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Spectroscopy is a unique experimental tool for measuring the fundamental Casimir-Polder interaction between excited state atoms, or other polarizable quantum objects, and a macroscopic surface. Spectroscopic measurements probe atoms at…

We discuss different physical effects related to the uniform acceleration of atoms in vacuum, in the framework of quantum electrodynamics. We first investigate the van der Waals/Casimir-Polder dispersion and resonance interactions between…

Quantum Physics · Physics 2017-08-24 M. Lattuca , J. Marino , A. Noto , R. Passante , L. Rizzuto , S. Spagnolo , W. Zhou

Dispersion interactions are long-range interactions between neutral ground-state atoms or molecules, or polarizable bodies in general, due to their common interaction with the quantum electromagnetic field. They arise from the exchange of…

Quantum Physics · Physics 2018-12-13 Roberto Passante

The central topic of this letter is to show that light-matter hybridization not only gives rise to novel dynamic responses but can also modify intermolecular interactions and induce new structural order. Using the van der Waals (vdW) system…

Quantum Physics · Physics 2023-10-20 Jianshu Cao , Eli Pollak

We compute the interaction energies of a two-atom system placed in the middle of a perfectly reflecting planar cavity, in the perturbative regime. Explicit expressions are provided for the van der Waals potentials of two polarisable atomic…

Quantum Physics · Physics 2017-11-01 M. Donaire , J. M. Muñoz-Castañeda , L. M. Nieto

We study the mutual interactions of simple, parallel polymers and nanotubes, and develop a scheme to include the van der Waals interactions in the framework of density functional theory (DFT) for these molecules at intermediate to…

Soft Condensed Matter · Physics 2007-05-23 Jesper Kleis , Per Hyldgaard , Elsebeth Schroder

The modified static exchange model (MSEM) recently introduced by Ray [1] to study two-atomic collision processes at low and cold-energies, is used for detailed analysis of the long-range effects due to induced dipole-dipole van der Waals…

Atomic Physics · Physics 2015-05-06 Hasi Ray , Anuradha De , Deparpita Ray

Quantum dot (QD) assemblies are nanostructured networks made from aggregates of QDs and feature improved charge and energy transfer efficiencies compared to discrete QDs. Using first-principles many-body perturbation theory, we…

Materials Science · Physics 2022-10-25 Sandip Aryal , Joseph Frimpong , Zhen-Fei Liu

The van der Waals (vdW) interaction plays a prominent role between neutral objects at separations where short ranged chemical forces are negligible. This type of dispersive coupling is determined by the interplay between geometry and…

Mesoscale and Nanoscale Physics · Physics 2022-06-02 Dai-Nam Le , Pablo Rodriguez-Lopez , Lilia M. Woods

Effects of two-body dipolar interactions on the effective permittivity/conductivity of a binary, symmetric, random dielectric composite are investigated in a self-consistent framework. By arbitrarily splitting the singularity of the Green…

Disordered Systems and Neural Networks · Physics 2012-06-06 Yves-Patrick Pellegrini , François Willot

Van der Waals forces as interactions between neutral and polarisable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum…

Chemical Physics · Physics 2019-06-05 Johannes Fiedler , Clas Persson , Mathias Boström , Stefan Y. Buhmann

We report a new technique to determine the van der Waals coeffcients of lithium (Li) atoms based on the relativistic coupled-cluster theory. These quantities are determined using the imaginary parts of the scalar dipole and quadrupole…

Atomic Physics · Physics 2009-11-13 L. W. Wansbeek , B. K. Sahoo , R. G. E. Timmermans , B. P. Das , D. Mukherjee

The long-range interactions of two atoms, of an atom and a dielectric wall, of an atom and a perfectly conducting wall, and of an atom between two perfectly conducting walls are calculated, including the effects of retardation, for Li using…

Atomic Physics · Physics 2008-02-03 Zong-Chao Yan , A. Dalgarno , J. F. Babb

Alkaline-earth-like transition-metal atoms such as Zn and Cd are promising candidates for precision measurements and quantum many-body physics experiments. Here, we theoretically investigate the properties of diatomic molecules containing…

Atomic Physics · Physics 2021-11-02 Klaudia Zaremba-Kopczyk , Michał Tomza

The three body (triple dipole) interaction of Axilrod, Teller and Muto (ATM) contributes 5 to 10 % of the total energy of condensed phases of inert elements. It is shown in this paper for clusters and films that a much larger or smaller ATM…

Soft Condensed Matter · Physics 2009-11-10 Silvina M. Gatica , M. Mercedes Calbi , Milton W. Cole , Darrell Velegol

Using perturbative QED we show that, while the retarded dispersive force between an electrically polarizable atom and a magnetically polarizable one is proportional to $1/r^{8}$, where $r$ is the distance between the atoms, the non-retarded…

High Energy Physics - Theory · Physics 2007-05-23 C. Farina , F. C. Santos , A. C. Tort

We present a generalization of the recently proposed variational cluster perturbation theory to extended Hubbard models at half filling with repulsive nearest neighbor interaction. The method takes into account short-range correlations…

Strongly Correlated Electrons · Physics 2009-11-10 M. Aichhorn , H. G. Evertz , W. von der Linden , M. Potthoff

This paper presents our current measurements in a vapor nanocell aiming at a test of the distance-dependence of the atom-surface interaction, when simple asymptotic descriptions may turn to be not valid. A state-of-the-art of atom-surface…

We present a systematic study of interaction induced dipole electric properties of all molecular dimers in the S66 set, relying on CCSD(T)-F12b/aug-cc-pVDZ-F12 as reference level of theory. For field strengths up to $\approx$5 GV m$^{-1}$…

Chemical Physics · Physics 2021-12-22 Max Schwilk , Pál D. Mezei , Diana N. Tahchieva , O. Anatole von Lilienfeld

We studied the van der Waals interactions of two finite, solid, cylindrical rods at arbitrary angle and position with respect to each other. An analytic interpolative formula for the interaction potential energy is constructed, based on…

Soft Condensed Matter · Physics 2018-10-03 Jack A. Logan , Alexei V. Tkachenko