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The non-relativistic cross section from Rayleigh scattering by hydrogen atoms in the ground state is calculated over a wide range of photon energies ($< 0.8$ keV). Evaluations are performed in terms of the real and imaginary components of…

Atomic Physics · Physics 2022-11-02 René D. Rohrmann , Matías Vera Rueda

Using both the second order correction of perturbation theory and the exact computation due to Dalgarno-Lewis, we compute the second order noncommutative Stark effect,i.e., shifts in the ground state energy of the hydrogen atom in the…

High Energy Physics - Theory · Physics 2009-11-10 Noureddine Chair , Mohammad A. Dalabeeh

Bound state properties of the four-electron lithium ion Li$^{-}$ in its ground $2^{2}S-$state and isotope-subsistuted ${}^{6}$Li$^{-}$ and ${}^{7}$Li$^{-}$ ions in their ground $2^1S-$state(s) are determined from the results of accurate,…

Atomic Physics · Physics 2015-07-16 Alexei M. Frolov , David M. Wardlaw

This work collects the spin-dependent leading-order relativistic and quantum-electrodynamical corrections for the electronic structure of atoms and molecules within the non-relativistic quantum electrodynamics framework. We report the…

Chemical Physics · Physics 2025-09-03 Péter Jeszenszki , Péter Hollósy , Ádám Margócsy , Edit Mátyus

The energy levels of hydrogen-like atom on a noncommutative phase space were studied in the framework of relativistic quantum mechanics. The leading order corrections to energy levels 2S_{1/2}, 2P_{1/2} and 2P_{3/2} were obtained by using…

Mathematical Physics · Physics 2012-02-14 Huseyin Masum , Sayipjamal Dulat , Mutallip Tohti

Large-scale relativistic configuration-interaction method combined with many-body perturbation theory is consistently applied to calculations of the energy levels of the ground and inner-L-shell excited states of berylliumlike ions in the…

High precision variational calculations in Hylleraas coordinates are presented for all singlet and triplet $P$-states of helium up to principal quantum number $n = 35$ with a uniform accuracy of 1 part in $10^{22}$ for the nonrelativistic…

Atomic Physics · Physics 2025-10-27 G. W. F. Drake , Aaron T. Bondy , Oliver P. Hallett , Benjamin C. Najem

Recent developments have seen the application of finite Gaussian basis sets to the $\alpha(Z\alpha)^{n\geq3}$ vacuum polarization. The energy shift for $s$ and $p$ electron states have been tabulated and their convergence investigated. In…

Atomic Physics · Physics 2026-04-28 Haisum Hayat , Harry M. Quiney

We calculate the energies of ground and three low lying excited states of confined helium atom centered in an impenetrable spherical box. We perform the calculation by employing variational method with two-parameter variational forms for…

Atomic Physics · Physics 2009-11-11 Arup Banerjee , C. Kamal , Avijit Chowdhury

We consider the ground state of an atom in the framework of non-relativistic qed. We assume that the ultraviolet cutoff is of the order of the Rydberg energy and that the atomic Hamiltonian has a non-degenerate ground state. We show that…

Mathematical Physics · Physics 2010-09-07 David Hasler , Ira Herbst

Density functional calculations are performed for twelve $2l2l'$n$l"$ (n$\geq$2) triply excited hollow resonance series of Li, {\em viz.,} 2s$^2$ns $^2$S$^e$, 2s$^2$np $^2$P$^o$, 2s$^2$nd $^2$D$^e$, 2p$^2$ns $^2$D$^e$,$^4$P$^e$, 2s2pns…

Chemical Physics · Physics 2015-06-16 Amlan K. Roy

The shift of atomic energy levels due to hadronic vacuum polarization is evaluated in a semiempirical way for hydrogenlike ions and for muonic hydrogen. A parametric hadronic polarization function obtained from experimental cross sections…

Quantum Physics · Physics 2022-10-19 Sören Breidenbach , Eugen Dizer , Halil Cakir , Zoltán Harman

Results of accurate computations of bound states in three- and four-electron atomic systems are discussed. Bound state properties of the four-electron lithium ion Li$^{-}$ in its ground $2^{2}S-$state are determined from the results of…

Atomic and Molecular Clusters · Physics 2016-07-08 Alexei M. Frolov , David M. Wardlaw

We compute the energy spectrum of the ground state of a 2D Dirac electron in the presence of a Coulomb potential and a constant magnetic field perpendicular to the plane where the the electron is confined. With the help of a mixed-basis…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Victor M. Villalba , Ramiro Pino

An indication of spontaneous symmetry breaking is found in the two-dimensional $\lambda\phi^4$ model, where attention is paid to the functional form of an effective action. An effective energy, which is an effective action for a static…

High Energy Physics - Theory · Physics 2009-10-30 Takanori Sugihara

Some typical kinetic energy integrals which arise in the application of extended Hylleraas-configuration interaction (E-Hy-CI) function in the framework of Rayleigh-Ritz method of variation, have been evaluated analytically for two-electron…

Atomic Physics · Physics 2018-02-01 B Padhy

We formulate the calculation of the ground-state wavefunction and energy of a system of strongly correlated electrons in terms of scattering matrices. A hierarchy of approximations is introduced which results in an incremental expansion of…

Condensed Matter · Physics 2009-10-31 P. Fulde , H. Stoll , K. Kladko

The Hylleraas-B-splines basis set is introduced in this paper, which can be used to obtain the eigenvalues and eigenstates of helium-like system's Hamiltonian. Comparing with traditional B-splines basis, the rate of convergence of our…

Atomic Physics · Physics 2017-06-21 San-Jiang Yang , Xue-Song Mei , Ting-Yun Shi , Hao-Xue Qiao

The Hylleraas coordinates $s=r_{1}+r_{2}$, $t=r_{1}-r_{2}$, $u=|{\bf r}_{1}-{\bf r}_{2}|$ are the natural coordinates for the determination of properties of the Helium atom, the positive ions of its isoelectronic sequence, and the negative…

Atomic Physics · Physics 2007-05-23 Xiao-Yin Pan , Viraht Sahni , Lou Massa

A framework for developing new approximate electronic structure methods is presented, in which the correlation energy of a many-electron system in the ground state is computed as in the single-reference second-order many-body perturbation…

Chemical Physics · Physics 2011-06-15 Dimitri Laikov