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We propose an extension of the law of corresponding states that can be applied to systems - such as colloidal suspensions - that have widely different ranges of attractive interactions. We argue that, for such systems, the ``reduced''…

Soft Condensed Matter · Physics 2009-10-31 Massimo G. Noro , Daan Frenkel

The time-dependent variational principle is used to optimize the linear and nonlinear parameters of Gaussian basis functions to solve the time-dependent Schrodinger equation in 1 and 3 dimensions for a one-body soft Coulomb potential in a…

We present a variational wavefunction which explains the behaviour of the supersolid state formed by hard-core bosons on the triangular lattice. The wavefunction is a linear superposition of {\em only and all} configurations minimising the…

Statistical Mechanics · Physics 2009-11-13 Arnab Sen , Prasenjit Dutt , Kedar Damle , R. Moessner

In single-reference coupled-cluster (CC) methods, one has to solve a set of non-linear polynomial equations in order to determine the so-called amplitudes which are then used to compute the energy and other properties. Although it is of…

Chemical Physics · Physics 2021-09-10 Antoine Marie , Fábris Kossoski , Pierre-François Loos

Computer-aided engineering techniques are indispensable in modern engineering developments. In particular, partial differential equations are commonly used to simulate the dynamics of physical phenomena, but very large systems are often…

Quantum Physics · Physics 2022-04-26 Yuki Sato , Ruho Kondo , Satoshi Koide , Hideki Takamatsu , Nobuyuki Imoto

Non-relativistic Helium-like ions $(-e,-e,Ze)$ with static nucleus in a $d-$dimensional space $\mathbb{R}^d$ ($d>1$) are considered. Assuming $r^{-1}$ Coulomb interactions, a 2-parametric correlated Hylleraas-type trial function is used to…

The pseudospectral method is a powerful tool for finding highly precise solutions of Schr\"{o}dinger's equation for few-electron problems. We extend the method's scope to wave functions with non-zero angular momentum and test it on several…

Atomic Physics · Physics 2013-05-29 Paul E. Grabowski , David F. Chernoff

The Hohenberg-Kohn theorem of the density functional theory is extended by modifying the Levy constrained-search formulation. The new theorem allows us to choose arbitrary physical quantities as the basic variables which determine the…

Condensed Matter · Physics 2009-11-10 M. Higuchi , K. Higuchi

The variational principle for a thin dust shell in General Relativity is constructed. The principle is compatible with the boundary-value problem of the corresponding Euler-Lagrange equations, and leads to ``natural boundary conditions'' on…

General Relativity and Quantum Cosmology · Physics 2014-11-17 V. D. Gladush

Taking the same trial wave function, the ground-state energy of Fr\"{o}hlich polaron is investigated by variational method and coherent-state expansion (CSE) one, respectively. Within the accuracy to $\alpha^{2}$(the electron-phonon…

Other Condensed Matter · Physics 2007-05-23 Qing Chen , Ke-Lin Wang , Yi Wang

We propose a method to construct the ground state $\psi(\lambda)$ of local lattice hamiltonians with the generic form $H_0 + \lambda H_1$, where $\lambda$ is a coupling constant and $H_0$ is a hamiltonian with a non degenerate ground state…

Condensed Matter · Physics 2009-10-22 J. G. Esteve , Germán Sierra

Fragmentation methods applied to multireference wave functions constitute a road towards the application of highly accurate ab initio wave function calculations to large molecules and solids. However, it is important for reproducibility and…

Chemical Physics · Physics 2020-07-23 Matthew R. Hermes , Laura Gagliardi

We propose and analyze a new numerical method for computing the ground state of the modified Gross-Pitaevskii equation for modeling the Bose-Einstein condensate with a higher order interaction by adapting the density function formulation…

Quantum Gases · Physics 2019-08-27 Weizhu Bao , Xinran Ruan

For a hydrogen atom subject to a constant magnetic field, we report a numerical realization of the two-dimensional Non-Linearization Procedure (NLP) to estimate the accuracy of the variational energy associated with a given trial function.…

Atomic Physics · Physics 2024-07-31 J. C. del Valle

In the present work, genetic algorithm method (GA) is applied to the problem of impurity at the center of a spherical quantum dot for infinite confining potential case. For this purpose, any trial variational wave function is considered for…

Mesoscale and Nanoscale Physics · Physics 2009-09-29 Haluk Safak , Mehmet Sahin , Berna Gulveren , Mehmet Tomak

We propose a variational approximation to the ground state energy of a one-dimensional gas of interacting bosons on the continuum based on the Bethe Ansatz ground state wavefunction of the Lieb-Liniger model. We apply our variational…

Quantum Gases · Physics 2020-01-08 S. De Palo , R. Citro , E. Orignac

A variational principle for determining unstable periodic orbits of flows as well as unstable spatio-temporally periodic solutions of extended systems is proposed and implemented. An initial loop approximating a periodic solution is evolved…

Chaotic Dynamics · Physics 2009-11-10 Yueheng Lan , Predrag Cvitanovic

A signature of the dark energy equation of state may be observed in the shape of voids. We estimate the constraints on cosmological parameters that would be determined from the ellipticity distribution of voids from future spectroscopic…

Cosmology and Nongalactic Astrophysics · Physics 2014-11-20 Rahul Biswas , Esfandiar Alizadeh , Benjamin D. Wandelt

A variational Perturbation theory based on the functional integral approach is formulated for many-particle systems. Using the variational action obtained through Jensen-Peierls' inequality, a perturbative expansion scheme for the…

Strongly Correlated Electrons · Physics 2009-10-31 Sang Koo You , Chul Koo Kim , Kyun Nahm , Hyun Sik Noh

Electrical signaling via voltage-gated ion channels depends upon the function of the voltage sensor (VS), identified with the S1-S4 domain of voltage-gated K channels. Here we investigate some physical aspects of the sliding-helix model of…

Biomolecules · Quantitative Biology 2015-03-13 Alexander Peyser , Wolfgang Nonner