Related papers: Relativistic and Radiative Energy Shifts for Rydbe…
The charge transfer (ionization) of hydrogen Rydberg atoms (principal quantum number $n=25-34$) incident at a Cu(100) surface is investigated. Unlike fully metallic surfaces, where the Rydberg electron energy is degenerate with the…
High-precision laser spectroscopy of atomic hydrogen has led to an impressive accuracy in tests of bound-state quantum electrodynamics (QED). At the current level of accuracy many systematics have to be studied very carefully and only…
The leading relativistic and QED corrections to the ground state energy of the three-body system (epe) are calculated numerically using a Hylleraas correlated basis set. The accuracy of the nonrelativistic variational ground state wave…
We evaluate a number of systematic effects that are important for an experimental microwave measurement of the $n$$=$$2$ S-to-P intervals in atomic hydrogen. The analysis is important for both re-evaluating the best existing measurement…
The invariant mass of free particles is used to derive a bound-state equation for the hydrogen atom at rest. This equation has the well-known solutions for the single-particle states. Existence of two-particle bound states, for which the…
We present a numerical evaluation of the loop-after-loop contribution to the second-order self-energy for the ground state of hydrogenlike atoms with low nuclear charge numbers Z. The calculation is carried out in the Fried-Yennie gauge and…
The maximal acceleration corrections to the Lamb shift of one--electron atoms are calculated in a non--relativistic approximation. They are compatible with experimental results, are in particularly good agreement with the $2S-2P$ Lamb shift…
In this work, we present expressions for the full effective potential corresponding to the one-photon exchange interaction within the framework of an effective Schr\"{o}dinger-like equation, which is derived exactly from the Bethe-Salpeter…
Corrections to energy levels in light muonic atoms are investigated in order $\alpha^2(Z\alpha)^4m$. We pay attention to corrections which are specific for muonic atoms and include the electron vacuum polarization loop. In particular, we…
We describe a new approach to computing energy levels of a non-relativistic bound-state of two constituents with masses M and m, by a systematic expansion in powers of m/M. After discussing the method, we demonstrate its potential with an…
We investigate the gauge invariance of the leading logarithmic radiative correction to the two-photon decay width in hydrogenlike atoms. It is shown that an effective treatment of the correction using a Lamb-shift "potential" leads to…
By combining a recent precise measurement of the ionization energy of $^{87}$Rb with previous measurements of electronic and hyperfine structure, an accurate value for the $^{85}\textrm{Rb}-^{87}\textrm{Rb}$ isotope shift of the…
The variational method is used to study the energy levels of muonic helium $(\mu^{-} \, e^{-} \, He)$ with an electron in the ground state and a muon in an excited state with principal and orbital quantum numbers $n \sim l+1 \sim 14$. The…
Rydberg excited states of molecules pose a challenge for electronic structure calculations because of their highly diffuse electron distribution. Even large and elaborate atomic basis sets tend to underrepresent the long-range tail, overly…
Precision measurements of transitions between singlet ($S=0$) Rydberg states of H$_2$ belonging to series converging on the $\mathrm{X}^+\,^2\Sigma_g^+(v^+=0,N^+=0)$ state of H$_2^+$ have been carried out by millimetre-wave spectroscopy…
A comprehensive theory of the Lamb shift in light muonic atoms such as $\mu$H, $\mu$D, $\mu^3$He$^+$, and $\mu^4$He$^+$ is presented, with all quantum electrodynamic corrections included at the precision level constrained by the uncertainty…
Recent improvements in the determination of the running of the fine-structure constant also allow an update of the hadronic vacuum-polarization contribution to the Lamb shift. We find a shift of -3.40(7) kHz to the 1S level of hydrogen. We…
Rydberg states of alkali atoms are highly sensitive to electromagnetic radiation in the GHz-to-THz regime because their transitions have large electric dipole moments. Consequently, environmental blackbody radiation (BBR) can couple Rydberg…
The dynamics of Rydberg states of atomic hydrogen perturbed simultaneously by a static electric field and a resonant microwave field of elliptical polarization is analysed in the quantum perturbative limit of small amplitudes. For some…
We have studied an ionization of alkali-metal Rydberg atoms by blackbody radiation (BBR). The results of the theoretical calculations of ionization rates of Li, Na, K, Rb and Cs Rydberg atoms are presented. Calculations have been performed…