Related papers: Progress on indium and barium single ion optical f…
A fundamental limit to the stability of a single-ion optical frequency standard is set by quantum noise in the measurement of the internal state of the ion. We discuss how the interrogation sequence and the processing of the atomic…
We have completed a new measurement of the Stark shift in 115In within the 410 nm 5P1/2- 6S1/2 transition. We measure the Stark shift constant to be kS= - 122.92(33)kHz/(kV/cm)^2, corresponding to a difference in the 6S1/2 and 5P1/2 state…
We have measured the frequency of the $6s^2S_{1/2} - 5d^2D_{3/2}$ electric-quadrupole transition of $^{171}$Yb$^+$ with a relative uncertainty of $1\times 10^{-14}$, $\nu_{Yb}$ = 688 358 979 309 312 Hz $\pm$ 6 Hz. A femtosecond frequency…
Precision comparisons of different atomic frequency standards over a period of a few years can be used for a sensitive search for temporal variations of fundamental constants. We present recent frequency measurements of the 688 THz…
An atom exposed to an electric field will experience Stark shifts of its internal energy levels, proportional to their polarizabilities. In optical frequency metrology, the Stark shift due to background black-body radiation (BBR) modifies…
We describe the current status of the Ca optical frequency standards with laser-cooled neutral atoms realized in two different laboratories for the purpose of developing a possible future optical atomic clock. Frequency measurements…
Over a two-year duration, we have compared the frequency of the 199Hg+ 5d106s 2S 1/2 (F=0)<-> 5d9 6s2 2D 5/2 (F=2) electric-quadrupole transition at 282 nm with the frequency of the ground-state hyperfine splitting in neutral 133Cs. These…
The paper describes the results achieved in the development of the compact transportable fully automated optical clock based on a single 171Yb+ ion in a radiofrequency (RF) quadrupole trap. The resulted measurements demonstrated the 4.9E-16…
Rubidium two-photon frequency standards are emerging as powerful contenders for compact, durable devices with exceptional stability. The field has focused on single-color excitation to date. Here we demonstrate the key advantages of a…
The hyperfine structure of the S1/2-D5/2 quadrupole transition at 729 nm in 43Ca+ has been investigated by laser spectroscopy using a single trapped 43Ca+ ion. We determine the hyperfine structure constants of the metastable level as…
We measure isotope shifts for five Yb$^+$ isotopes with zero nuclear spin on two narrow optical quadrupole transitions ${}^2S_{1/2} \rightarrow {}^2D_{3/2}$, ${}^2S_{1/2} \rightarrow {}^2D_{5/2}$ with an accuracy of $\sim 300$ Hz. The…
The Single Ion Differential alpha Measurement (SIDAM) method for measuring fine stucture variations (daa)and its figures of merit are illustrated together with the results produced by means of FeII absorption lines of QSO intervening…
Single trapped ions are ideal systems in which to test atomic physics at high precision: they are effectively isolated atoms held at rest and largely free from perturbing interactions. This thesis describes several projects developed to…
We report new experimental hyperfine structure (HFS) constants of neutral and singly ionized scandium (Sc I and Sc II). We observed spectra of Sc-Ar and Sc-Ne hollow cathode discharges in the region 200-2500 nm (50,000-4000 cm$^{-1}$) using…
This dissertation reports on the development of a low-power, high-stability miniature atomic frequency standard based on 171Yb+ ions. The ions are buffer-gas cooled and held in a linear quadrupole trap that is integrated into a sealed,…
We present an optical spectroscopy study on F-substituted NdOBiS$_2$ superconducting single crystals grown using KCl/LiCl flux method. The measurement reveals a simple metallic response with a relatively low screened plasma edge near 5000…
Indium Sulphide (InS) single crystals are successfully grown by In flux. Single crystal X-ray diffraction shows orthorhombic structure of Pnnm space group. Ellipsometry measurements performed on the (010) oriented crystal exhibit low…
We report the direct measurement of isotope shifts of the barium 6s$^2$ $^1$S$_0$ --5d6p $^3$D$^\text{o}_1$ 413-nm electric quadrupole transition, which is utilized for efficient barium ion trapping via photoionization using a single…
Pure electronic Raman spectra with no phonon structures superimposed to the electronic continuum, are reported, in optimally doped HgBa_{2}CaCu_{2}O_{6+\delta } single crystals (T_{c }=126 K). As a consequence, the spectra in the A_{1g },…
Both single-laser and two-laser experiments were conducted to look into the ion-imaging of Br*(2P1/2) and Br(2P3/2) photo-fragmented from 1-bromo-2-methylbutane in the range 232-240 nm via a detection scheme of (2+1) resonance-enhanced…