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Molecular self-assembly has been extensively used for surface modification of metals and oxides for a variety of applications, including molecular and organic electronics. One of the goals of this research is to learn how the electronic…

Materials Science · Physics 2009-11-13 M. F. Calhoun , J. Sanchez , D. Olaya , M. E. Gershenson , V. Podzorov*

Reading and manipulating the spin status of single magnetic molecules is of paramount importance both for applicative and fundamental purposes. The possibility to combine Electron Spin Resonance (ESR) and Scanning Tunnelling Microscopy…

Instrumentation and Detectors · Physics 2016-11-15 Paolo Messina , Paolo Sigalotti , Lorenzo Lenci , Matteo Mannini , Stefano Prato , Paolo Pittana , Dante Gatteschi

Implementation of quantum information processing based on spatially localized electronic spins in stable molecular radicals is discussed. The necessary operating conditions for such molecules are formulated in self-assembled monolayer (SAM)…

Quantum Physics · Physics 2007-05-23 A. Tamulis , V. I. Tsifrinovich , S. Tretiak , G. P. Berman , D. L. Allara

A key to building functional devices on the basis of single molecule magnets in the framework of molecular electronics is the ability to deposit and study these molecules on a surface, because the structural, electronic and magnetic…

Mesoscale and Nanoscale Physics · Physics 2016-01-26 Judith Donner , Jan-Philipp Broschinski , Bastian Feldscher , Anja Stammler , Hartmut Bögge , Thorsten Glaser , Daniel Wegner

Spin resonance of single spin centers bears great potential for chemical structure analysis, quantum sensing and quantum coherent manipulation. Essential for these experiments is the presence of a two-level spin system whose energy…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Philip Willke , Aparajita Singha , Xue Zhang , Taner Esat , Christopher P. Lutz , Andreas J. Heinrich , Taeyoung Choi

We use first principles density functional theory to calculate the electronic structure of the phenylthiolate (S-C$_6$H$_5$) self-assembled monolayer (SAM) on Cu(111) and Au(111) substrates. We find significant lateral dispersion of the SAM…

Materials Science · Physics 2009-11-10 Vasili Perebeinos , Marshall Newton

Interest in the magnetism of organic compounds is growing because of new organic magnets, spin-based electronics and the diverse properties of magnetic edge states in graphene nanoribbons. Electron spin resonance spectroscopy combined with…

Mesoscale and Nanoscale Physics · Physics 2025-04-28 Gregory Czap , Christoph Wolf , Jose Reina-Gálvez , Mark H. Sherwood , Christopher P. Lutz

Organic paramagnetic and electroactive molecules are attracting interest as core components of molecular electronic and spintronic devices. Currently, further progress is hindered by the modest stability and reproducibility of the…

Electron paramagnetic resonance (EPR) can provide unique insight into the chemical structure and magnetic properties of dopants in oxide and semiconducting materials that are of interest for applications in electronics, catalysis, and…

We propose a new universal mechanism that makes it possible to drive an individual atomic spin using a spin polarized scanning tunnel microscope (STM) with an oscillating electric signal. We show that the combination of the distance…

Mesoscale and Nanoscale Physics · Physics 2017-11-15 J. L. Lado , A. Ferron , J. Fernandez-Rossier

We propose an atom-superposition-based method for simulating spin-polarized scanning tunneling microscopy (SP-STM) from first principles. Our approach provides bias dependent STM images in high spatial resolution, with the capability of…

Materials Science · Physics 2011-11-28 Krisztián Palotás , Werner A. Hofer , László Szunyogh

Individual magnetic molecules are promising building blocks for quantum technologies because of their chemical tunability, nanoscale dimensions, and ability to self-assemble into ordered arrays. However, harnessing their properties in…

In this paper we analyze in details the electronic properties of (Co/Ni) multilayers, a model system for spintronics devices. We use magneto-optical Kerr (MOKE), spin-polarized photoemission spectroscopy (SRPES), x-ray magnetic circular…

We have carried out a preliminary design and simulation of a single-electron resistive switch based on a system of two linear, parallel, electrostatically-coupled molecules: one implementing a single-electron transistor and another serving…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Nikita Simonian , Andreas Mayr , Konstantin K. Likharev

Molecular-scale diodes made from self-assembled monolayers (SAMs) could complement silicon-based technologies with smaller, cheaper, and more versatile devices. However, advancement of this emerging technology is limited by insufficient…

High tunability of two dimensional magnetic materials (by strain, gating, heterostructuring or otherwise) provides unique conditions for studying versatile magnetic properties and controlling emergent magnetic phases. Expanding the scope of…

Computational Physics · Physics 2020-07-07 Raí M. Menezes , Clécio C. de Souza Silva , Milorad V. Milošević

We propose a computationally efficient atom-superposition-based method for simulating spin-polarized scanning tunneling spectroscopy (SP-STS) on complex magnetic surfaces based on the sample and tip electronic structures obtained from first…

Materials Science · Physics 2012-05-17 Krisztián Palotás , Werner A. Hofer , László Szunyogh

Recent experiments on electron scattering through molecular films have shown that chiral molecules can be efficient sources of polarized electrons even in the absence of heavy nuclei as source of a strong spin-orbit interaction. We show…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Ernesto Medina , Floralba López , Mark Ratner , Vladimiro Mujica

An attempt is made to bypass spectral analysis and fit internal coordinates of radicals directly to experimental liquid- and solid-state electron spin resonance (ESR) spectra. We take advantage of the recently introduced large-scale spin…

Chemical Physics · Physics 2014-07-16 G. T. P. Charnock , M. Krzystyniak , Ilya Kuprov

Understanding nanoscale mechanisms responsible for the recently discovered ferroelectric nematics can be helped by direct visualization of self-assembly of strongly polar molecules. Here we report on scanning tunneling microscopy (STM)…

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