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Attosecond pump-probe ionization process can be used to prepare atomic ions in the coherent superposition of states with opposite parity. The multiphoton shake-up ionization of Helium, in particular, generates ions with same principal…

Atomic Physics · Physics 2019-12-12 Saad Mehmood , Eva Lindroth , Luca Argenti

If the electrons in a plasma are suddenly heated, the resulting change in Debye shielding causes the ion kinetic energy to quickly increase. For the first time, this correlation heating, which is much faster than collisional energy…

Plasma Physics · Physics 2023-05-08 Thomas E. Foster , Henry Fetsch , Nathaniel J. Fisch

Anions and radicals are important for many applications including environmental chemistry, semiconductors, and charge transfer, but are poorly described by the available approximate energy density functionals. Here we test an approximate…

Chemical Physics · Physics 2015-06-18 André Mirtschink , C. J. Umrigar , John D. Morgan , Paola Gori-Giorgi

The ionization of two-active-electron systems by intense laser fields is investigated theoretically. In comparison with time-dependent Hartree-Fock and exact two electron simulation, we show that the ionization rate is overestimated in SAE…

Atomic Physics · Physics 2015-06-18 Zengxiu Zhao , Jianmin Yuan

The time-dependent Schr\"{o}dinger equation for the hydrogen atom and its interaction with coherent intense high-frequency short laser pulses is solved numerically exactly by propagating the single-electron wave packets. Thereby, the…

Atomic Physics · Physics 2013-09-11 Philipp V. Demekhin , David Hochstuhl , Lorenz S. Cederbaum

In this work we study the single ionization of hydrogen and helium by the impact of a punctual Coulomb projectile. To interpretate the cross section we introduce a series of Pad\'{e} approximant. The nodes of the denominator of the Pad\'{e}…

Atomic Physics · Physics 2020-11-23 J. E. Miraglia

The ionization dynamics of a two-electron atom in an attosecond XUV-infrared pump-probe experiment is simulated by solving the time-dependent two-electron Schr\"odinger equation. A dramatic change of the double ionization (DI) yield with…

Atomic Physics · Physics 2010-11-29 S. Bauch , K. Balzer , M. Bonitz

We derive a local approximation for the correlation energy in two-dimensional electronic systems. In the derivation we follow the scheme originally developed by Colle and Salvetti for three dimensions, and consider a Gaussian approximation…

Strongly Correlated Electrons · Physics 2008-11-21 S. Pittalis , E. Rasanen , M. Marques

We report on coulomb explosion imaging of the wavefunction of the quantum halo system He$_2$. Each atom of this system is ionized by tunnelionization in a femto second laser pulse and in a second experiment by single photon ionization…

This paper concerns the theory of non-recollisional ionization or detachment of atoms or ions by intense few-cycle pulses. It is shown that in certain conditions of pulse duration, peak intensity and carrier-envelope phase, the ionization…

Atomic Physics · Physics 2014-09-04 C. C. Chirila , R. M. Potvliege

The particle-hole interaction problem is longstanding within time-dependent density functional theory (TDDFT) and leads to extreme errors in the prediction of K-edge X-ray absorption spectra (XAS). We derive a linear-response formalism that…

Chemical Physics · Physics 2022-10-18 Kevin Carter-Fenk , Leonardo A. Cunha , Juan E. Arias-Martinez , Martin Head-Gordon

A fully relativistic calculation of the double photoionization of helium-like atoms is presented. The approach is based on the partial-wave representation of the Dirac continuum states and accounts for the retardation in the…

Atomic Physics · Physics 2015-05-30 V. A. Yerokhin , A. Surzhykov

We have studied the intensity correlations between two orthogonally linearly polarized components of a laser field propagating through a resonant atomic medium. These experiments have been performed in a Rubidium atomic vapor. We observe…

Using a three-dimensional quasiclassical technique we explore molecular double ionization by a linearly polarized, infrared (800 nm) and ultrashort (6 fs) laser pulse. We first focus on intensities corresponding to the tunneling regime and…

Atomic Physics · Physics 2015-05-14 A. Emmanouilidou , A. Staudte

We present a new class of non-adiabatic approximations in time-dependent density functional theory derived from an exact expression for the time-dependent exchange-correlation potential. The approximations reproduce dynamical step and peak…

Chemical Physics · Physics 2018-12-21 Lionel Lacombe , Neepa T. Maitra

An approach to electron correlation effects in atoms that uses quantum trajectories is presented. A comparison with the exact quantum mechanical results for 1D Helium atom shows that the major features of the correlated ground state…

Atomic Physics · Physics 2025-02-07 Ivan P. Christov

Correlated anion and cation motion can significantly reduce the overall ion conductivity in electrolytes versus the ideal conductivity calculated based on the diffusion constants alone. Using coarse-grained molecular dynamics simulations,…

Soft Condensed Matter · Physics 2020-06-01 Kuan-Hsuan Shen , Lisa M. Hall

Stochastic properties of loading and loss mechanism in a few atom trap are analyzed. An approximate formula is derived for the atom-number correlation function for the trapped atoms in the limit of reasonably small two-atom loss rate.…

Atomic Physics · Physics 2007-05-23 Youngwoon Choi , Seokchan Yoon , Sungsam Kang , Woongnae Kim , Jai-Hyung Lee , Kyungwon An

We consider the process of double photoionization (DPI) in a rare gas atom as a two-step process, namely (i) photoionization in an inner shell followed by (ii) the emission of an Auger electron from an outer shell. An angular correlation…

Atomic Physics · Physics 2009-11-07 Dipankar Chattarji , Chiranjib Sur

The adiabatic connection formula of ground-state density functional theory relates the correlation energy to a coupling-constant integral over a purely potential contribution, and is widely used to understand and improve approximations. The…

Chemical Physics · Physics 2016-06-01 Aurora Pribram-Jones , Kieron Burke