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Precise molecular transition frequencies are of great interest in the test of fundamental physics and also in various applications. Two well isolated ro-vibrational transitions of $^{12}$C$^{16}$O at 1.57 $\mu$m, R(9) and R(10) in the…

Atomic Physics · Physics 2017-10-11 Jin Wang , Yu R. Sun , Lei-Gang Tao , An-Wen Liu , Shui-Ming Hu

We analyze several possibilities for precisely measuring electronic transitions in atomic helium by the direct use of phase-stabilized femtosecond frequency combs. Because the comb is self-calibrating and can be shifted into the ultraviolet…

Atomic Physics · Physics 2008-06-23 E. E. Eyler , D. E. Chieda , Matthew C. Stowe , Michael J. Thorpe , T. R. Schibli , Jun Ye

We demonstrate theoretically the existence of a linear dc Stark shift of the individual substates of an alkali atom in its ground state, dressed by a circularly polarized laser field. It arises from the electroweak nuclear anapole moment…

Atomic Physics · Physics 2008-11-26 Marie-Anne Bouchiat

The highly forbidden $^2$S$_{1/2} \rightarrow ^2$F$_{7/2}$ electric octupole transition in $^{171}$Yb$^+$ is a potential candidate for a redefinition of the SI second. We present a measurement of the absolute frequency of this optical…

We report absolute frequency, isotope shift, radiative lifetime and hyperfine structure measurements of the $^1P_1 \leftarrow{} ^{1}S_0$ (213.8 nm) transition in Zn I using a cryogenic buffer gas beam. Laser-induced fluorescence is…

We measure the spectrum of tellurium-130 in the vicinity of the 461~nm ${}^1\text{S}_0-{}^{1}\text{P}_1$ cycling transition in neutral strontium, a popular element for atomic clocks, quantum information, and quantum-degenerate gases. The…

Atomic Physics · Physics 2022-05-23 T. G. Akin , Bryan Hemingway , Steven Peil

Modern resonant spectroscopic experiments to measure transition frequencies in atoms have reached a level where a meticulous description of all aspects of the processes under study has become obligatory. The precision achieved in the…

Atomic Physics · Physics 2025-09-11 D. Solovyev , T. Zalialiutdinov , A. Anikin , L. Labzowsky

Recently we reported a high precision optical frequency measurement of the (v,L):(0,2)->(8,3) vibrational overtone transition in trapped deuterated molecular hydrogen (HD+) ions at 10 mK temperature. Achieving a resolution of 0.85…

Atomic Physics · Physics 2017-02-20 J. Biesheuvel , J. -Ph. Karr , L. Hilico , K. S. E. Eikema , W. Ubachs , J. C. J. Koelemeij

Transition frequencies and fine-structure splittings of the $2\,{}^3\!S_1 \rightarrow 2\,{}^3\!P_{\!J}$ transitions in helium-like $^{12}\mathrm{C}^{4+}$ were measured by collinear laser spectroscopy on a 1-ppb level. Accuracy is increased…

We describe repumping and spectroscopy of laser-cooled strontium (Sr) atoms using the (5s5p)3P2 - (5s4d)3D2 transition. Atom number in a magneto-optical trap is enhanced by driving this transition because Sr atoms that have decayed into the…

The hyperfine structure and isotope shifts of the 3s23p2 3P2 to 3s3p3 3Do3 transition in silicon have been measured. The transition at 221.7 nm was studied by laser induced fluorescence in an atomic Si beam. For 29Si, the hyperfine A…

Atomic Physics · Physics 2015-05-20 Siu Au Lee , William Fairbank

We report the first observation of the magnetic-field-induced (5d10 6s2)1S0-(5d10 6s6p)3P0 transition in a bosonic isotope of mercury, 198Hg, realized in an optical lattice clock. We characterize this new isotope, determining key features…

We used a Cs atomic fountain frequency standard to measure the Stark shift on the ground state hyperfine transiton frequency in cesium (9.2 GHz) due to the electric field generated by the blackbody radiation. The measures relative shift at…

Atomic Physics · Physics 2009-11-10 F. Levi , D. Calonico , L. Lorini , S. Micalizio , A. Godone

We have measured the forbidden 2 3S1 - 2 1P1 transition at 887 nm in a quantum degenerate gas of metastable He-4 atoms confined in an optical dipole trap. The determined transition frequency is 338 133 594.4 (0.5) MHz, from which we obtain…

Atomic Physics · Physics 2014-06-27 Remy Notermans , Wim Vassen

We have determined the frequency shift that blackbody radiation is inducing on the $5s^2$ $^1$S$_0$ -- $5s5p$ $^3$P$_0$ clock transition in strontium. Previously its uncertainty limited the uncertainty of strontium lattice clocks to…

Atomic Physics · Physics 2013-01-01 Thomas Middelmann , Stephan Falke , Christian Lisdat , Uwe Sterr

We demonstrate a new simple technique to measure IR frequencies near 30 THz using a femtosecond (fs) laser optical comb and sum-frequency generation. The optical frequency is directly compared to the distance between two modes of the fs…

We experimentally investigate an optical frequency standard based on the $^2S_{1/2} (F=0)\to {}^2F_{7/2} (F=3)$ electric octupole (\textit{E}3) transition of a single trapped $^{171}$Yb$^+$ ion. For the spectroscopy of this strongly…

Atomic and Molecular Clusters · Physics 2016-02-15 N. Huntemann , C. Sanner , B. Lipphardt , Chr. Tamm , E. Peik

The $3p^{4}$ $^{3}$P$_{J}$ - $3p^{3}4p$ $^{3}$P$_{J}$ transition in the sulphur atom is investigated in a precision two-photon excitation scheme under Doppler-free and collision-free circumstances yielding an absolute accuracy of 0.0009…

Atomic Physics · Physics 2020-06-23 K. -F. Lai , E. J. Salumbides , W. Ubachs

We report on the atom loss spectroscopy of strontium Rydberg atoms in a magneto-optical trap, using a two-photon excitation scheme through the intermediate state $5\mathrm{s}5\mathrm{p} \, ^3\mathrm{P}_1$. Energies of the…

We demonstrate a technique to measure hyperfine structure using a frequency-stabilized diode laser and an acousto-optic modulator locked to the frequency difference between two hyperfine peaks. We use this technique to measure hyperfine…

Atomic Physics · Physics 2007-05-23 Umakant D. Rapol , Anusha Krishna , Vasant Natarajan