Related papers: Thermodynamic derivation of reciprocal relations
The statistical mechanical basis of the fluctuation theory of mixtures is reviewed. An overview of the statistical mechanical relations between the microscopic properties of a system and its macroscopic properties is presented. The…
Relating thermodynamic and kinetic properties is a conceptual challenge with many practical benefits. Here, based on first principles, we derive a rigorous inequality relating the entropy and the dynamic propagator of particle…
By assuming an appropriate energy composition law between two systems governed by the same non-extensive entropy, we revisit the definitions of temperature and pressure, arising from the zeroth principle of thermodynamics, in a manner…
The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…
Multiscale thermodynamics is a theory of relations among levels of investigation of complex systems. It includes the classical equilibrium thermodynamics as a special case but it is applicable to both static and time evolving processes in…
A realistic and objective axiomatic formulation of Thermostatics for composite systems is presented. The main feature of our axiomatics is that it is free of empirical definitions. In particular, the basic concepts of the theory, such as…
A few decades after Hill's work on nano-thermodynamics, the development of a thermodynamic framework, to account consistently for the fluctuations of small systems due to their interactions with the surrounding environment, is still…
We develop an exact quantum thermodynamic description for a noninteracting nanoscale steady state that couples strongly with multiple reservoirs. It is demonstrated that there exists a steady-state extension of the thermodynamic function…
Thermodynamics is based on a coarse-grained approach, from which its fundamental variables emerge, effectively erasing the complicate details of the microscopic dynamics within a macroscopic system. The strength of Thermodynamics lies in…
Thermodynamic uncertainty principles make up one of the few rare anchors in the largely uncharted waters of nonequilibrium systems, the fluctuation theorems being the more familiar. In this work we aim to trace the uncertainties of…
We show that there exists a natural way to define a condition of generalized thermal equilibrium between systems governed by Tsallis thermostatistics, under the hypotheses that i) the coupling between the systems is weak, ii) the structure…
We provide a characterization of energy in the form of exchanged heat and work between two interacting constituents of a closed, bipartite, correlated quantum system. By defining a binding energy we derive a consistent quantum formulation…
This is a general description of a probabilistic formalism of mechanics, i.e., an extension of the Newtonian mechanics principles to the systems undergoing random motion. From an analysis of the induction procedure from experimental data to…
We focus attention on some particular thermodynamic relations (PTR). Using information theory concepts we show that, for a reversible process, microscopic considerations related to these PTR make the concomitant informational contents of…
Thermodynamics at the nanoscale is known to differ significantly from its familiar macroscopic counterpart: the possibility of state transitions is not determined by free energy alone, but by an infinite family of free-energy-like…
We show that the zeroth law of thermodynamics holds within an alternative version of nonextensive statistical mechanics based on {\it incomplete probability distribution}. The generalized zeroth law leads to a generalized definition of…
Information dynamics is an emerging description of information processing in complex systems which describes systems in terms of intrinsic computation, identifying computational primitives of information storage and transfer. In this paper…
Some interactions between classical or quantum fields and matter are known to be irreversible processes. Here we associate an entropy to the electromagnetic field from well-known notions of statistical quantum mechanics, in particular the…
In this article a definition of reversible processes in terms of differences in intensive Thermodynamics properties (Affinities) is proposed. This definition makes it possible to both define reversible processes before introducing the…
This paper offers a pedestrian guide from the fundamental properties of entropy to the axioms of thermodynamics, which are a consequence of the axiom of statistical physics. It also dismantles flawed concepts, such as assigning physical…