) are localized within 1 nm at gaps or crevices of plasmonic nanoparticle (NP) dimers. We demonstrate SERRS hotspots with volumes that are extended in one dimension tens of…

Coherent propagation of two interacting particles in $1d$ weak random potential is considered. An accurate estimate of the matrix element of interaction in the basis of localized states leads to mapping onto the relevant matrix model. This…

Statistical Mechanics · Physics 2009-10-28 I. V. Ponomarev , P. G. Silvestrov