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Related papers: The correlation energy as an explicit functional o…

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The nonlocal correlation energy in the van der Waals density functional (vdW-DF) method [Phys. Rev. Lett. 92, 246401 (2004); Phys. Rev. B 76, 125112 (2007); Phys. Rev. B 89, 035412 (2014)] can be interpreted in terms of a coupling of…

Chemical Physics · Physics 2015-06-22 Per Hyldgaard , Kristian Berland , Elsebeth Schröder

A link between memory effects in quantum kinetic equations and nonequilibrium correlations associated with the energy conservation is investigated. In order that the energy be conserved by an approximate collision integral, the one-particle…

Statistical Mechanics · Physics 2007-05-23 V. G. Morozov , Gerd Ropke

The one body density matrix, momentum distribution, natural orbits and quasi hole states of 16O and 40Ca are analyzed in the framework of the correlated basis function theory using state dependent correlations with central and tensor…

Nuclear Theory · Physics 2009-11-06 A. Fabrocini , G. Co'

The explicit density (rho) dependence in the coupling coefficients of the non-relativistic nuclear energy-density functional (EDF) encodes effects of three-nucleon forces and dynamical correlations. The necessity for a coupling coefficient…

Nuclear Theory · Physics 2018-01-31 Panagiota Papakonstantinou , Tae-Sun Park , Yeunhwan Lim , Chang Ho Hyun

Density functional theory can be extended to excited states by means of a unified variational approach for passive state ensembles. This extension overcomes the restriction of the typical density functional approach to ground states, and…

Chemical Physics · Physics 2019-07-10 Tim Gould , Stefano Pittalis

In electronic structure calculations, the correlation energy is defined as the difference between the mean field and the exact solution of the non relativistic Schr\"odinger equation. Such an error in the different calculations is not…

Quantum Physics · Physics 2022-04-04 Kumar J. B. Ghosh , Sabre Kais , Dudley R. Herschbach

An important consequence which comes from noncommutativity (NC) is undoubtedly the energy density characterized by a microscopic free parameter; indeed a Trans-Planckian parameter. However, its functional form is an interesting and useful…

General Relativity and Quantum Cosmology · Physics 2017-08-08 Miguel A. Garcia-Aspeitia , J. C. Lopez-Dominguez , C. Ortiz , Sinhue Hinojosa-Ruiz , Mario A. Rodriguez-Meza

Dark energy might interact with cold dark matter in a direct, nongravitational way. However, the usual interacting dark energy models (with constant $w$) suffer from some catastrophic difficulties. For example, the $Q\propto\rho_{\rm c}$…

Cosmology and Nongalactic Astrophysics · Physics 2014-04-28 Yun-He Li , Xin Zhang

The effects of short-range correlations derived from a realistic meson-exchange potential on the single-particle density matrix in finite nuclei are investigated by analyzing the one-body density in terms of the natural orbits. Basic…

Nuclear Theory · Physics 2016-09-08 A. Polls , H. Müther , W. H. Dickhoff

In this chapter, we provide a review of ground-state Kohn-Sham density-functional theory of electronic systems and some of its extensions, we present exact expressions and constraints for the exchange and correlation density functionals,…

Chemical Physics · Physics 2022-09-12 Julien Toulouse

In the recent work of S. Sharma \emph{et al.}, (arxiv.org: arxiv:0912.1118), a single-electron spectrum associated with the natural orbitals was defined as the derivative of the total energy with respect to the occupation numbers at half…

Chemical Physics · Physics 2012-03-07 E. N. Zarkadoula , S. Sharma , J. K. Dewhurst , E. K. U. Gross , N. N. Lathiotakis

Variational and diffusion quantum Monte Carlo (VMC and DMC) methods with Slater-Jastrow-backflow trial wave functions are used to study the spin-polarized three-dimensional uniform electron fluid. We report ground state VMC and DMC energies…

Strongly Correlated Electrons · Physics 2025-11-11 Sam Azadi , N. D. Drummond , Sam. M. Vinko

As a simple model for single-file diffusion of hard core particles we investigate the one-dimensional symmetric exclusion process. We consider an open semi-infinite system where one end is coupled to an external reservoir of constant…

Statistical Mechanics · Physics 2009-11-07 J. E. Santos , G. M. Schuetz

We find the numerically exact partition potential for 1-D systems of interacting electrons designed to model diatomic molecules. At integer fragment occupations, the kinetic contribution to the partition potential develops sharp features in…

Chemical Physics · Physics 2018-11-14 Yan Oueis , Adam Wasserman

The Hohenberg-Kohn density functional was long ago shown to reduce to the Thomas-Fermi approximation in the non-relativistic semiclassical (or large-$Z$) limit for all matter, i.e, the kinetic energy becomes local. Exchange also becomes…

Materials Science · Physics 2016-08-24 Kieron Burke , Antonio Cancio , Tim Gould , Stefano Pittalis

We present a relativistic correction scheme to improve the accuracy of 1s core-level binding energies calculated from Green's function theory in the $GW$ approximation, which does not add computational overhead. An element-specific…

Chemical Physics · Physics 2020-09-23 Levi Keller , Volker Blum , Patrick Rinke , Dorothea Golze

Ground-state Kohn-Sham density functional theory provides, in principle, the exact ground-state energy and electronic spin-densities of real interacting electrons in a static external potential. In practice, the exact density functional for…

Chemical Physics · Physics 2022-07-11 Aaron D. Kaplan , Mel Levy , John P. Perdew

Density matrix quantum Monte Carlo (DMQMC) is used to sample exact-on-average $N$-body density matrices for uniform electron gas systems of up to 10$^{124}$ matrix elements via a stochastic solution of the Bloch equation. The results of…

Strongly Correlated Electrons · Physics 2016-09-14 Fionn D. Malone , N. S. Blunt , Ethan W. Brown , D. K. K. Lee , J. S. Spencer , W. M. C. Foulkes , James J. Shepherd

By correlating only the 1-particle states occupied in the reference determinant the conventional design for the single-reference R12/F12 explicitly-correlated methods biases them towards the ground state description thereby making treatment…

Chemical Physics · Physics 2025-10-13 Conner Masteran , Bimal Gaudel , Edward F. Valeev

The recursion and path-integral methods are applied to analytically study the electronic structure of a neutral $C_{60}$ molecule. We employ a tight-binding Hamiltonian which considers both the $s$ and $p$ valence electrons of carbon. From…

Materials Science · Physics 2009-10-22 Yeong-Lieh Lin , Franco Nori
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