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We have performed full-relativistic density functional theory calculations to study the geometry and binding energy of different isomers of free platinum clusters Pt$_{n}$ ($n=4-6$) within the spin multiplicities from singlet to nonet. The…

Atomic and Molecular Clusters · Physics 2016-07-06 Ali Sebetci

We studied the structural and the electronic properties of ionized and neutral small Au clusters via plane wave pseudopotential calculations. All except the anionic heptamer favor one-dimensional zigzag structures or two-dimensional…

Materials Science · Physics 2016-02-17 Byeong June Min , Won Chul Shin , Jae Ik Park

Gold clusters Aun of size n = 2 to 12 atoms were studied by the density-functional theory with an ab-initio pseudopotential and a generalized gradient approximation. Geometry optimizations starting from a number of initial candidate…

Other Condensed Matter · Physics 2007-05-23 Prashant K. Jain

Plutonium dihydride and trihydride show strikingly similar crystal structures when viewed as close-packed Pu planes with ABC and AB stacking, respectively. The similarity serves as a framework for density functional theory (DFT)…

Materials Science · Physics 2013-07-03 Sven P. Rudin

Magnetism in bare uncapped gold nano-clusters is explored from a density functional theory perspective with scalar relativistic effects included via the pseudo-potential. The computed electronic structures of various nano-clusters reveal…

Materials Science · Physics 2007-05-23 R. J. Magyar , V. Mujica , M. Marquez , C. Gonzalez

We study why gold forms planar and cage-like clusters while copper and silver do not. We use density functional theory and norm-conserving pseudo-potentials with and without a scalar relativistic component. For the exchange-correlation…

Other Condensed Matter · Physics 2007-05-23 Eva M. Fernandez , Jose M. Soler , L. C. Balbas

We use coupled-cluster quantum chemical methods to calculate the energetics of molecular clusters cut out of periodic molecular hydrogen structures that model observed phases of solid hydrogen. The hydrogen structures are obtained from…

Materials Science · Physics 2017-03-15 J. R. Trail , P. López Ríos , R. J. Needs

We present a detailed quantum mechanical non empirical DFT investigation of the energy-optimized geometries, phase stabilities and electronic properties of bulk Pt3N, PtN and PtN2 in a set of twenty different crystal structures. Structural…

Materials Science · Physics 2013-01-24 Mohammed S. H. Suleiman , Daniel P. Joubert

The adsorption profiles and electronic structures of Pt$_n$ (n = 1--4) clusters on stoichiometric, reduced and reconstructed rutile TiO$_2$(110) surfaces were systematically studied using on site d-d Coulomb interaction corrected hybrid…

Strongly Correlated Electrons · Physics 2011-01-06 Veysel Celik , Hatice Unal , Ersen Mete , Sinasi Ellialtioglu

The theoretical formalism of the local density approximation (LDA) to density functional theory (DFT) has been used to study the electronic and geometric structures of SimCn (1<=m, n<=4;n<=m) clusters. An all electron 6-311++G** basis set…

Atomic and Molecular Clusters · Physics 2007-05-23 Prachi Pradhan , Asok K. Ray

We study the structure and energetics of Au$_N$ clusters by means of parameter-free density-functional calculations ($N\le 8$), jellium calculations ($N\le 60$), embedded-atom calculations ($N\le 150$), and parameterized density-functional…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Denitsa Alamanova , Yi Dong , Habib ur Rehman , Michael Springborg , Valeri G. Grigoryan

Molybdenum clusters, characterised by their unique structure and intriguing catalytic properties, have gained significant attention in recent years. In several existing studies density functional theory (DFT) methods have been used to find…

Materials Science · Physics 2023-10-03 Yao Wei , Lev Kantorovich

We have investigated the lowest-energy structures and electronic properties of the Au$_n$(n=2-20) clusters based on density functional theory (DFT) with local density approximation. The small Au$_n$ clusters adopt planar structures up to…

Atomic and Molecular Clusters · Physics 2009-11-07 Jinlan Wang , Guanghou Wang , Jijun Zhao

In this work, the most stable structures of Pt5V clusters are investigated using the successive growth algorithm (SCG) in conjunction with density functional theory (DFT) calculations. The resulting structures are evaluated by various…

Materials Science · Physics 2024-08-08 P. L. Rodríguez-Kessler

The thermodynamic stabilities of various phases of the nitrides of the platinum metal elements are systematically studied using density functional theory. It is shown that for the nitrides of Rh, Pd, Ir and Pt two new crystal structures, in…

Materials Science · Physics 2010-09-03 Daniel Åberg , Babak Sadigh , Jonathan Crowhurst , Alexander F. Goncharov

We consider a system of particles interacting via a purely repulsive, soft-core potential recently introduced to model effective pair interactions between dendrimers, which is expected to lead to the formation of crystals with multiple…

Soft Condensed Matter · Physics 2015-05-11 Davide Pini

The size-dependent electronic, structural, magnetic and vibrational properties of small pure cop- per and silver clusters and their alloys with one and two palladium atoms are studied by using full-potential all-electron density functional…

The results of electronic structure calculations for a variety of palladium hydrides are presented. The calculations are based on density functional theory and used different local and semilocal approximations. The thermodynamic stability…

Materials Science · Physics 2014-11-07 Abdesalem Houari , Samir F. Matar , Volker Eyert

Systematically studying the crystal, magnetic, and electronic structures of PuGa3 with density functional theory (DFT) reveals the entanglement of the three types of structure. Magnetic structure affects the energy more strongly than…

Materials Science · Physics 2013-07-03 Sven P. Rudin

We have located the global minimum for all lead clusters with up to 160 atoms using a glue potential to model the interatomic interactions. The lowest-energy structures are not face-centred cubic as suggested previously. Rather, for N<40…

Condensed Matter · Physics 2007-05-23 Jonathan P. K. Doye , Shaun C. Hendy
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