Related papers: Hydrogen atom and one-electron molecular systems i…
Using a Hartree-Fock mesh method and a configuration interaction approach based on a generalized Gaussian basis set we investigate the behaviour of the exchange and correlation energies of small atoms and molecules, namely th e helium and…
We consider the interaction of hydrogen-like atoms with a strong laser field and show that the strong field approximation and all its variants may be grouped into a set of families of approximation schemes. This is done by introducing an…
Studies of strong field ionization have historically relied on the strong field approximation, which neglects all spatial dependence in the forces experienced by the electron after ionization. More recently, the small spatial inhomogeneity…
We investigate the electromagnetic transition probabilities for the helium atom embedded in a superstrong magnetic field taking into account the finite nuclear mass. We address the regime \gamma=100-10000 a.u. studying several excited…
We develop a phase-space electronic structure theory of molecules in magnetic fields. For a system of electrons in a magnetic field with vector potential $\bf{A}(\hat{\bf{r}})$, the usual Born-Oppenheimer Hamiltonian is the sum of the…
An accurate study of the lowest $1\sigma_g$ and the low-lying excited $1\sigma_u$, $1\pi_{u,g}$, $1\delta_{g,u}$ electronic states of the exotic molecular ion $H_3^{2+}$ in linear configuration parallel to a magnetic field is carried out.…
The quantum description of an atom with a magnetic quadrupole moment in the presence of a uniform effective magnetic field is analysed. The atom is also subject to rotation and a scalar potential proportional to the inverse of the radial…
An approximation-free, numerically efficient algorithm is presented for the Hamiltonian eigen-states of the Stark-Hydrogen problem describing a quantum particle exposed to the central Coulomb force and a homogeneous external field. As an…
A simple, approximate relation is found between the total energy of a free atom and its atomic number: E ~= -Z^{2.411}. The existence of this index is inherent in the Coulomb and many-body nature of the electron-electron interaction in the…
We consider a Dirac one-electron atom placed in a weak, static, uniform magnetic field. We show that, to the first order in the strength B of the external field, the only electric multipole moments, which are induced by the perturbation in…
Structural and thermodynamic properties of ionic fluids are related to those of a simpler ``mimic'' system with short ranged intermolecular interactions in a spatially varying effective field by use of Local Molecular Field (LMF) theory,…
One approximation is made to describe a M+1 electron many-body wavefunction by a M electron many-body wavefunction and a single electron wavefunction. Under this approximation, we have derived the Coulomb energy which relates the exciton…
In the present work, we predict the existence of new types of hydrogenlike matter, including hydrogenlike atoms ($\pi^+e^-$, $K^+e^-$, $D^+e^-$), hydrogenlike molecular ions ($\pi^+\pi^+e^-$, $K^+K^+e^-$, $D^+D^+e^-$) and hydrogenlike…
For a hydrogen atom subject to a constant magnetic field, we report a numerical realization of the two-dimensional Non-Linearization Procedure (NLP) to estimate the accuracy of the variational energy associated with a given trial function.…
Let E(B,Z,N) denote the ground state energy of an atom with N electrons and nuclear charge Z in a homogeneous magnetic field B. We study the asymptotics of E(B,Z,N) as $B\to \infty$ with N and Z fixed but arbitrary. It is shown that the…
Conditions at which a quasi-one-dimensional (1D) electron system can be considered as a quantum liquid of impenetrable charged particles are theoretically analyzed. In the presence of an inert, neutralizing background, a motion of…
The aim of the current work is the numerical research of the anisotropic characteristics of the two-dimensional hydrogen atom induced by a magnetic field. The ground state energy (GSE) of the two-dimensional hydrogen atom and the…
The quest for the value of the electron's atomic mass has been subject of continuing efforts over the last decades. Among the seemingly fundamental constants which parameterize the Standard Model (SM) of physics and which are thus…
Employing a local formula for the electron-electron interaction energy, we derive a self-consistent approximation for the total energy of a general $N$-electron system. Our scheme works as a local variant of the Thomas-Fermi approximation…
In this study, we develop and implement a specialized coupled-cluster (CC) approach tailored for accurately describing atoms and molecules in strong magnetic fields. Using the open-source Ghent Quantum Chemistry Package (\texttt{GQCP}) in…