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We show that the standard textbook description of (restricted) Hartree--Fock theory for (Fermi) Hubbard-like models is in need of an update, and we present such an update allowing us to correct basic and established results in the condensed…

Strongly Correlated Electrons · Physics 2025-06-23 E. Langmann , J. Lenells

By the use of integer and noninteger n-Slater Type Orbitals in combined Hartree-Fock-Roothaan method, self consistent field calculations of orbital and lowest states energies have been performed for the isoelectronic series of open shell…

Chemical Physics · Physics 2012-10-10 I. I. Guseinov , M. Erturk , E. Sahin

The applicability of the Hartree-Fock and random phase approximations to models of strongly correlated electrons is discussed. The 2D Hubbard model is analyzed. An antiferromagnetic phase (at half filling) and Fermi liquid behavior (at low…

Condensed Matter · Physics 2007-05-23 F. Guinea , E. Louis , J. A. Verges

We establish both a local and a global well-posedness theories for the nonlinear Hartree-Fock equations and its reduced analog in the setting of the modulation spaces on $\mathbb R^d$. In addition, we prove similar results when a harmonic…

Analysis of PDEs · Mathematics 2019-08-19 Divyang G. Bhimani , Manoussos Grillakis , Kasso A. Okoudjou

The energy levels of the first few low-lying states of helium and lithium atoms in intense magnetic fields up to $\approx 10^8-10^9$~T are calculated in this study. A pseudospectral method is employed for the computational procedure. The…

Quantum Physics · Physics 2014-06-11 Anand Thirumalai , Jeremy S. Heyl

A framework for developing new approximate electronic structure methods is presented, in which the correlation energy of a many-electron system in the ground state is computed as in the single-reference second-order many-body perturbation…

Chemical Physics · Physics 2011-06-15 Dimitri Laikov

We present a simplified method to generate the Hartree-Fock Gamow basis from realistic nuclear forces. The Hartree-Fock iteration in the harmonic-oscillator basis is first performed, and then the obtained HF potential is analytically…

Nuclear Theory · Physics 2018-06-05 Qiang Wu , Furong Xu

Condensed Fermi systems with an odd number of particles can be described by means of polarizing external fields having a time-odd character. We illustrate how this works for Fermi gases and atomic nuclei treated by density functional theory…

Superconductivity · Physics 2009-09-20 George Bertsch , Jacek Dobaczewski , Witold Nazarewicz , Junchen Pei

Pfaffian formulas used to compute overlaps necessary to carry out generator coordinate method calculations using a set of Hartree- Fock- Bogoliubov wave functions, is generalized to the case where each of the HFB states are expanded in…

Nuclear Theory · Physics 2025-04-01 L. M. Robledo

Projected Hartree-Fock theory provides an accurate description of many kinds of strong correlation but does not properly describe weakly correlated systems. Coupled cluster theory, in contrast, does the opposite. It therefore seems natural…

Strongly Correlated Electrons · Physics 2017-08-22 Ethan Qiu , Thomas M. Henderson , Gustavo E. Scuseria

Antiferromagnetic and charge ordered Hartree-Fock solutions of the one-band Hubbard model with on-site and nearest-neighbor Coulomb repulsions are exactly mapped onto an auxiliary local Kohn-Sham (KS) problem within a density-functional…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev

Mean-field methods such as Hartree-Fock (HF) or Hartree-Fock-Bogoliubov (HFB) constitute the building blocks upon which more elaborate many-body theories are based on. The HF and HFB wavefunctions are built out of independent…

Strongly Correlated Electrons · Physics 2013-06-28 Carlos A. Jimenez-Hoyos , R. Rodriguez-Guzman , Gustavo E. Scuseria

The multiconfigurational time-dependent Hartree-Fock equations are discussed and solved for a one-dimensional model of the Helium atom. Results for the ground state energy and two-particle density as well as the absorption spectrum are…

Quantum Physics · Physics 2015-03-13 D. Hochstuhl , S. Bauch , M. Bonitz

The density-constrained time-dependent Hartree-Fock (DC-TDHF) theory is a fully microscopic approach for calculating heavy-ion interaction potentials and fusion cross sections below and above the fusion barrier. We discuss recent…

Nuclear Theory · Physics 2017-08-23 A. S. Umar , V. E. Oberacker , J. A. Maruhn , R. Keser

The Hartree-Fock (HF) approximation has been an important tool for quantum-chemical calculations since its earliest appearance in the late 1920s, and remains the starting point of most single-reference methods in use today. Intuition…

Chemical Physics · Physics 2023-07-06 Steven Crisostomo , Mel Levy , Kieron Burke

We present a new approach for calculating the nuclear equation of state and compressibility for finite nuclei using the density-constrained Hartree-Fock method.

Nuclear Theory · Physics 2008-11-26 A. S. Umar , V. E. Oberacker

It is found that, in closed-$l$-shell atoms, the exact local exchange potential $v_{\text{x}}(\bf r)$ of the density functional theory (DFT) is very well represented, within the region of every atomic shell, by each of the suitably shifted…

Atomic Physics · Physics 2015-05-13 M. Cinal

In this paper we motivate, formulate and analyze the Multi-Configuration Time-Dependent Hartree-Fock (MCTDHF) equations for molecular systems under Coulomb interaction. They consist in approximating the N-particle Schrodinger wavefunction…

Mathematical Physics · Physics 2015-05-13 C. Bardos , I. Catto , N. Mauser , S. Trabelsi

We describe the new version 2.00d of the code HFBTHO that solves the nuclear Skyrme Hartree-Fock (HF) or Skyrme Hartree-Fock-Bogolyubov (HFB) problem by using the cylindrical transformed deformed harmonic-oscillator basis. In the new…

Nuclear Theory · Physics 2013-03-19 M. V. Stoitsov , N. Schunck , M. Kortelainen , N. Michel , H. Nam , E. Olsen , J. Sarich , S. Wild

We present detailed results of Unrestricted Hartree-Fock (UHF) calculations for up to eight electrons in a parabolic quantum dot. The UHF energies are shown to provide rather accurate estimates of the ground-state energy in the entire range…

Strongly Correlated Electrons · Physics 2009-11-10 Boris Reusch , Hermann Grabert