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We investigate condensation of a long confined chiral nematic polymer inside a spherical enclosure, mimicking condensation of DNA inside a viral capsid. The Landau-de Gennes nematic free energy {\sl Ansatz} appropriate for nematic polymers…

Soft Condensed Matter · Physics 2015-06-11 Daniel Svenšek , Rudolf Podgornik

Directed motion up a concentration gradient is crucial for the survival and maintenance of numerous biological systems, such as sperms moving towards an egg during fertilization or ciliates moving towards a food source. In these systems,…

Statistical Mechanics · Physics 2025-05-01 Bhavesh Valecha , Hossein Vahid , Pietro Luigi Muzzeddu , Jens-Uwe Sommer , Abhinav Sharma

We show that chiral symmetry can be broken spontaneously in one-component systems with isotropic interactions, i.e. many-particle systems having maximal a priori symmetry. This is achieved by designing isotropic potentials that lead to…

Materials Science · Physics 2012-05-16 Erik Edlund , Oskar Lindgren , Martin Nilsson Jacobi

Imprinting of cholesteric textures in a polymer network is a method of preserving a macroscopically chiral phase in a system with no molecular chirality. By modifying the elastics properties of the network, the resulting stored helical…

Soft Condensed Matter · Physics 2009-11-11 S. Courty , A. R. Tajbakhsh , E. M. Terentjev

Liquid crystal mesophases of achiral molecules are normally achiral, yet in a few materials they spontaneously segregate and form right- and left-handed chiral domains. One mechanism that drives chiral segregation is molecular shape…

Soft Condensed Matter · Physics 2026-01-16 Matthew J. Deutsch , Robin L. B. Selinger , Paul van der Schoot

A phase transition can drive the spontaneous emergence of chiral orders in crystals below a critical temperature. However, selecting either a right- or a left-handed phase with the aid of electromagnetic fields is challenging, particularly…

Materials Science · Physics 2025-03-11 Mauro Fava , Aldo H. Romero , Eric Bousquet

An autocatalytic pattern matching polymer system is studied as an abstract model for chemical ecosystem evolution. Highly ordered populations with particular sequence patterns appear spontaneously out of a vast number of possible states.…

Molecular Networks · Quantitative Biology 2015-06-17 Shinpei Tanaka , Harold Fellermann , Steen Rasmussen

In equilibrium liquid crystals, chirality leads to a variety of spectacular three-dimensional structures, but chiral and achiral phases with the same broken continuous symmetries have identical long-time, large-scale dynamics. In this…

Soft Condensed Matter · Physics 2021-06-23 S. J. Kole , Gareth P. Alexander , Sriram Ramaswamy , Ananyo Maitra

Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…

We review the existing mathematical models which describe physicochemical mechanisms capable of producing a symmetry-breaking transition to a state in which one chirality dominates the other. A new model is proposed, with the aim of…

Biomolecules · Quantitative Biology 2010-07-20 Jonathan AD Wattis

We study, experimentally, the dynamics of a binary mixture of air-fluidized disks. The disks are chiral since they incorporate a set of blades with constant tilt. Both species are identical except for their blades tilt angle, which is…

Soft Condensed Matter · Physics 2022-10-05 Miguel Ángel López-Castaño , Álvaro Rodríguez-Rivas , Francisco Vega Reyes

Chiral polymers are ubiquitous in nature and in the cellular context they are often found in association with membranes. Here we show that surface bound polymers with an intrinsic twist and anisotropic bending stiffness can exhibit a sharp…

Soft Condensed Matter · Physics 2016-04-26 David A. Quint , Ajay Gopinathan , Gregory M. Grason

From the beginning of molecular theory, the interplay of chirality and magnetism has intrigued scientists. There is still the question if enantiospecific adsorption of chiral molecules occurs on magnetic surfaces. Enantiomer discrimination…

Chiral molecules can selectively transport electrons of a particular spin orientation, yet the underlying mechanism remain poorly understood. Here, we present theoretical evidence that electrons propagating through chiral materials with…

Materials Science · Physics 2024-03-01 Xiaoming Wang , Yeming Xian , Yanfa Yan

We investigate the interaction between a chirally imprinted network and a solvent of chiral molecules. We find, a liquid crystalline polymer network is preferentially swollen by one component of a racemic solvent. This ability to separate…

Soft Condensed Matter · Physics 2009-11-07 Y. Mao , M. Warner

We experimentally investigate the chiral optical response of an individual nanostructure consisting of three equally sized spherical nanoparticles made of different materials and arranged in \ang{90} bent geometry. Placing the nanostructure…

Optics · Physics 2019-07-30 Sergey Nechayev , René Barczyk , Uwe Mick , Peter Banzer

A system formed by a crowded environment of catalytic obstacles and complex oscillatory chemical reactions is inquired. The obstacles are static spheres of equal radius, which are placed in a random way. The chemical reactions are carried…

Chemical Physics · Physics 2018-12-05 Carlos Echeverria , José L. Herrera , Kay Tucci , Orlando Alvarez-Llamoza , Miguel Morales

Chirality and chiral molecules are key elements in modern chemical and biochemical industries. Individual addressing, and the eventual separation of chiral enantiomers has been and still is an important elusive task in molecular physics and…

Detection of chiral molecules requires amplification of chirality to measurable levels. Typically, amplification mechanisms are considered at the microscopic scales of individual molecules and their aggregates. Here we demonstrate chirality…

Soft Condensed Matter · Physics 2015-07-28 Chenhui Peng , Oleg D. Lavrentovich

The question of the onset of the homochirality on prebiotic Earth still remains a fundamental question in the quest for the origin of life. Recent works in this field introduce the concept of recycling, rather than the traditional open-flow…

Molecular Networks · Quantitative Biology 2011-05-23 Raphael Plasson