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Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a…

Quantum Physics · Physics 2021-05-25 Paolo Facchi , Giovanni Gramegna , Arturo Konderak

A formalism for the study of highly interacting electronic systems is presented. The proposed scheme is based on two key concepts: composite operators and algebra constraints. Composite field operators, that naturally appear as a…

Strongly Correlated Electrons · Physics 2009-11-10 Ferdinando Mancini

We use quantum harmonic analysis for densely defined operators to provide a simplified proof of the Berger-Coburn theorem for boundedness of Toeplitz operators. In addition, we revisit compactness and Schatten-class membership of densely…

Functional Analysis · Mathematics 2025-08-20 Vishwa Dewage , Mishko Mitkovski

The probability operator is derived from first principles for an equilibrium quantum system. It is also shown that the superposition states collapse into a mixture of states giving the conventional von Neumann trace form for the quantum…

Statistical Mechanics · Physics 2014-01-09 Phil Attard

Starting with an operator in the universal enveloping algebra of a semi-simple, complex Lie group the nearest neighbor statistics of the spectra of this operator along a sequence of representations are discussed. After a short introduction…

Representation Theory · Mathematics 2007-05-23 Ingolf Schäfer

Functionals of the one-body reduced density matrix (1-RDM) are routinely minimized under Coleman's ensemble $N$-representability conditions. Recently, the topic of pure-state $N$-representability conditions, also known as generalized Pauli…

Chemical Physics · Physics 2015-05-05 Iris Theophilou , Nektarios N. Lathiotakis , Miguel A. L. Marques , Nicole Helbig

Hubertus J. J. van Dam [Phys. Rev. A 93, 052512, 2016] claims that the one-particle reduced density matrix (1RDM) of an interacting system can be represented by means of a single-determinant wavefunction of fictitious non-interacting…

Chemical Physics · Physics 2017-10-20 Mario Piris , Katarzyna Pernal

Ando established an algebraic criterion for when a complex orientation for a Morava E-theory is an $H_\infty$-map. The criterion relates such an orientation to a specific property of the formal group associated to the E-theory, namely, a…

Algebraic Topology · Mathematics 2023-10-17 Hongxiang Zhao

We develop the theory of integrable operators $\mathcal{K}$ acting on a domain of the complex plane with smooth boundary in analogy with the theory of integrable operators acting on contours of the complex plane. We show how the resolvent…

Mathematical Physics · Physics 2023-08-17 Marco Bertola , Tamara Grava , Giuseppe Orsatti

Koopmans-compliant functionals provide an orbital-density-dependent framework for an accurate evaluation of spectral properties; they are obtained by imposing a generalized piecewise-linearity condition on the total energy of the system…

Materials Science · Physics 2022-07-06 Riccardo De Gennaro , Nicola Colonna , Edward Linscott , Nicola Marzari

We report benchmark results for one-dimensional (1D) atomic and molecular systems interacting via the Coulomb operator $|x|^{-1}$. Using various wavefunction-type approaches, such as Hartree-Fock theory, second- and third-order…

Chemical Physics · Physics 2015-06-19 Pierre-François Loos , Caleb J. Ball , Peter M. W. Gill

In this paper, we present a completely rigorous formulation of Kohn-Sham density functional theory for spinless fermions living in one dimensional space. More precisely, we consider Schr\"odinger operators of the form $H_N(v,w) = -\Delta +…

Mathematical Physics · Physics 2026-03-24 Thiago Carvalho Corso

A double-atom partitioning of the molecular one-electron density matrix is used to describe atoms and bonds. All calculations are performed in Hilbert space. The concept of atomic weight functions (familiar from Hirshfeld analysis of the…

We present a general multi-component density functional theory in which electrons and nuclei are treated completely quantum mechanically, without the use of a Born-Oppenheimer approximation. The two fundamental quantities in terms of which…

Materials Science · Physics 2007-05-23 Thomas Kreibich , Robert van Leeuwen , E. K. U. Gross

Quantum dots with conduction electrons or holes originating from several bands are considered. We assume the particles are confined in a harmonic potential and assume the electrons (or holes) belonging to different bands to be different…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 K. Karkkainen M. Koskinen , S. M. Reimann , M. Manninen

One approach to multivariate operator theory involves concepts and techniques from algebraic and complex geometry and is formulated in terms of Hilbert modules. In these notes we provide an introduction to this approach including many…

Functional Analysis · Mathematics 2007-11-28 Ronald G. Douglas

For three standard models of commutative algebras generated by Toeplitz operators in the weighted analytic Bergman space on the unit disk, we find their representations as the algebras of bounded functions of certain unbounded self-adjoint…

Functional Analysis · Mathematics 2022-03-09 Grigori Rozenblum , Nikolai Vasilevski

The study of mathematical connections between operator-theoretic formulations of classical dynamics and quantum mechanics began at least as early as the 1930s in work of Koopman and von Neumann and was developed in later decades by many…

Dynamical Systems · Mathematics 2026-03-23 Dimitrios Giannakis , Michael Montgomery

Every unital nonselfadjoint operator algebra possesses canonical and functorial classes of faithful (even completely isometric) Hilbert space representations satisfying a double commutant theorem generalizing von Neumann's classical result.…

Operator Algebras · Mathematics 2007-05-23 David P. Blecher , Baruch Solel

The expression for the density operator of the damped harmonic oscillator is derived from the master equation in the framework of the Lindblad theory for open quantum systems. Then the von Neumann entropy and effective temperature of the…

Quantum Physics · Physics 2007-05-23 A. Isar