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Polar molecules are desirable systems for quantum simulations and cold chemistry. Molecular ions are easily trapped, but a bias electric field applied to polarize them tends to accelerate them out of the trap. We present a general solution…

We propose a scheme to transfer molecules from a slow beam into an optical trap using only a single photon absorption and emission cycle. The efficiency of such a scheme is numerically explored for BaF using realistic experimental…

A detailed treatment of an electro-optical trap for polar molecules, realized by embedding an optical trap within a uniform electrostatic field, is presented and the trap's properties analyzed and discussed. The electro-optical trap offers…

Atomic Physics · Physics 2022-06-15 Bretislav Friedrich

We demonstrate the deceleration of heavy polar molecules in low-field seeking states by combining a cryogenic source and a travelling-wave Stark decelerator. The cryogenic source provides a high intensity beam with low speed and…

A continuously operated electrostatic trap for polar molecules is demonstrated. The trap has a volume of ~0.6 cm^3 and holds molecules with a positive Stark shift. With deuterated ammonia from a quadrupole velocity filter, a trap density of…

Chemical Physics · Physics 2007-05-23 T. Rieger , T. Junglen , S. A. Rangwala , P. W. H. Pinkse , G. Rempe

We revisit the operation of the Stark decelerator and present a new, optimized operation scheme, which substantially improves the efficiency of the decelerator at both low and high final velocities, relevant for trapping experiments and…

Chemical Physics · Physics 2016-03-22 Dongdong Zhang , Nicolas Vanhecke , Gerard Meijer

A method for decelerating a continuous beam of neutral polar molecules is theoretically demonstrated. This method utilizes non-uniform, static electric fields and regions of adiabatic population transfer to generate a mechanical force that…

Atomic Physics · Physics 2015-05-13 Eric R. Hudson

Laser cooling of molecules employing broadband optical pumping involves a timescale separation between laser excitation and spontaneous emission. Here, we optimize the optical pumping step using shaped laser pulses. We derive two…

Quantum Physics · Physics 2013-12-24 Daniel M. Reich , Christiane P. Koch

We report on the production of a pulsed molecular beam of metastable NH ($a ^1\Delta$) radicals and present first results on the Stark deceleration of the NH ($a ^1\Delta, J=2, M\Omega=-4$) radicals from 550 m/s to 330 m/s. The decelerated…

We propose a modified Stark-chirped rapid adiabatic passage technique for a robust rovibrational population transfer in the gas phase molecules in the presence of certain inhomogeneous electric fields. As an example application, the new…

Atomic Physics · Physics 2025-06-06 Emil Zak , Jochen Küpper , Andrey Yachmenev

Recently, a decelerator for neutral polar molecules has been presented that operates on the basis of macroscopic, three-dimensional, traveling electrostatic traps (Osterwalder et al., Phys. Rev. A 81, 051401 (2010)). In the present paper, a…

Nitric oxide (NO) molecules initially traveling at 795 m/s in pulsed supersonic beams have been photoexcited to long-lived hydrogenic Rydberg-Stark states, decelerated and electrostatically trapped in a cryogenically cooled, chip-based…

Chemical Physics · Physics 2020-09-21 A. Deller , M. H. Rayment , S. D. Hogan

Selection of "magic" trapping conditions with ultracold atoms or molecules, where pairs of internal states experience identical trapping potentials, brings substantial benefits to precision measurements and quantum computing schemes.…

Quantum Physics · Physics 2011-01-04 Svetlana Kotochigova , David DeMille

The Stark deceleration of OH radicals in both low-field-seeking and high-field-seeking levels of the rovibronic ${}^2\Pi_{3/2},v=0,J=3/2$ ground state is demonstrated using a single experimental setup. Applying alternating-gradient…

Chemical Physics · Physics 2008-09-18 Kirstin Wohlfart , Frank Filsinger , Fabian Grätz , Jochen Küpper , Gerard Meijer

We describe the production of cold, slow-moving LiH molecules. The molecules are produced in the ground state using laser ablation and supersonic expansion, and 68% of the population is transferred to the rotationally excited state using…

Atomic Physics · Physics 2015-05-13 S. K. Tokunaga , J. M. Dyne , E. A. Hinds , M. R. Tarbutt

A microstructured array of 1254 electrodes on a substrate has been configured to generate an array of local minima of electric field strength with a periodicity of 120 $\mu$m about 25 $\mu$m above the substrate. By applying sinusoidally…

Atomic Physics · Physics 2009-05-20 Samuel A Meek , Horst Conrad , Gerard Meijer

The large electric dipole moments associated with highly excited Rydberg states of atoms and molecules make gas-phase samples in these states very well suited to deceleration and trapping using inhomogeneous electric fields. The methods of…

Atomic Physics · Physics 2016-03-16 Stephen D. Hogan

We present an experimental realization of a moving magnetic trap decelerator, where paramagnetic particles entrained in a cold supersonic beam are decelerated in a co-moving magnetic trap. Our method allows for an efficient slowing of both…

Atomic physics was revolutionized by the development of forced evaporative cooling: it led directly to the observation of Bose-Einstein condensation, quantum-degenerate Fermi gases, and ultracold optical lattice simulations of condensed…

Atomic Physics · Physics 2015-06-11 Benjamin K. Stuhl , Matthew T. Hummon , Mark Yeo , Goulven Quéméner , John L. Bohn , Jun Ye

We propose and analyze an electrostatic-optical nano-scale trap for cold diatomic polar molecules. The main ingredient of our proposal is an square-array of ferroelectric nano-rods {with alternating polarization}. We show that, in contrast…

Quantum Gases · Physics 2018-02-21 Omjyoti Dutta , Geza Giedke